Method of treating proppants and fractures in-situ with fluorinated silane
A technology of fluorinated silane and proppant, which is applied in the field of fracturing underground geological formations containing hydrocarbons, and can solve the problems of increasing density, adverse effects, etc.
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[0151] Usable fluorine-containing urethane oligomers can be prepared, for example, by reacting at least one polyfunctional isocyanate with at least one polyol and subsequently reacting the resulting oligomer with at least one fluorinated monoalcohol and At least one silane reacts. Exemplary reaction conditions, polyfunctional isocyanates, fluorochemicals, fluoromonoalcohols, silanes, and water solubilizing compounds are described in US Patent No. 6,646,088 (Fan et al.).
[0152] In the formula -O-Z-Rf 2 In some examples represented, Rf 2 is the monovalent perfluoroalkyl group described above for Rf in the examples of compounds represented by formula I.
[0153] Formula-O-Z-Rf 2 The divalent organic linker Z in can be a linear, branched or cyclic structure, which can be saturated or unsaturated and optionally contains one or more hetero compounds selected from sulfur, oxygen and nitrogen atoms, and / or optionally contain one or more functional groups selected from ester, ami...
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