Lightweight brick with mullite roll bar waste as raw material and preparation method thereof

A technology for mullite and lightweight bricks, which is applied in the field of lightweight bricks and its preparation, can solve problems such as the inability to guarantee the uniformity of pores, instability, and the limited scope of application of porous material methods, so as to promote environmental protection and sustainable development, The effect of reducing the temperature drop rate of molten steel and reducing solid pollution

Inactive Publication Date: 2012-02-08
WUHAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the burn-out additive method pollutes the environment, and it is difficult to control the production of lightweight bricks with ultra-low bulk density; the gas generation method cannot guarantee the uniformity of pores, and is unstable, resulting in poor slag resistance of the product; the porous material method has a limited scope of application and consumes less energy. High; such as the patented technology of "lightweight mullite heat-insulating brick" (CN101172840), which uses Suzhou soil, Lushan soil, and Jiaozuo mortar to prepare mullite heat-insulating bricks. The strength of the product is too low, which is not conducive to production and practical use.
The patented technology of "corundum-mullite adiabatic transfer" (CN1762906A) uses polystyrene foam balls and sawdust to prepare corundum mullite lightweight bricks. The pores are large and pollute the environment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] A lightweight brick using mullite roller waste as raw material and a preparation method thereof. Firstly, 50-60wt% mullite roller waste, 28-40wt% clay clinker, 0.1-3wt% α-Al 2 o 3 Micropowder, 0.1~2wt% ρ-Al 2 o 3 Micropowder, 3-5wt% of nano silicon dioxide and 6-9wt% of kyanite powder are mixed, plus 20-30wt% of water and 0.1-0.2wt% of sodium hexametaphosphate, mixed for 3-8 minutes to prepare Slurry and foam made by adding 0.1-0.2wt% foaming agent, mix evenly, pour into molding, dry at room temperature for 4-10 hours, and then dry at 100-110°C for 3-5 hours After demoulding, it is finally fired at 1350-1400°C and kept warm for 3-5 hours.

[0017] The bulk density of the mullite lightweight bricks prepared in Example 1 is 0.75 to 0.80 g / cm 3 , the thermal conductivity is 0.25~0.3w / (m.k), the compressive strength reaches 6.0~6.8MPa, and the reburning line change is 0.9~1.0%.

Embodiment 2

[0019] A lightweight brick made of mullite roller waste as a raw material and a preparation method thereof. First, 60-68wt% of mullite roller bar waste, 19-28wt% of clay clinker, 3-6wt% of α-Al 2 o 3 Micropowder, 2~4wt% ρ-Al 2 o 3 Mix micropowder, 2-3wt% silicon micropowder and 4-6wt% kyanite micropowder, add 30-40wt% water and 0.2-0.3wt% sodium tripolyphosphate, mix for 8-15 minutes, and prepare a slurry , and then add 0.2-0.3wt% foaming agent to make the foam, mix it evenly, cast it, dry it at room temperature for 10-16 hours, and then dry it at 110-120°C for 5-7 hours to release the mold. Finally, it is fired under the condition of 1400-1450°C and kept for 5-7 hours.

[0020] The bulk density of the mullite lightweight bricks prepared in Example 2 is 0.74~0.76g / cm 3 , the thermal conductivity is 0.24~0.28w / (m.k), the compressive strength reaches 5.8~6.2MPa, and the reburning line change is 0.98~1.0%.

Embodiment 3

[0022] A lightweight brick made of mullite roller waste as a raw material and a preparation method thereof. First, 68-74wt% of mullite roller bar waste, 15-19wt% of clay clinker, 6-8wt% of α-Al 2 o 3 Micropowder, 4~6wt% ρ-Al 2 o 3 Mix micropowder, 0.1-2wt% silicon micropowder and 0.1-4wt% kyanite micropowder, add 10-20wt% water and 0.2-0.3wt% sodium lignosulfonate, mix for 3-8 minutes, and prepare the material Slurry, and then add 0.1-0.2wt% foaming agent to make foam, mix evenly, pour into molding, dry at room temperature for 16-20 hours, and then dry at 100-110°C for 7-10 hours to release the mold , and finally fired at 1450-1500°C and kept for 7-12 hours.

[0023] The bulk density of the mullite lightweight bricks prepared in Example 3 is 0.78~0.82g / cm 3 , the thermal conductivity is 0.26~0.3w / (m.k), the compressive strength reaches 6.3~6.8MPa, and the reburning line change is 0.9~1.0%.

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Abstract

The invention specifically relates to a lightweight brick using mullite roller bar waste as a raw material and a preparation method thereof. The technical scheme adopted is: first mix 50~74wt% of mullite roller bar waste, 15~40wt% of clay clinker, 0.1~8wt% of α-Al2O3 micropowder, 0.1~5wt% of SiO2 micropowder, 0.1~ Mix 9wt% kyanite powder with 0-6wt% ρ-Al2O3 powder or 0-5wt% cement powder, add 10-40wt% water and 0.1-0.3wt% water reducer, mix for 3-15 minutes , modulated into a slurry, and then add 0.1-0.3wt% foaming agent to form a foam, mix evenly, cast and mold, dry at room temperature for 4-20 hours, and then dry at 100-120°C for 3-3 hours Release the mold after 10 hours, and finally fire it at 1350-1500°C, and keep it warm for 3-12 hours. The invention adopts the foam method, has simple production technology, less environmental pollution and low energy consumption; the produced product has higher strength, lower bulk density and thermal conductivity.

Description

technical field [0001] The invention belongs to the technical field of lightweight brick refractory materials, and in particular relates to a lightweight brick using mullite roller bar waste as a raw material and a preparation method thereof. Background technique [0002] With the extensive use of mullite rollers, the amount of leftovers and fracture losses after processing and cutting has also increased sharply. A large amount of mullite roller waste is no longer a problem that can be solved simply by landfilling, and with the increasing economic development and social progress, the environment has become the focus of people's attention, and the accumulation of mullite roller waste occupies land , affects the dust content of the local air, and the landfill of mullite roller waste consumes manpower and material resources, and also pollutes groundwater quality. How to turn waste into treasure and waste into resources has become a top priority for science and technology and en...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/66C04B35/185
Inventor 赵雷瞿为民李远兵李亚伟吴清顺黄凯李绍康冯斌李淑静金胜利桑绍柏
Owner WUHAN UNIV OF SCI & TECH
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