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Polyester film for electronic tag and preparation method thereof

A technology of polyester film and electronic tags, which is applied to record carriers used in machines, instruments, computer parts, etc., can solve problems such as unstable electrical properties, poor dimensional stability, and difficult definition of reading areas, and achieve good economy Benefits and social benefits, good practical effect

Active Publication Date: 2012-06-27
YIHUA TORAY POLYESTER FILM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

6) Compared with RFID products in other frequency bands, the data transmission rate of this frequency band is relatively slow
7) The price of the sensor is high
3) Radio waves in the ultra-high frequency band cannot pass through many materials, especially suspended particles such as water, dust, and fog
5) This frequency band has a good reading distance, but it is difficult to define the reading area
In China, although it has been reported that the longitudinal shrinkage rate of polyester film used for electronic labels is ≤0.1% under the condition of 150°C / 30min, the polyester film prepared by the existing production technology has poor processability and poor electrical properties. The disadvantages of stability and poor dimensional stability still cannot meet the requirements for the use of electronic tags, so it is necessary to innovate and improve the existing polyester film and its preparation method

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Preparation of functional slice A: Select high-quality shell powder with an average particle size of less than 6 μm (commercially available), use titanate coupling agent (brand NDZ-201, commercially available), silane coupling agent (brand KH550, commercially available) , surfactants (fatty acid glycerides , commercially available) for processing, using the DMT method to synthesize functional slice A with a mass percentage of shell micropowder of 0.1-13.5% under the condition of adding polyphosphoric acid (referred to as PPA, commercially available). The performance indicators that the functional polyester chips A meet include: moisture 0.62dL / g, diethylene glycol ≤1.4%, and shell powder content of 0.1-13.5% by mass.

Embodiment 2

[0038]Preparation of functional slice B: put nano-montmorillonite (commercially available) into a high-speed mixer, then slowly add solvent-treated silane coupling agent (brand KH550, commercially available), and stir at high speed for 20 minutes to obtain modified nano-montmorillonite Desoiling, using the DMT method or the PTA method to synthesize functional polyester chips B with a mass percentage of nano-montmorillonite of 0.5-32.6%. The performance indicators that the functional slice B meets include: moisture 0.62dL / g, diethylene glycol ≤1.4%, and nano-montmorillonite mass percentage of 0.5-32.6%.

Embodiment 3

[0040] To prepare recycled particles of waste polyester materials, the recycled waste polyester materials without impurities are crushed and heated, then dehydrated, dried, low molecular weight removed, filtered, melted and extruded in a vacuum venting regranulation extruder. Granulated, then dried vested. The performance indicators that the regenerated particles of waste polyester materials meet include: moisture 0.59dL / g, diethylene glycol ≤ 1.5%.

[0041] Preparation of ordinary polyester chips: the large-scale industrialized PTA method is used to synthesize ordinary polyester chips, that is, basic chips, using PTA and EG.

[0042] Preparation of IPA chips: The production method is the same as that of ordinary polyester chips. Only PTA is replaced with IPA to obtain IPA chips. The mass percentage of IPA in the polyester chips containing IPA is 0.2~7.8%.

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PUM

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Abstract

The invention discloses a polyester film for an electronic tag and a preparation method thereof. The preparation raw materials of the polyester film for the electronic tag comprises the following components in percentage by weight: 0.1-35.6 percent of functional chip A, 0.1-42.2 percent of functional chip B, 20-68 percent of recycled particle of waste polyester material, 40-90 percent of common polyester chip, 1-12 percent of polyester chip containing IPA (isopropyl alcohol), and 5-92 percent of silicon chip, wherein the mass percentage content of shell micro powder in the functional chip A is 0.1-13.5 percent; the mass percentage content of nano-montmorillonite in the functional chip B is 0.5-32.6 percent; the mass percentage content of the IPA in the polyester chip containing the IPA is0.2-7.8 percent; and the mass percentage content of silicon oxide in the silicon chip is 200-18900PPM (parts per million). Compared with the polyester film for the electronic tag in the prior art, the polyester film for the electronic tag disclosed by the invention has the outstanding advantages that: the polyester film for the electronic tag has longitudinal thermal shrinkage being within 0-1 percent at the high temperature of 180 DEG C, dielectric constant being within 1-3 under a test condition of 1 GHz, and dielectric loss tangent value being 0.2 percent to 0.8 percent; meets the use requirement of the electronic tag; has good practical applicability; and can make better economic benefits and social benefits.

Description

technical field [0001] The invention belongs to the technical field of new polymer materials for electronic products, and in particular relates to a polyester film for electronic labels and a preparation method thereof. Background technique [0002] Radio Frequency Identification (RFID), commonly known as electronic tags, is a non-contact automatic identification technology, which automatically identifies target objects and obtains relevant data through radio frequency signals, used to control, detect and track objects, and can work in various It can identify high-speed moving objects and identify multiple tags at the same time. The identification work does not require manual intervention, and the operation is fast and convenient. RFID is a simple wireless system, including an interrogator (or reader) and many transponders (or tags), its basic structure is composed of tags, readers and antennas; tags (Tag) are composed of coupling elements and chips , each tag has a unique ...

Claims

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Application Information

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IPC IPC(8): C08L67/00C08L67/02C08K13/06C08K9/04C08K9/06C08K3/26C08K3/34C08K3/36B29C55/14G06K19/07
Inventor 林跃建穆稚吴建勋黄家阳刘国平王彩虹接道良王正康
Owner YIHUA TORAY POLYESTER FILM CO LTD
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