Inorganic phase separation membrane and application of thereof to oil-water separation

A technology of oil-water separation and separation membrane, which is applied in the direction of liquid separation, separation method, semi-permeable membrane separation, etc., to achieve wide application prospects and excellent mechanical properties

Active Publication Date: 2012-07-25
JILIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the oil-water separation membranes that have been developed are limited by their own material properties, so it is difficult to apply in some harsh environments, such as strong acid environment, high ionic strength environment, microbial contamination environment and high temperature environment, etc.
However, in practical applications, the oil-water separation process often occurs under the above-mentioned environment

Method used

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  • Inorganic phase separation membrane and application of thereof to oil-water separation
  • Inorganic phase separation membrane and application of thereof to oil-water separation
  • Inorganic phase separation membrane and application of thereof to oil-water separation

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] The stainless steel mesh (80 mesh) was impregnated in the dispersed silicalite-1 nanometer molecular sieve (pure silicon MFI type molecular sieve) (see Chem. Treat for 10 minutes, then dry at 180°C for 2 hours; repeat the steps of impregnation, ultrasonication, and drying for 3 times.

[0044] The treated stainless steel mesh was vertically placed in a hydrothermal reactor and immersed in the synthetic sol of silicalite-1 molecular sieve (the molar ratio was 1KOH: 1TPABr: 1000H 2 O: 4.4TEOS, hydrothermal reaction at 200° C. for 120 hours for secondary growth of molecular sieves, resulting in a silicalite-1 molecular sieve coating with a thickness of 50 microns, and a mass ratio of stainless steel mesh to silicalite-1 molecular sieve coating of 5:1.

[0045] The product is washed twice with deionized water, dried at 60°C for 24 hours, and flattened to obtain an inorganic phase separation membrane that can separate various oils and fats with high efficiency and low energy...

Embodiment 2

[0047] The stainless steel mesh (360 mesh) was immersed in the dispersed silicalite-1 nano-molecular sieve (pure silicon MFI type molecular sieve) (the nano-molecular sieve was synthesized from Chem. Mater 20, 2008, 3543-3545) aqueous solution (mass fraction 2%), Ultrasonic treatment for 10 minutes, followed by drying at 180°C for 2 hours; repeat the steps of impregnation, ultrasonication, and drying 3 times.

[0048] The treated stainless steel mesh was vertically placed in a hydrothermal reactor and immersed in the synthetic sol of silicalite-1 molecular sieve (the molar ratio was 1KOH: 1TPABr: 1000H 2 O: 4.4TEOS, hydrothermal reaction at 200° C. for 72 hours for secondary growth of molecular sieves, resulting in a silicalite-1 molecular sieve coating with a thickness of 18 microns, and a mass ratio of stainless steel mesh to silicalite-1 molecular sieve coating of 25:1.

[0049] The product is washed twice with deionized water, dried at 60°C for 24 hours, and flattened to o...

Embodiment 3

[0051] The stainless steel mesh (800 mesh) was immersed in the dispersed silicalite-1 nanometer molecular sieve (pure silicon MFI type molecular sieve) (the nanomolecular sieve was synthesized from Chem.Mater 20, 2008, 3543-3545) aqueous solution (mass fraction 2%), Ultrasonic treatment for 10 minutes, followed by drying at 180°C for 2 hours; repeat the steps of impregnation, ultrasonication, and drying 3 times.

[0052] The treated stainless steel mesh was vertically placed in a hydrothermal reactor and immersed in the synthetic sol of silicalite-1 molecular sieve (the molar ratio was 1KOH: 1TPABr: 1000H 2 O: 4.4TEOS, hydrothermal reaction at 200° C. for 12 hours for secondary growth of molecular sieves, resulting in a silicalite-1 molecular sieve coating with a thickness of 7 microns, and a mass ratio of stainless steel mesh to silicalite-1 molecular sieve coating of 100:1.

[0053] The product is washed twice with deionized water, dried at 60°C for 24 hours, and flattened t...

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Abstract

The invention discloses an inorganic phase separation membrane and application of thereof to oil-water separation, belongs to a functional material technology and relates to the superhydrophilic and underwater super hydrophobic oil inorganic phase separation membrane which grows a molecular sieve coating on a porous base, and thus micro and nanometer scale, a composite surface and a mesh structure are formed. The membrane material can be used for separating various greases at high efficiency and high speed and low energy consumption under various serious water body environments; and the membrane can be used for a long time and is easy to regenerate. The inorganic phase separation membrane consists of the porous base and the molecular sieve coating grown on the porous base; the aperture size of the porous base is 20-200 micrometers; the thickness range of the molecular sieve coating is 3-50 micrometers; the mass ratio of the porous base to the molecular sieve coating is (100:1)-(5:1); the porous base is made of a stainless steel wire mesh, a copper mesh, an aluminum mesh or porous ceramic; and framework types of the molecular sieve are LTA, SOD, FAU, MEL, CHA, MFI , DDR, AFI, BEA or PHI.

Description

technical field [0001] The invention belongs to the technical field of functional materials, and in particular relates to a molecular sieve coating grown on a porous substrate, which has a micro-nano scale super-hydrophilic and underwater super-oleophobic inorganic phase separation membrane, which can be widely used for oil-water separation , remove the water in the oil. Background technique [0002] Crude oil extraction, phase separation process in industrial production, treatment of oily wastewater and frequent offshore oil spill accidents make oil-water separation technology widely concerned. At present, people have developed a variety of oil-water separation materials. Most of the materials developed in the past are based on the lipophilic and hydrophobic properties of materials, which can absorb oil from water. However, such materials are easily contaminated by oil and difficult to recycle, which greatly limits their applications. Recently, someone has developed a no...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D71/02B01D67/00B01D17/02
CPCB01D17/02B01D71/02B01D67/00B01D69/02B01D71/028B01D2325/02B01D2325/04B01D17/085B01D67/0051B01D69/10B05D1/18B05D1/38B05D3/007B05D3/0254
Inventor 于吉红温强邸建城张聪徐如人
Owner JILIN UNIV
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