Preparation method of modified bentonite particle retention aid for papermaking

A technology of bentonite and retention aids, which is applied in the fields of chemical industry and papermaking industry. It can solve the problems of inability to dehydrate by extrusion, low content of active ingredients, and difficult separation of impurities, so as to improve drying efficiency, increase content of active ingredients, and reduce production costs. Effect

Inactive Publication Date: 2011-04-13
SHAANXI UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But this modification method has the following disadvantages: one, the densities of natural bentonite and impurities such as fine sand are basically the same, and they are insoluble in water, so the separation of impurities is difficult, resulting in low active ingredient content; two, bentonite is modified by sodium After curing, the bentonite becomes a hydrated state and becomes a gel. Although impurities are easy to precipitate and separate at this time, the concentration of bentonite after sodium modification is generally only below 20%, and it cannot be dehydrated by extrusion. If it is directly dried, very high cost

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] 1) First, mechanically pulverize the mined natural bentonite to below 200 mesh, then disperse in water, wash and screen to remove impurities;

[0014] 2) Next, adjust the mass concentration of the bentonite suspension to 1%, then add a sulfuric acid solution that is 1% relative to the mass of the bentonite, and react at 80° C. for 4 hours. After the reaction is completed, separate and remove the precipitated impurities;

[0015] 3) Then, repeatedly washing and extruding the separated bentonite suspension to a pH value of 5 after extrusion dehydration;

[0016] 4) Finally, directly carry out dilution and sodium modification, or first dry, then dilute and sodium modification;

[0017] Said sodium modification process: dilute and disperse the bentonite after the acidification treatment with water to a mass concentration of 0.1%, then add 0.5% sodium carbonate relative to the mass of the bentonite, and react for 7 hours at 20°C. After the reaction, the The bentonite suspen...

Embodiment 2

[0019] 1) First, mechanically pulverize the mined natural bentonite to below 200 mesh, then disperse in water, wash and screen to remove impurities;

[0020] 2) Next, adjust the mass concentration of the bentonite suspension to 10%, and then react at 40°C for 10 hours with respect to a 5% hydrochloric acid solution with a mass of bentonite, and separate and remove the precipitated impurities after the reaction is completed;

[0021] 3) Then, repeatedly washing and extruding the separated bentonite suspension to a pH value of 6.5 after extrusion dehydration;

[0022] 4) Finally, directly carry out dilution and sodium modification, or first dry, then dilute and sodium modification;

[0023] Said sodium modification process: dilute and disperse the acidified bentonite with water to a mass concentration of 20%, then add 2% sodium hydroxide relative to the mass of bentonite, react at 50°C for 5 hours, and after the reaction, The bentonite suspension is diluted to a mass concentrat...

Embodiment 3

[0025] 1) First, mechanically pulverize the mined natural bentonite to below 200 mesh, then disperse in water, wash and screen to remove impurities;

[0026] 2) Next, adjust the mass concentration of the bentonite suspension to 20%, then add a nitric acid solution that is 10% relative to the mass of the bentonite, and react at 100° C. for 2 hours. After the reaction, separate and remove the precipitated impurities;

[0027] 3) Then, repeatedly washing and extruding the separated bentonite suspension to pH 3 after extrusion dehydration;

[0028] 4) Finally, directly carry out dilution and sodium modification, or first dry, then dilute and sodium modification;

[0029] Said sodium modification process: dilute and disperse the bentonite after the acidification treatment with water to a mass concentration of 50%, then add 5% sodium chloride relative to the mass of the bentonite, and react for 3 hours at 80°C. After the reaction, The bentonite suspension is diluted to a mass conce...

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PUM

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Abstract

The invention relates to a preparation method of a modified bentonite particle retention aid for papermaking, comprising the following steps of: mechanically pulverizing mined natural bentonite into particles below 200 meshes, then dispersing the pulverized bentonite in water, and washing and sieving to remove impurities; adding an acid solution into bentonite suspension for reacting and then separating to remove the precipitated impurities; extruding and dehydrating the separated bentonite suspension, repeatedly washing and extruding until the pH value is 3-6.5; and finally, diluting and dispersing bentonite subjected to acidization with water, adding sodium salt for reacting and then diluting the bentonite suspension until the mass concentration is 0.01-5% to obtain the modified bentonite particle retention aid. In the invention, the adopted two-step modification method can be used for favorably removing the impurities in the bentonite so as to improve the content of the active ingredients in the bentonite, and in addition, the extrusion and dehydration treatment can be carried out before drying so as to improve drying efficiency and reduce production cost. The method benefits the improvement of the quality of the bentonite particle retention aid and use effect of the same in papermaking.

Description

technical field [0001] The invention belongs to the fields of chemical industry and papermaking industry, and in particular relates to a preparation method of a modified bentonite particulate retention aid for papermaking. Background technique [0002] In 1986, Langley, Litchfield and others studied the use of bentonite particles in the wet end of papermaking, marking the emergence of particle retention and drainage systems. This system has a very good retention and drainage effect on paper materials. Therefore, it has been rapidly promoted once it appeared. At present, most modern paper machines at home and abroad use this retention and drainage system. In this retention and drainage system, the modification method of the bentonite particulate retention aid is as follows: the natural bentonite is first washed with water, screened, and impurities are removed to increase the content of the active ingredient montmorillonite in the bentonite, and then, use sodium hydroxide or ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21H21/10
Inventor 夏新兴耿秀娟刘峰王建李佩燚修慧娟
Owner SHAANXI UNIV OF SCI & TECH
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