Method for preparing metal nanometer particles with hexagonal network in lattice distribution on substrate

A metal nanoparticle and substrate technology, which is applied in the preparation and application of nanomaterials, can solve the problems of random distribution of metal particles, difficult to control size and shape, and complicated experimental procedures, and achieves low equipment cost, short experimental period and mature technology. Effect

Inactive Publication Date: 2012-01-18
GRADUATE SCHOOL OF THE CHINESE ACAD OF SCI GSCAS
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Problems solved by technology

However, there are very few types of monodisperse metal nanoparticles that have been successfully prepared, and their size and shape are not easy to control. It is very difficult to prepare monodisperse nanoparticles with a diameter greater than 30 nm.
The metal catalytic particles required by the vapor-liquid-solid (VLS) growth method are generally obtained by high-temperature annealing of the metal film, and the diameters of th

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  • Method for preparing metal nanometer particles with hexagonal network in lattice distribution on substrate
  • Method for preparing metal nanometer particles with hexagonal network in lattice distribution on substrate
  • Method for preparing metal nanometer particles with hexagonal network in lattice distribution on substrate

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Embodiment Construction

[0018] The method proposed by the present invention to prepare metal nanoparticles distributed in a hexagonal network lattice on a substrate comprises the following steps:

[0019] (1) Using a physical vapor deposition method, uniformly deposit a metal film with a thickness of 50 nanometers to 180 nanometers on the substrate with a hexagonal close-packed microsphere template;

[0020] (2) Shake the sample quickly in an ultrasonic atmosphere for 2 seconds to 10 seconds, remove the microspheres on the substrate, and leave a nearly triangular metal nanoparticle array with a hexagonal network lattice distribution on the substrate;

[0021] (3) Place the substrate with the metal nanoparticle array horizontally into a rapid annealing furnace, and perform rapid thermal annealing on the substrate in an inert atmosphere at a temperature 30-80°C lower than the eutectic point of the metal and the substrate material, and the annealing time is For 30-90 seconds, metal nanoparticles with he...

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Abstract

The invention relates to a method for preparing metal nanometer particles with hexagonal network in lattice distribution on a substrate, which belongs to the technical fields of nano-material preparation and application. The method comprises the following steps: preparing a layer of metal film by a physical vapor deposition method on the substrate with a hexagonal close-packing microsphere template, rapidly removing the template to obtain a triangle metal nanometer particles array which is orderly arrayed, introducing inert gas under the temperature below 30 DEG C-80 DEG C which is an eutectic point of the substrate and the metal material, performing a rapid thermal annealing treatment to the substrate disposed horizontally to obtain the nearly semispherical metal nanometer particles with hexagonal network in lattice distribution on the substrate. The method has the advantages of simple flow and mature technology which realizes adjustable density and diameter of the metal particles and well-regulated assignment. The invention has wide application prospects in the fields of nano-material engineering, novel energy development and the like.

Description

technical field [0001] The invention relates to a method for preparing metal nanoparticles distributed in a hexagonal network lattice on a substrate, and belongs to the technical field of preparation and application of nanomaterials. Background technique [0002] Two-dimensional discrete and ordered nano-metal particle lattices have broad application prospects in the fields of nanostructure solar cells, surface-enhanced Raman spectroscopy, surface plasmon resonance research, and preparation of ordered nanomaterials. To prepare an ordered array on a substrate by conventional methods, first obtain monodisperse metal particles, and then use a suitable process to arrange the particles in an orderly manner. However, few types of monodisperse metal nanoparticles have been successfully prepared, and its size and shape are not easy to control. It is very difficult to prepare monodisperse nanoparticles with a diameter greater than 30 nm. The metal catalytic particles required by the...

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Application Information

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IPC IPC(8): B81C1/00
Inventor 董刚强刘丰珍
Owner GRADUATE SCHOOL OF THE CHINESE ACAD OF SCI GSCAS
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