Anisotropic conductive film, composition contained therein and device having the film
An anisotropic, conductive film technology for conductive adhesives, conductive materials dispersed in non-conductive inorganic materials, film/flake adhesives, etc.
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Embodiment 1
[0071] Embodiment 1: Preparation of anisotropic conductive film composition
[0072]Prepare an adhesive resin system, which consists of 3wt% polyurethane microbeads (MM-101-MS, sample prepared from Negami, Tg: 15°C) with a particle size of 0.1 μm in toluene / methyl ethyl ketone, 32wt% Polyurethane resin (UN5500, Negami), 5wt% of acrylonitrile-butadiene rubber (NBR) resin (N-34, Nippon Zeon) (30vol%) and 24wt% of MMA, BA and cyclohexyl methacrylate Alkyl methacrylate resin (weight average molecular weight = 90,000 g / mol, acid value = 2KOHmg / mg) composition of the copolymer. The binder resin system serves as a film-forming matrix. Prepare a curing system consisting of 25 wt% urethane acrylate (UN5507, Negami), 1 wt% 2-methacryloyloxyethyl phosphate as a reactive monomer, 2 wt% pentaerythritol tri(methyl) Acrylate and 2.5% by weight of 2-hydroxyethyl (meth)acrylate. Curing takes place in this curing system. Mix the adhesive resin system, the curing system, 2.5 wt% lauroyl pero...
Embodiment 2
[0073] Embodiment 2: Preparation of anisotropic conductive film composition
[0074] A film composition was prepared in the same manner as in Example 1, except that 21 wt % and 6 wt % of acrylic resin and polyurethane microbeads were used, respectively.
Embodiment 3-4
[0075] Example 3-4: Preparation of anisotropic conductive film composition
[0076] A film composition was prepared in the same manner as in Example 1 except that the size of the polyurethane microbeads was changed as shown in Table 1. In Example 3, polyurethane microbeads (particle diameter=0.8 μm, Tg: 40° C.) were used. In Example 4, polyurethane microbeads (particle diameter=1.0 μm, Tg: 40° C.) were used.
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