Desulfurization and demercuration method for flue gas

A flue gas and mercury removal technology, applied in the field of environmental pollution control, can solve the problems of insignificant desulfurization effect and high regeneration cost of mercury removal by-products, and achieve the effects of good absorption effect, large specific surface area and strong adsorption capacity

Inactive Publication Date: 2011-07-06
CHINESE RES ACAD OF ENVIRONMENTAL SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] At present, there are also methods of using bromine-loaded activated carbon and semi-coke to remove mercury from flue gas, but these methods have no obvious effect on desulfurization, and the regeneration cost of mercury removal by-products is relatively high.

Method used

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  • Desulfurization and demercuration method for flue gas
  • Desulfurization and demercuration method for flue gas
  • Desulfurization and demercuration method for flue gas

Examples

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Embodiment 1

[0031] A 50MW coal-fired unit boiler, the boiler load is 188t / h, the sulfur content of coal combustion is 0.5%, and the mercury content of coal combustion is 0.11mg / kg. The flue gas temperature at the outlet is 139.9°C, and the flue gas volume is 234000-236000Nm 3 / h, flue gas SO 2 The concentration is 920mg / Nm 3 . Dry flue gas desulfurization and dust removal using steam to transport desulfurizers and auxiliary desulfurizers, the temperature of the flue gas after desulfurization and dust removal is 76-79°C, and the SO 2 The concentration is 89mg / Nm 3 , using this method can remove about 98.6% of the mercury vapor in the flue gas, and the mercury content in the desulfurization ash can reach 1.58mg / kg.

[0032] The physical and chemical properties of the desulfurization ash changed significantly after steam delivery, and a part of CaO was transformed into porous Ca(OH) 2 , improve the adsorption capacity of desulfurization ash to mercury. The BET specific surface area of ...

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Abstract

The invention provides a novel desulfurization and demercuration method for flue gas. In the method, lime / Ca(OH)2 is adopted as a desulfurizing agent; recycling flue gas desulfurization residue is adopted as an auxiliary desulfurizing agent; water mist is sprayed into a flue in advance; the flue gas is cooled and enters a desulfurizing tower, and simultaneously the lime / Ca(OH)2 desulfurizing agent is fed into the desulfurizing through a steam conveyer to be mixed with the flue gas; the SO2 in the flue gas reacts with the lime / Ca(OH)2; and simultaneously the lime / Ca(OH)2 desulfurizing agent has strong adsorbability on hydrargyrum after steam conveying, so that the desulfurization and demercuration of the flue gas are realized. The flue gas desulfurization residue collected by the desulfurizing tower and a bag type dust collector is conveyed to a desulfurizing agent inlet through the steam conveyer to be mixed with the flue gas, and enters the desulfurizing tower once again; after the flue gas is subjected to the desulfurization and the demercuration, the generated desulfurization residue is collected through the bag type dust collector; and the purified flue gas is discharged from a chimney through an induced draft fan. By utilizing the technology, higher removal rate on SO2 and mercury steam is achieved, Pb and other heavy metals can be removed at the same time, and the operation cost is lower; and the side product flue gas desulfurization residue can be directly recycled, and does not cause secondary pollution.

Description

technical field [0001] The invention relates to a method for flue gas desulfurization and mercury removal, which belongs to the technical field of environmental pollution control. Background technique [0002] Coal is the main primary energy source in China at this stage, and the growth of coal consumption has led to SO 2 Emissions continue to climb rapidly, each year due to acid rain and SO 2 Pollution has caused massive economic losses to the ecological environment and human health, and the problem of emission reduction needs to be solved urgently. The coal burning process not only emits sulfur dioxide and nitrogen oxides, but also emits other pollutants such as mercury. Most of the mercury in the coal combustion process enters the flue gas and is emitted into the atmosphere, becoming an important source of mercury in the atmosphere. Mercury is one of the main harmful heavy metal elements. Although the amount is small, it can accumulate in the environment after burning ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/83B01D53/50B01D53/64B01D46/02
Inventor 王凡张凡王红梅朱金伟刘宇田刚石应杰林军
Owner CHINESE RES ACAD OF ENVIRONMENTAL SCI
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