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Universal refrigerant resistant solvent-free impregnating resin for high and low voltage motor and preparation method thereof

A technology of impregnating resin, high and low voltage, applied in the field of general solvent-free impregnating resin for high and low voltage motors and its preparation, can solve the problems of unenvironmental protection, high price, high volatility, etc., and achieve the effect of low VOC content

Active Publication Date: 2013-06-19
SUZHOU JUFENG ELECTRICAL INSULATION SYST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] Among the existing refrigerant-resistant insulating varnishes (resins) at home and abroad, the typical example is the CC-1105 insulating varnish of the American DOLPHON company, which has a viscosity greater than 100s (4# viscometer, 25°C). It is used in the insulation treatment of high-voltage motors and requires heating and impregnation. , inconvenient to use, expensive
Domestic Sichuan Dongcai Technology Group Co., Ltd.’s DY001 insulating varnish is used in the insulation treatment of low-voltage motors. The solvent content is greater than 40%, which is highly volatile, pollutes the environment, is not environmentally friendly, and is not suitable for high-voltage motors.
There is no environmentally friendly refrigerant-resistant insulating impregnation resin that can take into account both high and low voltage motors in the market, so it is necessary to develop a new environmentally friendly high and low voltage motor that is free of volatile substances such as styrene and has excellent refrigerant resistance. General Refrigerant Resistant Impregnated Resin

Method used

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  • Universal refrigerant resistant solvent-free impregnating resin for high and low voltage motor and preparation method thereof
  • Universal refrigerant resistant solvent-free impregnating resin for high and low voltage motor and preparation method thereof
  • Universal refrigerant resistant solvent-free impregnating resin for high and low voltage motor and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0033] The formula of the solvent-free impregnating resin according to this embodiment is as follows:

[0034] 6kg of unsaturated polyester imine resin solution with a solid content of 70%;

[0035] 1.8 kg of polyoxazolidone resin solution with a solid content of 80%;

[0036] Crosslinking monomer (vinyl toluene) 1.5kg;

[0037] Curing agent (chromium acetylacetonate) 0.35kg;

[0038] Initiator (dicumyl peroxide) 0.175kg;

[0039] Polymerization inhibitor (hydroquinone) 2.4g.

[0040] The preparation of the solvent-free impregnating resin includes the following steps:

[0041] (1). Prepare an unsaturated polyester imine resin solution with a solid content of 70%: add 252g neopentyl glycol, 116g isophthalic acid, 128g maleic anhydride, and 53.4g partial benzene to a standard three-necked flask Tricarboxylic anhydride (phenyl)imide acid and 0.5g p-toluenesulfonic acid, heated to 200℃ under the protection of nitrogen, reacted for 5-6h, when the acid value fell below 20mgKOH / g, cooled to 100℃...

Embodiment 2

[0045] The formula of the solvent-free impregnating resin according to this embodiment is as follows:

[0046] 4.5 kg of unsaturated polyester imine resin solution with a solid content of 70%;

[0047] 3.2 kg of polyoxazolidone resin solution with a solid content of 80%;

[0048] Crosslinking monomer (vinyl toluene) 2kg;

[0049] Curing agent (zirconium acetylacetonate) 0.5kg;

[0050] Initiator: 200g dicumyl peroxide + 40g tert-butyl peroxybenzoate;

[0051] Polymerization inhibitor (p-benzoquinone) 4.5g.

[0052] The preparation of the solvent-free impregnating resin includes the following steps:

[0053] (1) Preparation of an unsaturated polyester imine resin solution with a solid content of 70%: In a standard three-necked flask, add 238g neopentyl glycol, 26.1g SEC, 116g isophthalic acid, 14.6g adipic acid, 128g maleic anhydride, 19.5g tetrahydrophthalic anhydride imine ethyl alcohol and 0.45g p-toluenesulfonic acid, heated to 200℃ under the protection of nitrogen, reacted for 5-6h, w...

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Abstract

The invention relates to a universal refrigerant resistant solvent-free impregnating resin for a high and low voltage motor and a preparation method thereof. The impregnating resin is composed of 45-65 parts of unsaturated polyesterimide resin solution with 65-75% of solid content, 15-35 parts of oxazolidone resin solution with 75-85% of solid content, 10-25 parts of environment-friendly dilutingagent, 3-8 parts of curing agent, 1-3 parts of initiating agent and 0.01-0.06 part of polymerization inhibitor; the raw material formula of an unsaturated polyesterimide resin comprises a first monomer, a second monomer and a third monomer, wherein the first monomer is selected from one or multiple of neopentyl glycol, propoxylation bisphenol A and trihydroxyethyl isocyanurate; the second monomeris selected from one or multiple of isophthalic acid, hexanedioic acid, trimellitie anhydride and maleic anhydride; and the third monomer is a compound containing imide groups. The resin provided by the invention has low content of VOC (Volatile Organic Compounds), resists novel refrigerating fluids such as R134a and is universal for the high and low voltage motor.

Description

Technical field [0001] The invention belongs to the technical field of insulating impregnating resin (vacuum pressure impregnation), and particularly relates to a general-purpose solvent-free impregnating resin for high and low voltage motors resistant to refrigerant and a preparation method thereof. Background technique [0002] Motors, transformers and other electrical windings can only operate safely and reliably after they are treated with insulating varnish. After the winding coil is treated with VPI varnish, baking and curing become a whole, which improves the insulation performance and mechanical strength, avoids partial discharge in the internal air gap, improves moisture resistance and salt spray resistance, enhances operational reliability, and extends service life. It is one of the most important links in the motor manufacturing process. A motor cooled by a refrigerant has windings in contact with a refrigerant for a long time. The previously commonly used refrigerant...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L79/08C08L75/00C08K5/07C08K5/098C08K5/14C08J3/24
Inventor 徐伟红袁世臻何少波夏宇宁方为安小珍
Owner SUZHOU JUFENG ELECTRICAL INSULATION SYST
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