Method for preparing nano-crystal cellulose II by using basic anion-exchange resin

A technology of ion exchange resin and basic anion, which is applied in the field of preparation of nanocrystalline cellulose, can solve the problems of difficult control of cellulose degradation, large amount of acidic waste liquid, and large environmental pollution, and achieve good catalytic activity and equipment Less corrosive and less environmental pollution

Inactive Publication Date: 2010-07-07
FUJIAN AGRI & FORESTRY UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

On the other hand, its biodegradability and renewability are unmatched by other materials.
[0003] At present, the preparation of nanocellulose crystals reported in the literature mainly adopts strong acid hydrolysis such as sulfuric acid, which is not easy to control the degree of cellulose degradation, and is more corrosive to equipment, and post-processing will produce a large amount of acidic waste liquid, causing great environmental pollution.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] Example 1 Weigh 2 g of microcrystalline cellulose, add it to 250 ml of deionized water at a ratio of 1:10 with basic styrene-based anion exchange resin, stir and sonicate for 3 hours at 50°C. After the catalytic hydrolysis is completed, the ion exchange resin is filtered out, and the cellulose sample is separated, and then the sample is further separated and purified under high-speed centrifugation at 12000r / min. The milky white colloid that appears is nanocrystalline cellulose II.

Embodiment 2

[0015] Example 2 Weigh 2g of cotton linters, dissolve it in 250ml of NaOH aqueous solution, mix it with basic acrylic anion exchange resin at a ratio of 1:8, and treat it with microwave for 1h. After the catalytic hydrolysis is completed, the ion exchange resin is filtered out, and the cellulose sample is separated, and then the sample is further separated and purified under high-speed centrifugation at 12000r / min. The milky white colloid that appears is nanocrystalline cellulose II.

Embodiment 3

[0016] Example 3 Weigh 2g of microcrystalline cellulose, add 250ml of ZnCl to it and basic vinylpyridine anion exchange resin in a ratio of 1:8 ２ In the aqueous solution, stir and sonicate for 2.5 hours at 60°C. After the catalytic hydrolysis is completed, the ion exchange resin is filtered out, and the cellulose sample is separated, and then the sample is further separated and purified under high-speed centrifugation at 10,000r / min. The milky white colloid that appears is nanocrystalline cellulose II.

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Abstract

The invention relates to a method for preparing nano-crystal cellulose II by using basic anion-exchange resin. The method comprises steps of: adding fibers and ion exchange resin into a solvent to obtain a suspension; performing agitation, ultrasound or microwave radiation processing to the suspension; then further performing the ultrasonic dispersion processing to filter out the ion exchange resin and obtain a fiber suspension after separation; and finally obtaining the nano-crystal cellulose II through further high-speed centrifugal purification to the fiber suspension. The invention takes basic anion-exchange resin as an alkaline catalyst that can dissociate OH- from the solution, overcomes disadvantages of liquid alkali reaction, can be used repeatedly, has little corrosion to equipment, excellent catalytic activity, wide temperature range for use, can work normally under different pH values, and has the advantages of slight degrade damage to the cellulose and less environmental pollution.

Description

technical field [0001] The present invention relates to a method for preparing nanocrystalline cellulose, and more particularly relates to a method for preparing nanocrystalline cellulose II by using basic cation exchange resin. Background technique [0002] Cellulose is the most abundant natural polymer material in nature, and the development of renewable cellulose resources has important strategic significance under the current situation. As a natural polymer compound, cellulose has limitations in performance such as limited strength, which limits its application range. If it is prepared into nanomaterials, its performance can be optimized to a certain extent. Manipulating cellulose molecules and their supramolecular aggregates in the nanoscale range, designing and assembling stable multiple patterns, and creating new nano fine chemicals and new nano materials with excellent functions have become the frontier of cellulose science. Nanoscale crystalline cellulose and amorp...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08B15/08
Inventor 唐丽荣黄彪欧文李涛陈燕丹陈学榕戴达松
Owner FUJIAN AGRI & FORESTRY UNIV
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