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A kind of preparation method of organic formaldehyde adsorbent

A formaldehyde adsorption, organic technology, applied in the direction of chemical instruments and methods, other chemical processes, etc., can solve the problems of bacteria and viruses in the filter screen, inconvenient for ordinary customers, increased air humidity, etc., achieve good purification and removal effect, easy to industrialize The effect of high production and production efficiency

Inactive Publication Date: 2011-12-21
邯郸派瑞电器有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, according to the good solubility of formaldehyde in water, some manufacturers use water washing to purify formaldehyde. Although the short-term effect is better, there are also some unfavorable factors. Bacteria, viruses, etc.
There is also a formaldehyde scavenger, which uses the chemical activity of formaldehyde to spray on the surface of furniture or in the air to eliminate and capture formaldehyde, but this formaldehyde scavenger may cause secondary pollution
It is mostly used by some air treatment companies, and it is inconvenient for ordinary customers who have already moved in or used furniture

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Measure 10 ml of polymethyl acrylate macroporous resin (wet material), put it into 100 ml of sodium hydroxide aqueous solution with a mass concentration of 10%, heat to boiling, and reflux for 10 hours for hydrolysis.

[0024] Take out the resin, wash it with deionized water until neutral, put the resin into 50ml of diethylenetriamine, heat to 80°C, and fully react for 5 hours to make a formaldehyde adsorbent. After testing, the saturated adsorption capacity of the obtained formaldehyde adsorbent sample to formaldehyde is 2.85mmol / g.

Embodiment 2

[0026] Measure 10ml of polymethyl methacrylate macroporous resin (wet material), put it into a sulfuric acid solution with a volume of 100ml and a mass concentration of 8%, heat to boiling, and reflux for 5 hours for hydrolysis.

[0027] Take out the resin, wash it with deionized water until neutral, put the resin into 50ml of diethylenetriamine, heat to 80°C, and fully react for 5 hours to make a formaldehyde adsorbent. After testing, the saturated adsorption capacity of the obtained formaldehyde adsorbent sample to formaldehyde was 2.12 mmol / g.

Embodiment 3

[0029] Measure 10 ml of polymethyl acrylate macroporous resin (wet material), put it into 100 ml of sulfuric acid aqueous solution with a mass concentration of 7%, heat to boiling, and reflux for 10 hours for hydrolysis.

[0030] Take out the resin, wash it with deionized water until neutral, put the resin into 50ml tetraethylenetriamine, heat to 70°C, and fully react for 3 hours to make a formaldehyde adsorbent. After testing, the saturated adsorption capacity of the obtained formaldehyde adsorbent sample to formaldehyde was 1.67mmol / g.

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Abstract

The invention discloses a preparation method of an organic formaldehyde adsorbent: (1) ester group hydrolysis. The polymethyl acrylate macroporous resin or the polymethyl methacrylate macroporous resin is put into sodium hydroxide aqueous solution or sulfuric acid solution, and heated under reflux for 2 to 10 hours for hydrolysis. (2) Amination and imidization reactions. (1) Wash the hydrolyzed macroporous resin to neutrality, add an aminating agent, and react at 50°C to 150°C for 2 to 20 hours, take out the macroporous resin, wash and dry. The formaldehyde adsorbent is a solid powder or granular organic material, including a matrix material and active functional groups, the active functional groups are amino functional groups and imidazole derivative functional groups. The formaldehyde adsorbent achieves the purpose of adsorbing formaldehyde through the reaction of formaldehyde with amine groups and imidazole derivatives.

Description

technical field [0001] The invention belongs to the field of air pollution purification, and relates to an organic formaldehyde adsorbent and a preparation method thereof. Background technique [0002] In recent years, with the continuous improvement of living standards and the continuous improvement of people's living conditions, people have begun to pay more and more attention to the environmental pollution caused by interior decoration. Relevant state departments have successively formulated a series of standards on indoor environment, but the reality is not optimistic. Formaldehyde is recognized as the No. 1 killer of home decoration and is closely related to people's lives. In particular, phenolic resin with formaldehyde as the main component is the preferred adhesive for plywood, thin board, medium density board, etc. used in interior decoration. After these panels are used as decoration materials or made into furniture, the residual free formaldehyde in the panels wi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/26B01J20/30
Inventor 范海明张琴陈兆文周钧徐伟张民张浩
Owner 邯郸派瑞电器有限公司
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