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A kind of pull-tab outer cover material for infusion bottle or bag and preparation method thereof

An infusion bottle and pull-ring type technology is applied in the field of modified polypropylene pull-ring type outer cover material for infusion bottles or bags and its preparation field, which can solve the problem of poor welding performance between bottle caps and polypropylene bottle bodies, and the size of the outer cover. Poor stability, the outer cover is not resistant to radiation, etc., to achieve good toughening effect, improve processing fluidity, and easy to open.

Active Publication Date: 2011-12-14
合诚技术股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

On the basis of the inventor's research on the inner cover of the infusion bottle or bag (application number 201010117138.1), further research is carried out on the pull-tab outer cover of the infusion bottle or bag to solve the problem of the existence of the pull-tab outer cover of the infusion bottle or bag. The following problems: (1) The opening force of the pull ring is large, it is not easy to pull open, and the edge is not neat after opening; (2) The toughness of the pull ring is insufficient, and the pull ring is easy to break; (3) Low molecular components are separated out, causing the outer cover Dimensional stability is poor, and the deformation is obvious after high-temperature disinfection. (4) The outer cover is not resistant to radiation, and the yellowing is obvious after radiation disinfection
[0004] The Chinese invention patent with the application number of 200410024446.4 discloses a cap material for infusion bottles prepared by adding polyethylene (PE), polyolefin elastomer (POE) and KN resin to polypropylene resin (PP), so as to improve the compatibility between the cap and polypropylene. The welding performance of the bottle body is not good, the pull ring connection is easy to crack, and it is not easy to open the problem

Method used

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  • A kind of pull-tab outer cover material for infusion bottle or bag and preparation method thereof
  • A kind of pull-tab outer cover material for infusion bottle or bag and preparation method thereof
  • A kind of pull-tab outer cover material for infusion bottle or bag and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] 71 parts by mass of polypropylene (ethylene content is 9% by mass, MI is 5g / 10min at 230°C and 2160g) and radiation resistance additives (7-methoxyrosmanol and tetrakis[methyl -β-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate] pentaerythritol ester is formed by mixing 0.05 parts by mass in a mass ratio of 70:30, and mix well, then add styrene-butadiene- Styrene copolymer (density 0.88g / cm 3 , MI is 6g / 10min at 230°C and 2160g) 9 parts by mass and lubricating resin (by 7 parts by mass of silicone masterbatch (10% by mass percentage of silicone powder and 90% by mass of poly Propylene blending) mixed with 12.95 parts by mass of polytetrafluoroethylene (particle size 400nm)) 19.95 parts by mass, mixed uniformly, then added to the extruder at a speed of 60 rpm at 150 ° C, and extruded at a speed of 300 rpm , water-cooled, granulated, and dried to obtain a pull-tab outer cover material for infusion bottles or bags. The melt index of the pull-tab outer cover material for th...

Embodiment 2

[0046] 75 parts by mass of polypropylene (the ethylene content is 4% by mass, MI is 30g / 10min at 230°C and 2160g) and radiation-resistant additives (7-methoxyrosmanol and β-(3 , 5-di-tert-butyl-4-hydroxyphenyl) n-octadecyl propionate is formed by mixing 90:10 by mass ratio) 0.2 parts by mass are uniformly mixed, and then successively add 50% benzene by mass percentage Ethylene-butadiene-styrene copolymer (density 0.86g / cm 3 , MI at 230°C and 2160g is 5g / 10min) and ethylene butene copolymer (density 0.89g / cm 3 , MI is 18g / 10min under the condition of 230 ℃ and 2160g) total 8 mass parts, and lubricating resin (made of 6 mass parts silicone masterbatch (silicone powder with mass percentage content 10% and mass percentage content 90% Polypropylene blending) mixed with 10.8 parts by mass of polytetrafluoroethylene (particle size 500nm)) 16.8 parts by mass, after mixing uniformly, then added to the extruder at a speed of 60 rpm at 180 ° C, and at a speed of 400 rpm Extruded, water...

Embodiment 3

[0048] 80 parts by mass of polypropylene (ethylene content is 8% by mass, MI is 8g / 10min at 230°C and 2160g) and radiation resistance additives (7-methoxyrosmanol and 3,9- Bis[1,1-dimethyl-2-[(3-tert-butyl-4-hydroxy-5-methylphenyl)propionyloxy]ethyl]-2,4,8,10-tetraoxo Heterospiro[5.5]undecane is formed by mixing 0.3 parts by mass at a mass ratio of 80:20) and mixes uniformly, and then successively add styrene-butadiene-styrene copolymers (density of 0.89 g / cm 3 , at 230°C and 2160g, MI is 8g / 10min) and styrene-ethylene-butylene-styrene copolymer (density 0.87g / cm 3 , MI is 20g / 10min under 230 ℃ and 2160g condition) totally 6 mass parts, and lubricating resin (made of 4 mass parts silicone masterbatch (silicone powder with mass percentage content 10% and mass percentage content 90% Polypropylene blending) mixed with 9.7 parts by mass of polytetrafluoroethylene (particle size 600nm)) 13.7 parts by mass, after mixing uniformly, then added to the extruder at a speed of 80 rpm at...

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Abstract

The invention discloses a pull-tab outer cover material used for infusion bottles or bags, and the material provided by the invention comprises the following components in parts by weight: 71-89 parts of polypropylene, 1-9 parts of flexibilizer, 9-25 parts of lubrication resin and 0.01-0.4 part of radiation-resistant accessory ingredient. The melting index of the pull-tab outer cover material used for infusion bottles or bags is 9-60g / min under the condition of 230DEG C and 2160g, and the outer cover material can be directly injected to prepare the pull-tab outer cover material used for infusion bottles or bags. A cover body and the infusion bottles or bags have high welding strength, a pull tab is easy to open, an opening edge is tidy, and the opening force is less than or equal to 60N; the pull tab has small possibility of being ruptured, and the fracture rate of the pull tab is less than or equal to 1%; no low-molecule ingredients are separated out, the size stability is good, and the size change rate of the outer cover is less than or equal to 0.5% before and after disinfection; and the radiation-resistant performance is good, the yellow index is less than or equal to 7 after the material is radiated by 60Co-gamma ray of 25kGy dose, and the material haze is less than or equal to 20.

Description

technical field [0001] The invention relates to a material for an infusion bottle or a bag, in particular to a modified polypropylene pull-tab outer cover material for an infusion bottle or a bag and a preparation method thereof, belonging to the technical field of medical polymer materials. Background technique [0002] In recent years, my country's large infusion plastic packaging industry has developed rapidly. From 2007 to 2009, the market share of medical infusion plastic packaging products increased from 34% to 56%, and plastic packaging is increasing year by year with a market share of more than 10% per year, replacing traditional glass bottle packaging and becoming my country's large infusion solution. Pharmaceutical packaging market key development trends. [0003] Plastic large infusion packaging includes two types of infusion bottle and infusion soft bag. The infusion bottle is composed of a bottle body, inner and outer covers and rubber pads, and the infusion sof...

Claims

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Application Information

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IPC IPC(8): C08L23/16C08L23/12C08L53/02C08L83/04C08L27/18C08L23/08C08K5/13C08K5/134C08K5/3492A61J1/14
Inventor 官习鹏许永昌游华燕刘永焯诸泉蒋文真
Owner 合诚技术股份有限公司
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