Lithium ion battery electrolyte and lithium ion secondary battery
A lithium-ion battery and electrolyte technology, applied in the field of lithium-ion battery electrolyte, lithium-ion secondary battery, and lithium-ion battery electrolyte, can solve the problems of insufficient cycle performance and low-temperature discharge performance, and achieve the effect of improving cycle performance
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Embodiment 1
[0031] This example 1 is used to illustrate that the resistance of the SEI film formed by the lithium-ion battery electrolyte additive provided by the present invention is relatively small.
[0032] Mix EC, EMC, and DEC evenly according to the volume ratio of 1:1:1, and slowly add lithium salt LiPF 6 A non-aqueous organic electrolyte with a concentration of 1M was prepared to prepare an electrolyte 1, and 2 wt% of tris(trimethylsilane) phosphate TMSP was added to the electrolyte 1 to prepare an electrolyte 2.
[0033] The negative electrode sheet with lithium sheet and artificial graphite as the active material is used as the two electrodes, the porous polyolefin compound diaphragm is used as the diaphragm, and the prepared electrolyte 1 and electrolyte 2 are used as the electrolyte to make a button half-cell.
[0034] Perform cyclic voltammetry (CV) test at a speed of 0.5mV / S, the test results are shown in figure 1 , it can be clearly seen that TMSP is reduced on the surface...
Embodiment 2
[0037] Mix EC, EMC, and DEC evenly according to the volume ratio of 3:4:3, and slowly add lithium salt LiPF 6 Prepare a non-aqueous organic electrolytic solution with a concentration of 1M, add tris(trimethylsilane) phosphate to the prepared electrolytic solution in proportions of 0.5wt%, 1wt%, and 5wt% of the total weight of the electrolytic solution to obtain Electrolyte 3, Electrolyte 4, Electrolyte 5.
Embodiment 3
[0039] Mix EC and DEC evenly according to the volume ratio of 3:7, and slowly add lithium salt LiPF 6Prepare a non-aqueous organic electrolyte with a concentration of 1M, add tris(triphenylsilane) phosphate and 2 wt% to the prepared electrolyte in proportions of 1wt%, 10wt%, and 15wt% of the total weight of the electrolyte Electrolyte 6, Electrolyte 7, and Electrolyte 8 were prepared from fluoroethylene carbonate FEC.
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