Halogen-free flame-retardant POE (Polyolefin Elastomer) compound material and preparation method thereof

A technology of composite materials and composite flame retardants, applied in the field of halogen-free flame-retardant POE composite materials and its preparation, can solve the problems of fatality, high flame-retardant efficiency, toxic smoke, etc., and achieve improved flame-retardant effect and good flame-retardant effect , the effect of improving fluidity

Inactive Publication Date: 2012-07-18
JIANGSU UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Traditional halogen-containing flame retardants have high flame retardant efficiency, but they will produce deadly toxic fumes when burned

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1）

[0017] The halogen-free flame-retardant POE composite material of this embodiment is made of the following components by weight:

[0018] 100kg of POE resin, 100kg of active magnesium hydroxide, 6kg of zinc borate, 18kg of microencapsulated red phosphorus, 15kg of low-density polyethylene, 4kg of solid paraffin (melting point is 50°C, the same below) and 0.5kg of antioxidant Agent 1010.

[0019] The preparation method of the above-mentioned halogen-free flame-retardant POE composite material has the following steps:

[0020] ①Pour 200kg of micron-grade magnesium hydroxide (average particle size of 100 microns) and 6kg of silane coupling agent of the brand KH-570 produced by Nanjing Qianqian Chemical Co., Ltd. into a high-speed mixer at a speed of 900 rpm Mix in the medium for 8 minutes until the frictional heat generated by the mixing makes the temperature of the material reach 115°C, and then discharge and cool to obtain active magnesium hydroxide.

[0021] 100kg of active ...

Embodiment 2～ Embodiment 4）

[0024] The preparation method of each example is the same as Example 1, the difference lies in the weight ratio of each component, see Table 1 for details.

[0025] Table 1

[0026] Example 1 Example 2 Example 3 Example 4 POE resin 100kg 100kg 100kg 100kg active hydroxide Activated magnesium hydroxide 100kg Activated aluminum hydroxide 100kg Activated aluminum hydroxide 100kg Activated magnesium hydroxide 100kg Zinc borate 6kg 8kg 6kg 10kg Microencapsulated red phosphorus 18kg 20kg 14kg 16kg modifier LDPE 15kg HDPE 10kg HDPE 10kg HDPE 12kg Lubricant Dispersant Solid paraffin 2kg Solid paraffin 5kg Solid paraffin 6kg Polyethylene wax 6kg Antioxidant 1010 0.5kg 0.8kg 0.5kg 0.7kg

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PUM

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Abstract

The invention discloses a halogen-free flame-retardant POE (Polyolefin Elastomer) compound material and a preparation method thereof. The halogen-free flame-retardant POE compound material is prepared from the following components in parts by weight: 100 parts of POE resin, 70-140 parts of halogen-free compound retardant, 5-30 parts of modifier, 3-10 parts of lubricating dispersing agent and 0.1-0.6 parts of anti-oxidant. The preparation method comprises the following steps of: putting the POE resin, the halogen-free retardant, the modifying agent, the lubricating dispersing agent and the anti-oxidant into a high-speed mixing machine for mixing till the materials are heated to 65-75 DEG C through frication heat generated by mixing, discharging and cooling; and feeding a cooled mixed material into a double-screw extruder for melting and extruding, cooling an extruded bar stock with a water groove, and drawing into a granulating machine for granulating to obtain the halogen-free frame-retardant POE compound material. The elongation rate of the halogen-free flame-retardant POE compound material is over 600 percent, the oxygen index is over 30 percent, the liquidity of a melt is high, and the heat ageing resistance is high.

Description

technical field [0001] The invention relates to a polymer composite material and a preparation method thereof, in particular to a halogen-free flame-retardant POE composite material and a preparation method thereof. Background technique [0002] POE resin is a new type of polyolefin elastomer polymerized by DOW Chemical Company of the United States with metallocene as a catalyst. Compared with other polyolefin elastomers, it has the advantages of low price and easy molding and processing. It is widely used in automobiles, electronic appliances, building seals, sports, etc. Equipment and polymer toughening modification and other fields. [0003] POE is a flammable material, and as its application continues to increase, it is imperative to modify it for flame retardancy. Traditional halogen-containing flame retardants have high flame retardant efficiency, but they produce deadly toxic fumes when burned. Contents of the invention [0004] One of the objectives of the presen...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L23/06C08K13/06C08K9/06C08K3/22C08K3/38C08K3/02B29C47/92B29C48/92
CPCB29C48/04B29C48/40
Inventor 周健
Owner JIANGSU UNIV OF TECH
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