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Top-blown bath antimony smelting method and bath smelting furnace

A molten pool smelting furnace and molten pool smelting technology, applied in the field of metal antimony smelting, can solve the problems of difficult control, high cost of flue gas treatment, no industrial application, etc., achieve continuous and stable production, solve environmental problems, and strengthen smelting The effect of the process

Inactive Publication Date: 2010-07-07
TAOJIANG JIUTONG ATIMONY IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The main disadvantages of the blast furnace process are: simple process, backward equipment, difficult flue gas treatment, and serious pollution
Due to the use of side blowing, part of the melt in the molten pool is blown into the smoke and mixed with the antimony oxygen powder, resulting in poor quality of the produced antimony oxygen powder, which cannot be further processed in the subsequent process, so this method cannot be used. Industrial production, ultimately unsuccessful
On the other hand, the smelting method is still a periodic production rather than a stable continuous production. The concentration of sulfur dioxide in the flue gas fluctuates greatly and the average concentration is low. It is difficult to control the production of sulfuric acid from the flue gas, and the cost of flue gas treatment is high.
Due to the large investment of the molten pool smelting method, and the small production scale of antimony industry enterprises, etc., the molten pool smelting of antimony has not been used industrially at home and abroad until now.

Method used

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  • Top-blown bath antimony smelting method and bath smelting furnace
  • Top-blown bath antimony smelting method and bath smelting furnace
  • Top-blown bath antimony smelting method and bath smelting furnace

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Depend on figure 2 As can be seen, a kind of melting pool smelting furnace adopting the above method comprises a body of furnace 6, the depth of the molten pool 1 of the body of furnace 6 is 1500mm-2000mm, and the upper part of the body of furnace 6, that is, the top of the furnace, is provided with a charging port 2 and is used for adding fuel, The spray gun 3 of oxygen-enriched air; the flue 4 is arranged on the top of the furnace body 6, and the bottom of the furnace body 6 is provided with a slag discharge port 7.

[0019] Depend on figure 1 It can be seen that a method for smelting antimony in a top-blown molten pool comprises the following steps: (1) stock preparation: the antimony ore grade contains antimony ≥ 20% (the present embodiment contains antimony 35%, and controls moisture content 10%), iron ore Stone grade contains iron 35%-60% (present embodiment is iron-containing 55%), limestone contains calcium oxide 30%-65% (present embodiment is containing calci...

Embodiment 2

[0028] In the present invention, in the step (1), the powder into the furnace is lead-antimony ore, containing 21% antimony and 25% lead, and controlling the water content of the material to be 9.5%;

[0029] In the present invention in step (2), batching is based on 100 parts of antimony ore weight, by iron ore: limestone: lump coal is 32: 15: 5 batching;

[0030]In step (3) of the present invention, the depth of the molten pool 1 is controlled at 1800mm, the melting temperature is controlled at 1280°C, pulverized coal and 50% oxygen-enriched air are sprayed into the molten pool 1 by the spray gun 3; the depth of the spray gun head inserted into the melt 5 300mm, nozzle pressure 0.20MPa.

[0031] Continuous trial production, the smelting atmosphere in the furnace is controlled to be neutral, and the slag generated in the molten pool is released continuously; the flue gas SO 2 The concentration reaches 11%, which is used to produce industrial concentrated sulfuric acid; the m...

Embodiment 3

[0038] In the present invention, in step (1), the furnace charge is antimony ore powder, containing 28% antimony, controlling the water content of the material to 9.8%, and the iron ore grade containing 46% iron;

[0039] In the present invention in step (2), batching is based on 100 parts of antimony ore weight, by iron ore: limestone: lump coal is 55: 21: 3 batching;

[0040] In step (3) of the present invention, the depth of molten pool 1 is controlled at 1700mm, the melting temperature is controlled at 1250°C, and the calorific value is 4606kJ / Nm 3 Gas and 60% oxygen-enriched air are sprayed into the molten pool 1 by the spray gun 3;

[0041] Continuous production, the smelting atmosphere in the furnace is controlled to be neutral, and the slag generated in the molten pool is released continuously; the flue gas SO 2 The concentration reaches 7.6%, which is used to produce industrial concentrated sulfuric acid; the antimony oxygen powder contains antimony ≥ 80%, and the an...

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PUM

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Abstract

The invention discloses a top-blown bath smelting antimony method which is characterized by comprising the following steps of: preparing materials, dosing the materials, smelting, collecting dust and discharging dregs. The bath smelting furnace adopting the method is characterized in that the depth of a bath (1) of a furnace body (6) is 1500mm to 2000mm; the upper part of the furnace body (6), namely a furnace top is provided with a feeding hole (2) and a spray gun (3) for feeding fuel and oxygen-enriched air; a flue (4) is arranged at the top of the furnace body (6); and the bottom of the furnace body (6) is provided with a dregs discharge hole (7). In the invention, the production can be continuously stable, the smelting process is strengthened, the production efficiency is high, the quality of antimony oxide powder is good, fuel can be used for preparing industrial concentrated sulfuric acid so as to thoroughly solve the environment protection problems, coke is replaced by bituminous coal and lump coal so as to reduce the production cost, the adaptability to raw materials is wide, antimony ore of original agents with lower grade can be processed, and the lead antimony ore can be processed.

Description

Technical field: [0001] The invention relates to a metal antimony smelting method, in particular to a method for smelting antimony in a top blowing molten pool and a molten pool melting furnace thereof. Background technique: [0002] At present, the large and medium-sized antimony smelting plants in my country basically adopt blast furnace volatilization smelting, reverberatory furnace reduction smelting and refining technologies, all of which have insurmountable shortcomings such as high energy consumption, serious environmental pollution and low labor productivity. As far as smelting antimony is concerned, the blast furnace process is a more advanced process at this stage. The main disadvantages of the blast furnace process are: simple process, outdated equipment, difficult flue gas treatment, and serious pollution. In particular, higher concentrations of oxygen-enriched smelting cannot be used, and flue gas SO 2 The concentration is only 1%-2%, and it cannot be used for...

Claims

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Application Information

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IPC IPC(8): C22B30/02
Inventor 陈正于春胜龚小平张卫华龚照青
Owner TAOJIANG JIUTONG ATIMONY IND
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