A kind of high-strength nylon compound and preparation method thereof

A composite, high-strength technology, applied in the field of high-strength nylon composites prepared by blending and extrusion, can solve the problems of high water absorption, poor dimensional stability, poor fluidity, etc., and achieve creep resistance and fatigue resistance. Effects of increased strength, reduced molding shrinkage, and wider application range

Inactive Publication Date: 2011-12-21
广东奇德新材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

There are many modified nylons with glass fiber added on the market to enhance the shortcomings of nylon products such as easy warping and poor fluidity, but it is easy to cause the size of the injection products to be unstable and easy to deform, which will have a negative impact on the post-assembly of the products , seriously affecting its performance
In terms of formula, simply using glass fiber to enhance the characteristics of nylon can easily cause nylon to warp and have poor fluidity. Even if minerals are added to improve warpage and fluidity, it will also cause a great impact on the mechanical properties. Negative impact
In terms of production technology, volumetric feeding is mainly used to feed nylon, mineral powder and other additives at the same time, and long glass fiber is used for side feeding. This kind of production technology often makes the product quality unstable.
In addition, nylon also has more prominent shortcomings, such as high water absorption rate, resulting in poor dimensional stability, etc. Nylon is used as an engineering plastic, and its mechanical properties need to be further improved in order to obtain polyamide materials with higher strength and heat distortion temperature.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0017] In addition, this embodiment also relates to a method for preparing a high-strength nylon composite, the preparation steps of which are:

[0018] ①Put Nylon 6 or Nylon 66 in a dehumidification dryer, and dry and dehumidify it at a temperature of 110°C for 8 hours;

[0019] ②Put the dried and dehumidified Nylon 6 or Nylon 66 together with magnesium salt whiskers, nylon chain extender, antioxidant and lubricant into a high-speed mixer for 2 minutes and then set aside;

[0020] ③Put the mixture in ② above into the twin-screw extruder, and at the same time, add alkali-free long glass fiber at the glass fiber port of the twin-screw extrusion, so that the alkali-free long glass fiber and the mixture are fully mixed, and then extruded through the twin-screw Extrude nylon compound;

[0021] ④The nylon composite is water-cooled in a cooling water tank and formed into strips, and then cut into nylon composite particles by a pelletizer to complete the preparation of the nylon com...

Embodiment 2

[0026] Present embodiment 2 changes on the basis of embodiment 1, and it is specifically as follows:

[0027] Retain the preparation method of the high-strength nylon composite in Example 1, mainly to change the component formula of the high-strength nylon composite, that is, the high-strength nylon composite is made of 74.4% nylon 66 by mass percentage and 20% by mass. % alkali-free long glass fiber, 5% by mass of magnesium salt whisker, 0.2% by mass of nylon chain extender, 0.1% by mass of antioxidant and 0.3% by mass of lubricant. Among them, the magnesium salt whisker product has a single-whisker fiber structure, and the diameter is in the range of nanometers. The magnesium salt whisker has high physical and mechanical properties, and the addition of it can enhance the strength of the nylon composite material. The nylon chain extender uses carbonyl biscaprolactam (CBC); the antioxidant is bis(2.4-di-tert-butylphenyl) pentaerythritol bis-diphosphite; the lubricant is calciu...

Embodiment 3

[0029] Present embodiment 3 is to change on the basis of embodiment 1 equally, and it is specifically as follows:

[0030] Retain the preparation method of the high-strength nylon composite in Example 1, mainly to make changes to the component formulation of the high-strength nylon composite, that is, the high-strength nylon composite is made of 48.8% by mass percentage of nylon 6, and the mass percentage is 45%. % alkali-free long glass fiber, 5% by mass of magnesium salt whisker, 0.5% by mass of nylon chain extender, 0.2% by mass of antioxidant and 0.5% by mass of lubricant. Among them, the magnesium salt whisker product has a single-whisker fiber structure, and the diameter is in the range of nanometers. The magnesium salt whisker has high physical and mechanical properties, and the addition of it can enhance the strength of the nylon composite material. The nylon chain extender is phenylbisoxazoline (PBO); the antioxidant is disodium hydrogen phosphate; the lubricant is ca...

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PUM

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Abstract

The invention discloses a high-strength nylon composite, which consists of nylon 6 or nylon 66 with a mass percentage of 43.1% to 74.4%, alkali-free long glass fibers with a mass percentage of 20% to 50%, and magnesium with a mass percentage of 5%. It consists of salt whiskers, 0.2% to 1% by mass of nylon chain extender, 0.1% to 0.3% by mass of antioxidant and 0.3% to 0.6% by mass of lubricant. The high-strength nylon compound of the present invention adds formulation materials: magnesium salt whisker, nylon chain extender, antioxidant and lubricant on the basis of main material being nylon 6 or nylon 66, alkali-free long glass fiber, can have greatly Increases the physical and mechanical properties of nylon compounds. The advantages of the high-strength nylon compound of the present invention are: doubled mechanical properties, significantly improved heat resistance, reduced molding shrinkage, reduced water absorption, significantly improved creep resistance and fatigue resistance.

Description

technical field [0001] The invention relates to a high-strength nylon composite and its preparation method, in particular to a high-strength nylon composite prepared by adding glass fibers into a nylon (polyamide) matrix and blending and extruding. Background technique [0002] Nylon (polyamide) has excellent mechanical properties, physical and mechanical properties, electrical properties, wear resistance and chemical resistance, such as high tensile strength, good impact resistance, outstanding chemical resistance and oil resistance, and is one of the five general engineering The most widely used variety in plastics. There are many modified nylons with glass fiber added on the market to enhance the shortcomings of nylon products such as easy warping and poor fluidity, but it is easy to cause the size of the injection products to be unstable and easy to deform, which will have a negative impact on the post-assembly of the products , seriously affecting its performance. In ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/02C08L77/06C08K13/04C08K7/14C08K7/04B29C47/92B29C48/92
Inventor 饶德生
Owner 广东奇德新材料股份有限公司
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