Acrylonitrile-chlorinated polyethylene-styrene resin composition and preparation method of acrylonitrile-chlorinated polyethylene-styrene resin composition

A technology of chlorinated polyethylene and styrene resin, applied in the field of resin composition and its preparation, can solve the problem that weather resistance and low temperature resistance cannot be satisfied at the same time, achieve excellent weather resistance, high low temperature impact resistance, improve rigidity and toughness Effect

Active Publication Date: 2013-06-26
SHANGHAI KUMHO SUNNY PLASTICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

"Although the product obtained by this patent has good weather resistance, it cannot meet the requirements of weather resistance and low temperature resistance at the same time.

Method used

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  • Acrylonitrile-chlorinated polyethylene-styrene resin composition and preparation method of acrylonitrile-chlorinated polyethylene-styrene resin composition
  • Acrylonitrile-chlorinated polyethylene-styrene resin composition and preparation method of acrylonitrile-chlorinated polyethylene-styrene resin composition
  • Acrylonitrile-chlorinated polyethylene-styrene resin composition and preparation method of acrylonitrile-chlorinated polyethylene-styrene resin composition

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] Add 30Kg of SAN resin 2, 43Kg of methyl methacrylate, 10Kg of polymer containing silicone rubber, 4Kg of compatibilizer, and 3Kg of antioxidant into a high-speed mixer and stir for 20 minutes before discharging to obtain mixture A.

[0057] Add mixture A from the main feeding port of the twin-screw extruder, mix 5Kg light absorber and 5Kg light stabilizer first, then add it from the side feeding port of the twin-screw extruder, extrude and granulate to obtain weather-resistant masterbatch , the barrel temperature of the extruder is 150-200°C, and the screw speed is 180-600rpm.

[0058] Put 45Kg of ACS resin, 45Kg of SAN resin 1, 0.5Kg of lubricant, 0.3Kg of antioxidant, and 0.8Kg of heat stabilizer into a high-speed mixer, stir for 5-30 minutes, and discharge to obtain mixture B.

[0059] Add mixture B from the main feeding port of the twin-screw extruder, add 10Kg of weather-resistant masterbatch from the side feeding port of the twin-screw extruder, extrude and granul...

Embodiment 2-4

[0061] In order to better reflect the characteristics of the above-mentioned high weather-resistant acrylonitrile-chlorinated polyethylene-styrene resin composition, the present invention uses Examples 2-4, selects the same weather-resistant masterbatch as in Example 1, and compares the weather-resistant masterbatch The impact of different dosages of ACS and ACS resins on product performance, the specific material formulation is shown in Table 1, and the steps are the same as in Example 1.

Embodiment 5

[0076] Add 10Kg of SAN resin 2, 50Kg of methyl methacrylate, 15Kg of polymer containing silicone rubber, 8Kg of compatibilizer, and 3Kg of antioxidant into a high-speed mixer and stir for 20 minutes before discharging to obtain mixture A.

[0077] Add mixture A from the main feeding port of the twin-screw extruder, mix 3Kg light absorber and 6Kg light stabilizer first, then add it from the side feeding port of the twin-screw extruder, extrude and granulate to obtain weather-resistant masterbatch , the barrel temperature of the extruder is 150-200°C, and the screw speed is 180-600rpm.

[0078] Put 30Kg of ACS resin, 50Kg of SAN resin 1, 3Kg of lubricant, 0.05Kg of antioxidant, and 0.5Kg of heat stabilizer into a high-speed mixer and stir for 5-30 minutes before discharging to obtain mixture B.

[0079] Add the mixture B from the main feeding port of the twin-screw extruder, add 15Kg weather-resistant masterbatch from the side feeding port of the twin-screw extruder, extrude and...

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Abstract

The invention discloses an acrylonitrile-chlorinated polyethylene-styrene resin composition and a preparation method of the acrylonitrile-chlorinated polyethylene-styrene resin composition. The composition comprises the following components in part by weight: 30 to 60 parts of acrylonitrile-chlorinated polyethylene-styrene grafting powder, 30 to 50 parts of SAN resin 1, 5 to 15 parts of weather resistance master batch, 0.3 to 3 parts of lubricant, 0.05 to 0.5 part of antioxidant and 0.5 to 1.5 parts of heat stabilizer. The composition is prepared by stirring and mixing the components except for the weather resistance master batch, adding the mixture from a main feed inlet of a double screw extrusion machine, adding the weather resistance master batch from a side feed inlet of the double screw extrusion machine and carrying out extrusion and granulation to obtain a sample. The obtained composition has excellent weather resistance, high low-temperature impact property and good antistatic property, size stability and processing property and is particularly suitable for the field of electrons, electrical appliances, communication, instruments, building materials, decorative materials,automobile parts and the like with high requirements on weather resistance, impact resistance and surface antistatic property.

Description

technical field [0001] The invention relates to a resin composition and a preparation method thereof, in particular to a highly weather-resistant acrylonitrile-chlorinated polyethylene-styrene resin composition and a preparation method thereof. Background technique [0002] Polybutadiene rubber is used in the synthesis of ABS resin, and the unsaturated carbon-carbon double bonds contained in it are easily broken by ultraviolet rays, which will easily cause yellowing and pulverization of ABS resin parts during use. , cracking and other phenomena. ABS resin cannot be directly used in outdoor products, and must undergo surface treatment methods such as spraying and electroplating to improve its weather resistance, but further surface treatment processes are not only time-consuming and laborious, but also cause serious environmental pollution. The application of high pollution processes such as spraying and electroplating will be limited, which requires solving the problem of p...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L51/06C08L25/12C08L33/12C08L51/08C08J3/22B29B9/06B29C47/92B29C48/92
CPCB29C48/04B29C48/40B29C48/92B29C2948/9259B29C2948/92704B29C2948/92885B29C2948/92895
Inventor 邱卫美周赞周霆宋治乾罗明华辛敏琦
Owner SHANGHAI KUMHO SUNNY PLASTICS
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