Bi-component reaction-type flame-retardant waterborne polyurethane and preparation method thereof
A water-based polyurethane, reactive flame-retardant technology, applied in the field of two-component reactive flame-retardant water-based polyurethane and its preparation, can solve the problems of water resistance, solvent resistance, chemical resistance, abrasion resistance, and hardness that cannot reach the solvent level. It can improve the cross-linking density and improve the water resistance.
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Embodiment 1
[0021] The formula of component A is as follows:
[0022] raw material
Mass / g
Toluene diisocyanate
(TDI)
12.88
[0023] raw material
Mass / g
Organophosphorus polyols (hydroxyl value
170mgKOH / g)
19.43
Polyether polyol (PPG, hydroxyl
Value 109-115mgKOH / g)
60.00
Dimethylolpropionic acid (DMPA)
4.86
Triethylamine (TEA)
3.29
Stannous octoate (T9)
0.15
Deionized water
402
[0024] The preparation steps are as follows:
[0025] (1) Add PPG, TDI, DMPA and organophosphorus polyols in the N 2 Reaction under protection until NCO completely disappears (it can be detected by infrared spectroscopy), to obtain a prepolymer;
[0026] (2) be cooled to 40 ℃, adjust prepolymer viscosity with 30g methyl ethyl ketone;
[0027] (3) Dissolve TEA in 402g of deionized water, add it to the prepolymer, immediately carry out emulsification and n...
Embodiment 2
[0031] The formula of component A is as follows:
[0032] raw material
Mass / g
Isophorone diisocyanate
(IPDI)
42.61
Halogenated polyols (hydroxyl value
428mgKOH / g)
54.48
[0033] raw material
Mass / g
Polyester polyol (PEA, hydroxyl
Value 105-115mgKOH / g)
60.00
Dimethylolpropionic acid (DMPA)
7.78
Triethylamine (TEA)
5.28
Stannous octoate (T9)
0.23
Deionized water
484
[0034] The preparation steps are as follows:
[0035] (1) Add PEA, IPDI, DMPA and halogen-containing polyols sequentially in a four-necked flask equipped with a stirrer, a reflux condenser, and a thermometer in N 2 Reaction under protection until NCO completely disappears (it can be detected by infrared spectroscopy), to obtain a prepolymer;
[0036] (2) be cooled to 40 ℃, regulate prepolymer viscosity with 40g methyl ethyl ketone;
[0037] (3) Dissolve T...
Embodiment 3
[0041] The formula of component A is as follows:
[0042] raw material
Mass / g
Diphenylmethane diisocyanate
(MDI)
32.32
Organophosphorus polyols (hydroxyl value
170mgKOH / g)
12.31
Polyether polyol (PPG, hydroxyl
Value 109-115mgKOH / g)
60
[0043] raw material
Mass / g
Halogenated polyols (hydroxyl value
428mgKOH / g)
12.31
Dimethylolpropionic acid (DMPA)
6.15
Triethylamine (TEA)
4.17
(T12)
0.21
Deionized water
467
[0044] The preparation steps are as follows:
[0045] (1) Add PPG, TDI, DMPA and organophosphorus polyols and halogen-containing polyols sequentially in a four-necked flask equipped with a stirrer, a reflux condenser, and a thermometer, and react under N2 protection until NCO completely disappears (infrared spectroscopy can be used to detect It detects), obt...
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