High-voltage lithium ion battery anode, lithium ion battery using same and preparation method of high-voltage lithium ion battery anode
A lithium-ion battery, high-voltage technology, applied in battery electrodes, secondary batteries, circuits, etc., can solve the problems of low specific energy of lithium-ion battery cathode and low discharge voltage platform, and achieve easy large-scale industrial production and discharge voltage. The effect of high platform and high specific energy
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[0047] The preparation method of the positive electrode is
[0048] Disperse the binder evenly in the solvent first,
[0049] Then make a mixture of the positive electrode active material and the conductive agent, add it into a container with an inert atmosphere of nitrogen or argon, and ball mill it. After it is fully ground and mixed uniformly, add it to the solvent, and mix it evenly to obtain a slurry. The obtained slurry is coated on the aluminum foil of the current collector, dried, rolled, and cut to obtain the above-mentioned positive electrode.
[0050] The solvent is N-methylpyrrolidone.
[0051] The lithium-ion battery provided in this embodiment includes a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, an electrolyte, and a battery casing. The separator is polyethylene, polypropylene or a composite film of polyethylene and polypropylene, which is inserted between the positive electrode a...
Embodiment 1
[0060] This embodiment is used to prepare the positive electrode of the high-voltage lithium-ion battery of this embodiment
[0061] By mass percentage, 91% of the positive electrode active material LiNi 0.5 mn 1.5 o 4 / C, 2.5% super conductive carbon black, 2.5% super conductive graphite, 4% binder polyvinylidene fluoride, using N-methylpyrrolidone as a solvent, first uniformly disperse the binder in the solvent; then The conductive agent and the positive electrode active material are mixed and stirred evenly, then dispersed in the solvent, stirred, and mixed uniformly to form a slurry. Using 19 μm thick aluminum foil as a current collector, evenly coat the slurry on the aluminum foil, control the temperature at 125°C and dry for 8 hours, and the coating surface density of the positive electrode is 31mg / cm 2 .
[0062] The pole pieces were rolled and dried in an inert argon atmosphere at 115° C. for 12 hours, and then cut to make positive electrodes.
Embodiment 2
[0064] This embodiment is used to prepare the positive electrode of the high-voltage lithium-ion battery of this embodiment
[0065] By mass percentage, 86% of the positive electrode active material LiNi 0.5 mn 1.5 o 4 / C material, 3.75% superconducting carbon black, 3.75% conductive graphite, 6.5% binder polyvinylidene fluoride, using N-methylpyrrolidone as a solvent, first uniformly disperse the binder in the solvent; then The conductive agent and the positive electrode active material are mixed and stirred evenly, then dispersed in the solvent, stirred, and mixed uniformly to form a slurry. A 25 μm thick aluminum foil was used as a current collector, the slurry was coated on the aluminum foil, and the temperature was controlled at 125° C. for 8 h. The coated surface density of the positive electrode is 26 mg / cm 2 .
[0066] The pole pieces were rolled and dried at 110° C. for 12 hours under an inert nitrogen atmosphere, and then cut to make positive electrodes.
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