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Magnesium chrome three-layer composite brick and preparation method thereof

A layer composite, magnesia-chrome technology, applied in the field of magnesia-chrome three-layer composite bricks and its preparation, can solve the problems of increased heat dissipation of the kiln shell, increased heat consumption of clinker, and increased temperature of the supporting wheel tiles, etc., to achieve good Fire-resistant and heat-insulating effects, prolonging the service life of equipment, and saving energy consumption

Inactive Publication Date: 2012-07-25
SUZHOU LOW CARBON ENERGY CONSERVATION TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Most of the existing refractory bricks and heat insulation bricks are made of a single material. When using them, bricks with various properties need to be used together. If they are used on relatively fixed equipment, such as tunnel kilns and downdraft kilns, they can meet the requirements. , but on some relatively moving equipment, such as a rotary kiln, it is difficult to meet the requirements when used together
Some manufacturers and research units have conducted research and research on this, and have introduced some composite bricks that combine heavy materials and light materials. However, due to the low structural strength of the light parts, they cannot meet the requirements for use, and the The light part is easy to react due to material problems, which affects product performance and use effect, so it has not been widely promoted, and heavy bricks are still the main ones
[0003] Taking the 10,000t / d rotary kiln of Conch Group as an example, spinel bricks are used in the front transition zone, and magnesia-chrome bricks are used in the firing zone. Due to the large thermal conductivity of spinel bricks in the front transition zone and magnesia-chrome bricks in the firing zone (≥ 2.7W / m·K), so that the temperature of the outer wall of the kiln shell is relatively high (about 380°C, and it can reach 420°C at high temperature), which will increase the heat dissipation of the kiln shell on the one hand, thereby increasing the heat consumption of clinker. It will cause an increase in the unit cost of clinker; on the other hand, it is very easy to cause the cylinder to expand due to heat, resulting in an increase in the temperature of the supporting wheel in the middle of the kiln, especially in the later period of use or in summer, which will bring great hidden dangers to the normal operation of the equipment.
The overheating of the cylinder increases the damage probability of mechanical equipment and accelerates the deformation of the cylinder, and the deformation of the cylinder accelerates the mechanical damage of the inner lining. The result is brick falling and kiln shutdown, which affects the operation rate of the cement rotary kiln

Method used

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  • Magnesium chrome three-layer composite brick and preparation method thereof
  • Magnesium chrome three-layer composite brick and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Such as figure 1 As shown, the magnesia-chrome three-layer composite brick of this embodiment includes a heavy working layer 1, a light heat insulating layer 3, and a transition layer 2 between the heavy working layer 1 and the light heat insulating layer 3.

[0023] in:

[0024] The particle size distribution and mass percentage of the raw materials used in the heavy working layer 1 are as follows: sintered magnesia with a particle size larger than 1mm: 30%; fused magnesia with a particle size larger than 1mm: 10%; Sintered magnesia with a particle size greater than 325 mesh: 30%; fused magnesia-chrome sand with a particle size of less than 1mm and larger than 325 mesh: 5%; sintered magnesium powder with a particle size of 325 mesh: 21%; fused magnesia-chrome powder with a particle size of 325 mesh: 4%. The binding agent adopted during material preparation is magnesium sulfate solution, and its weight is 3% of the weight of the heavy working layer.

[0025] The part...

Embodiment 2

[0034] Such as figure 1As shown, the magnesia-chrome three-layer composite brick of this embodiment includes a heavy working layer 1, a light heat insulating layer 3, and a transition layer 2 between the heavy working layer 1 and the light heat insulating layer 3.

[0035] in:

[0036] The particle gradation and mass percentage of the raw materials used in the heavy working layer 1 are: fused magnesia-chrome sand with a particle size greater than 1mm: 40%; fused magnesia-chrome sand with a particle size less than 1mm and greater than 325 mesh: 25%; Fused magnesium powder with a particle size of 325 mesh: 35%. The binding agent adopted during material preparation is magnesium sulfate solution, and its weight is 2% of the weight of the heavy working layer.

[0037] The particle size distribution and mass percentage of the raw materials used in the transition layer 2 are: fused spinel with a particle size larger than 1mm: 50%; fused spinel with a particle size smaller than 1mm ...

Embodiment 3

[0046] Such as figure 1 As shown, the magnesia-chrome three-layer composite brick of this embodiment includes a heavy working layer 1, a light heat insulating layer 3, and a transition layer 2 between the heavy working layer 1 and the light heat insulating layer 3.

[0047] in:

[0048] The particle size distribution and mass percentage of the raw materials used in the heavy working layer 1 are as follows: chrome concentrate with a particle size larger than 1mm: 20%; fused magnesia with a particle size larger than 1mm: 15%; particle size smaller than 1mm and larger than 325 mesh chrome concentrate: 20%; particle size less than 1mm and larger than 325 mesh fused magnesia: 15%; particle size 325 mesh fused magnesia powder: 10%; particle size 325 mesh chrome concentrate: 20% ; The binding agent adopted when preparing materials is a yellow dextrin solution, and its weight is 2% of the heavy working layer weight.

[0049] The gradation and mass percentage of raw material particle...

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Abstract

The invention provides a magnesium chrome three-layer composite brick with good abrasive resistance, high degree of fire resistance, high structural strength and good heat-preservation and heat-insulation performance, and a preparation method of the magnesium chrome three-layer composite brick. With the adoption of the magnesium chrome three-layer composite brick and the preparation method, the integrated function of fire resistance and heat insulation of the composite brick is realized, and the energy-saving effect of a rotary kiln is improved. The magnesium chrome three-layer composite brick comprises a heavy work layer prepared by taking a magnesium zirconium material as a raw material, a soft heat-insulation layer prepared by taking an electric melting hollow ball as a raw material and a transition layer between the heavy work layer and the soft heat-insulation layer. The transition layer is prepared by taking spinel, or magnesium aluminum chromium, or magnesium aluminum titanium, or magnesium spinel zirconium as a raw material. According to the magnesium chrome three-layer composite brick, the transition layer is introduced, the heavy work layer and the soft heat-insulation layer can be avoided to be reacted, a product can have good fire-resistance and heat-insulation performances without reducing the service life of the material, and therefore, the roles of saving energy consumption, reducing material consumption and reducing dosage of a fire resistance material of the rotary kiln are played, and the service life of equipment can be effectively prolonged.

Description

technical field [0001] The invention belongs to the technical field of refractory materials, and in particular relates to a magnesia-chrome three-layer composite brick and a preparation method thereof. Background technique [0002] With the continuous emergence of new technologies for cement production, the main equipment of cement production is developing in the direction of large-scale, increasing production, improving quality, saving energy, reducing consumption, and reducing costs have become the key to increasing efficiency in production management. Most of the existing refractory bricks and heat insulation bricks are made of a single material. When using them, bricks with various properties need to be used together. If they are used on relatively fixed equipment, such as tunnel kilns and downdraft kilns, they can meet the requirements. , but on some relatively moving equipment, such as a rotary kiln, it is difficult to meet the requirements when used together. Some ma...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/66
Inventor 王家邦
Owner SUZHOU LOW CARBON ENERGY CONSERVATION TECH
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