Method for preparing polyester and polyether modified silicone oil ternary copolymer textile finishing agent

A silicone oil ternary copolymerization fabric and polyether modification technology, which is applied in fiber treatment, textiles and papermaking, etc., can solve the problems of poor fabric hand feeling, unsatisfactory hydrophilicity and durability, and unsatisfactory repairability, etc., to achieve Highly stable effect

Active Publication Date: 2011-04-27
LIAONING KELONG FINE CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The commonly used polyester-polyether multi-block binary copolymer is used in the post-finishing method of fabrics, which makes the fabrics have good hydrophilic and antistatic properties, but the fabrics have poor hand feeling, and then use amino-modified silicone oil emulsion to treat the fabrics. Soft finishing, but its cross-linking with the fabric to form a film is not easy to remove, and the repair performance is not ideal; the patent No. is the polyester polyether polyoxysilane terpolymer fiber disclosed in the CN1069086 patent. The softness and smoothness of polyester fabrics, but the hydrophilicity and durability are found to be unsatisfactory in practice

Method used

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  • Method for preparing polyester and polyether modified silicone oil ternary copolymer textile finishing agent
  • Method for preparing polyester and polyether modified silicone oil ternary copolymer textile finishing agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] Allyl polyether uses the azeotrope of toluene and water to remove moisture and the silicone oil is dried with anhydrous magnesium sulfate, then add 720 grams of allyl polyether as the reaction raw material in a 2L reactor, with a hydrogen content of 0.10%-0.20% 33.6 grams of hydrogen-containing silicone oil, 264 grams of solvent toluene, and 150 ppm of isopropanol solution of chloroplatinic acid as a catalyst were heated to 120° C. under a nitrogen atmosphere, stirred evenly, and kept for 4 hours for reaction. Toluene and low boilers were distilled off at a vacuum of 0.09 Ma to obtain a transparent viscous liquid which was polyether modified silicone oil.

[0016] Add 144 grams of dimethyl terephthalate into a 2L reaction kettle, raise the temperature to 150°C, and after the dimethyl phthalate is completely dissolved, add 320 grams of ethylene glycol, and add a transesterification catalyst of manganese acetate and di 1 gram of compound of antimony is heated up to 190 DE...

Embodiment 2

[0018] Allyl polyether uses the azeotrope of toluene and water to remove moisture and the silicone oil is dried with anhydrous magnesium sulfate, then add 720 grams of allyl polyether as the reaction raw material in a 2L reactor, with a hydrogen content of 0.10%-0.20% 33.6 grams of hydrogen-containing silicone oil, 264 grams of solvent toluene, and 150 ppm of catalyst chloroplatinic acid isopropanol solution were heated to 140° C. under nitrogen atmosphere, stirred evenly, and kept for 2.5 hours for reaction. Toluene and low boilers were distilled off at a vacuum of 0.09 Ma to obtain a transparent viscous liquid which was polyether modified silicone oil.

[0019] Add 144 grams of dimethyl terephthalate into a 2L reaction kettle, raise the temperature to 140°C, and after the dimethyl phthalate is completely dissolved, add 320 grams of ethylene glycol, and add manganese acetate and di 1 gram of compound of antimony is heated up to 200 ℃ with the speed of 1 ℃ / min, carries out tra...

Embodiment 3

[0021] Allyl polyether uses the azeotrope of toluene and water to remove moisture and the silicone oil is dried with anhydrous magnesium sulfate, then add 720 grams of allyl polyether as the reaction raw material in a 2L reactor, with a hydrogen content of 0.10%-0.20% 33.6 grams of hydrogen-containing silicone oil, 264 grams of toluene as a solvent, and 150 ppm of isopropanol solution of chloroplatinic acid as a catalyst were heated to 130° C. under a nitrogen atmosphere, stirred evenly, and kept for 3 hours for reaction. Toluene and low boilers were distilled off at a vacuum of 0.09 Ma to obtain a transparent viscous liquid which was polyether modified silicone oil.

[0022] Add 144 grams of dimethyl terephthalate into a 2L reactor, heat up to 160°C, and after the dimethyl phthalate is completely dissolved, add 320 grams of ethylene glycol, and add manganese acetate and di 1 gram of compound of antimony is heated up to 180 ℃ with the speed of 1 ℃ / min, carries out transesterif...

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PUM

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Abstract

The invention relates to a method for preparing a polyester and polyether modified silicone oil ternary copolymer textile finishing agent, and belongs to the field of the synthesis of ternary copolymer synthetic fiber finishing agents. The method comprises the following steps of: performing a hydrosilylation reaction of allyl polyether and hydrogen-containing silicone oil under the action of a chloroplatinic acid catalyst to form polyether modified silicone oil; and performing a polycondensation reaction of the polyether modified silicone oil and dimethyl terephthalate, glycol and polyethylene glycol under the action of antimonous oxide, manganese acetate, n-tetrabutyl titanate and triphenyl phosphate to obtain the polyester and polyether modified silicone oil ternary copolymer multifunctional textile finishing agent. The textile finishing agent can make textiles very absorbent, antistatic and washable and touch very soft.

Description

technical field [0001] The invention relates to a preparation method of a terpolymerized synthetic fiber finishing agent, in particular to a polyester and polyether modified organic silicone oil terpolymerized fabric finishing agent. Background technique [0002] Polyester fiber has excellent properties that many natural fibers cannot match, and is currently the most widely used type of synthetic fiber. However, the shortcomings of poor hygroscopicity, easy to be charged with static electricity, easy to absorb dirt, and poor hand feel limit the use of polyester fibers. In the development process of polyester fiber, people use fiber synthesis technology to modify polyester fiber and use fabric finishing technology to finish polyester fiber fabric, which improves the performance of polyester fiber. The commonly used polyester-polyether multi-block binary copolymer is used in the post-finishing method of fabrics, which makes the fabrics have good hydrophilic and antistatic pro...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M15/647C08G63/695C08G81/00C08G77/38
Inventor 李红敏姜艳韩旭
Owner LIAONING KELONG FINE CHEM
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