Composite polycarboxylic acid water reducing agent

A technology for compounding polycarboxylic acid and water reducing agent, which is applied in the field of concrete additives, can solve the problems of restricting the popularization and application of polycarboxylic acid water reducing agent, rough concrete surface, and not very long time, and achieves good pumping construction and water reduction. High rate and good workability

Inactive Publication Date: 2011-11-23
CHINA STATE CONSTR ENG CORP TIANJIN +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Since the polycarboxylate high-performance water reducer is a high-molecular substance, it contains some unreacted active small molecules, while waste engine oil and release agent contain many organic substances, which are easily mixed with the polycarboxylate water reducer. The active small molecules react chemically to form new substances that bond on the surface between the formwork and the concrete. After the concrete mixed with polycarboxylate high-performance water reducer is hardened and the formwork is removed, on the one hand, there are many dense and small air bubbles on the surface of the concrete. On the other hand, the concrete surface is rough due to bonding during formwork removal, which seriously affects the appearance and greatly limits the popularization and application of polycarboxylate superplasticizers.
[0004] Since the application of polycarboxylic acid at home and abroad is not very long, especially in the season with high temperature, the air bubbles on the surface of concrete are more obvious, and there have been no relevant patents and literatures that have a good solution to this.

Method used

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  • Composite polycarboxylic acid water reducing agent
  • Composite polycarboxylic acid water reducing agent
  • Composite polycarboxylic acid water reducing agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] 200kg of modified polyether polycarboxylate high-performance water reducer (solid content 40%, zj-ss-01 polycarboxylate water reducer produced by China Construction Commercial Concrete Co., Ltd. , sodium gluconate 30kg, functional additives 0.1kg (polypropylene glycol ether 0.04kg, polypropylene glycol ether 0.06kg), paraben preservatives (Wuxi Jiangda Baitai Technology Co., Ltd., p-hydroxybenzene Sodium methyl formate) 1.5kg, tap water 768kg, stirred about 20 minutes and made it dissolve into a homogeneous solution, and its prepared solution concentration was 11.16% (solid content) to obtain polycarboxylic acid composite water reducer 1#.

Embodiment 2

[0024] 400kg of ester polycarboxylate high-performance water reducer (20% solid content, zj-ss-02 polycarboxylate water reducer produced by China Construction Commercial Concrete Co., Ltd. 30kg, sodium tripolyphosphate 20kg, functional additives 1kg (polypropylene glycol ether 0.75kg, polypropylene propylene glycol ether 0.25kg), paraben preservatives (Wuxi Jiangda Baitai Technology Co., Ltd., p-hydroxy Sodium methyl benzoate) 2.0kg, tap water 547kg, stir about 20 minutes and make it dissolve into uniform solution, the solution concentration of its preparation is 13.3% (solid content), obtains polycarboxylate composite superplasticizer 2#.

Embodiment 3

[0026] 200 kg of maleic anhydride-based polycarboxylate high-performance water reducer (solid content 40%, zj-ss-03 polycarboxylate water reducer produced by China Construction Commodity Concrete Co., Ltd. Sodium citrate 26kg, borax 4kg, functional additives 0.03kg (polypropylene glycol ether 0.01kg, polypropylene glycol ether 0.02kg), paraben preservative 1.5kg, tap water 790kg, stir for about 20 minutes to make It was dissolved into a uniform solution, and the concentration of the prepared solution was 11.15% (mass), to obtain polycarboxylic acid composite water reducer 3#.

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Abstract

The invention belongs to the technical field of concrete additives, in particular relates to a water reducing agent, and more particularly a composite polycarboxylic acid water reducing agent. The composite polycarboxylic acid water reducing agent is characterized by being prepared from the following components in percentage by mass: 8-28.6 percent of polycarboxylic acid high-performance water reducing agent, 0.5-7.36 percent of inhibiting agent, 0.001-0.15 percent of functional aid, 0.01-0.65 percent of preservative and the balance of water, wherein the total mass percentage of the components is 100 percent. The composite polycarboxylic acid water reducing agent is applied to freshly mixed concrete. After a template coated with waste engine oil or rosinate soap is dismantled, the surface of hardened concrete is smooth, air bubbles are reduced remarkably, and the construction requirement is fully met. By adopting the composite polycarboxylic acid water reducing agent, the problem of a large quantity of air bubbles on the surface of concrete, produced after the use of demolding agents such as waste engine oil or rosinate soap and the like is solved.

Description

technical field [0001] The invention belongs to the technical field of concrete additives, and in particular relates to a water reducer. Background technique [0002] With the construction of large-scale infrastructure in my country, as well as the increasing number of high-speed railways and high-rise and super high-rise buildings, the requirements for concrete water reducing agents are also getting higher and higher, especially some super large projects have higher requirements for appearance , and polycarboxylate superplasticizers are widely used due to their incomparable advantages over traditional superplasticizers. Polycarboxylate superplasticizer has more active groups, large degree of freedom in molecular structure, high water reducing rate and relatively better compatibility with different cements. Even at low dosage, polycarboxylate water reducing The agent can make the concrete have high fluidity, and has low viscosity and slump retention performance at low water-...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/26C04B103/30
Inventor 韩周冰郑广军熊骁辉黄波刘行宇肖宏军纪晓辉沈浩蒋新锋邰伟李东来
Owner CHINA STATE CONSTR ENG CORP TIANJIN
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