Composition for processing porous polycarbonate material, porous polycarbonate material and preparation method thereof

A technology of polycarbonate and porous materials, applied in the field of polymers, can solve the problems of expensive carbon fiber, high cost, and discounts, and achieve the effects of simple and feasible processing, easy mastery of technology, and cost reduction

Inactive Publication Date: 2012-10-03
5ELEM HI TECH CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] There is already a Chinese patent CN101591469A for producing conductive polycarbonate materials by adding conductive carbon black and conductive carbon nanotubes. However, because conductive carbon black and other powders are in contact with each other in the matrix to form a conductive network, a relatively large amount of addition is generally required. On the one hand, it increases cost, on the other hand may affect the performance of the substrate
[0004] There is already a Chinese patent CN101215413A to prepare antistatic and conductive polycarbonate materials by adding conductive carbon fibers, but carbon fibers are expensive
[0005] Chinese patent CN 101840745 A prepares antistatic and conductive polycarbonate materials by adding stainless steel fibers, but this material is not only expensive, but also has a density much higher than traditional plastics, and the advantages of light weight of plastics are greatly reduced
[0006] The methods described in the above patents can well prepare conductive polycarbonate materials, but the materials obtained in the above patents have poor mechanical properties or are expensive, and cannot be widely used in daily production and life.

Method used

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  • Composition for processing porous polycarbonate material, porous polycarbonate material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] In percent by weight, take polycarbonate (121R, Saudi Basic Industries Corporation) 72%, lubricant (Rome 2 type calcium stearate, Shanghai Aoke Chemicals Co., Ltd.) 2% and antioxidant (168, steam Ba Jinghua Co., Ltd.) 0.5% and conductive carbon fiber (12K long carbon fiber, Taiwan Taili carbon fiber) 25.5% adopt twin-screw extruder to carry out melt blending extruding granulation at 270~275 ℃, then above-mentioned pellet is at room temperature Add 1% foaming agent (LDM10070S, Shanghai Jieshangjie Trading Co., Ltd.) and mix well, and inject samples or parts with an injection molding machine at 285°C, injection pressure of 80MPa and mold temperature of 90°C.

[0027] Below is the comparison of the performance detection data of solid spline (not using blowing agent) and porous spline (embodiment 1):

[0028] Table 1 Performance test results of Example 1

[0029]

[0030] It is shown from Table 1 that the polycarbonate porous material has a density reduction of more tha...

Embodiment 2

[0032] By weight percentage, take polycarbonate (121R, SABIC) 74%, lubricant (Rome 2 type calcium stearate, Shanghai Aoke Chemical Co., Ltd.) 0.5%, toughening agent (EM500, LG ) 2% and antioxidant (168, Ciba Specialty Chemical Co., Ltd.) 0.5% and conductive carbon fiber (TR06U, Mitsubishi carbon fiber) 23% at 255 ~ 260 ° C using a twin-screw extruder for melt blending extrusion granulation , then add 0.8% foaming agent (LDM10070S, Shanghai Jieshangjie Trading Co., Ltd.) to the above-mentioned pellets at room temperature and mix them evenly, and inject them with an injection molding machine at 290°C, an injection pressure of 55MPa and a mold temperature of 100°C. into samples or parts.

[0033] Below is the comparison of performance detection data of solid spline (not using blowing agent) and porous spline (embodiment 2):

[0034] Table 2 Performance Test Results of Example 2

[0035]

[0036] As shown in Table 2, similar to Example 1, the density of the polycarbona...

Embodiment 3

[0038] By weight percentage, take polycarbonate (1225Y, Teijin Group) 87%, lubricant (Rome 2 calcium stearate, Shanghai Aoke Chemical Co., Ltd.) 2%, dispersant (TM932, Yizheng Tianyang) Chemical Co., Ltd.) 0.8% and antioxidant (168, Ciba Specialty Chemicals Co., Ltd.) 0.2% and conductive carbon black (Ketjenblack EC-300J, AkzoNobel) 10% are carried out at 275~280 ° C using a single-screw extruder Melt blending extrusion granulation, and then the above-mentioned granules are mixed at room temperature with 1% foaming agent (LDM10070S, Shanghai Jieshangjie Trading Co., Ltd.), at 265 ° C, injection pressure is 75 MPa and mold temperature is 90 ° C Conditions, injection into samples or parts with an injection molding machine.

[0039] Below is the comparison of performance detection data of solid spline (not using blowing agent) and porous spline (embodiment 3):

[0040] Table 3 Performance Test Results of Example 3

[0041]

[0042] As shown in Table 3, similar to Exam...

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Abstract

The invention discloses a composition for processing a porous polycarbonate material, the porous polycarbonate material and a preparation method thereof. The composition comprises the following components and content thereof, by weight, 65-88% of polycarbonate, 10-30% of conductive filler and 0.1-5% of auxiliaries, wherein the auxiliaries at least include antioxidant. A porous material processed by the composition is a porous polycarbonate material with permanent antistatic and conductive performance and is formed in an extrusion or injection manner by corresponding equipment such as an extruder. Compared with that of the conventional material, cost can be reduced by 20% around on the basis of keeping volume resistivity and surface resistivity constant.

Description

technical field [0001] The invention belongs to the field of macromolecules, and relates to a permanent antistatic and conductive polycarbonate porous material processing composition, a polycarbonate porous material and a preparation method thereof. Background technique [0002] Antistatic, especially conductive polymer materials are a new type of functional plastics, which are widely used in antistatic turnover boxes, fuel filters, shells and structural parts of explosion-proof products, etc. [0003] There is already a Chinese patent CN101591469A for producing conductive polycarbonate materials by adding conductive carbon black and conductive carbon nanotubes. However, because conductive carbon black and other powders are in contact with each other in the matrix to form a conductive network, a relatively large amount of addition is generally required. On the one hand, it increases Cost, on the other hand, may have an impact on the performance of the substrate. [0004] Th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L69/00C08K13/04C08K7/06C08K3/04C08K3/08C08J9/04B29C47/92B29B9/06B29C48/92
CPCB29C48/04
Inventor 沙月华毛宇黄骥
Owner 5ELEM HI TECH CORP
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