Process for balling by mixing 200 meshes of celestite mineral powders and reduction coals

A technology of lapis lazuli and mineral powder, applied in the field of 200-mesh lapis lazuli powder and reduced coal mixed pelletizing technology, which can solve the problems of waste of strontium resources, incomplete reaction, and decrease of strontium yield, and achieve less investment in equipment and lower cost Low, consistent quality results

Inactive Publication Date: 2012-11-14
QINGHAI INST OF SALT LAKES OF CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Celestite mineral powder and coal powder are roasted in the rotary kiln according to the conventional process. The negative pressure in the rotary kiln causes the mineral powder to be sucked away by the induced draft fan, the yield of strontium decreases, and the waste of strontium resources is serious, causing pollution to the environment and cannot be restored by conventional roasting process. strontium sulfate to strontium sulfide
200-mesh celestite concentrate agglomeration process, rolling in the disc pelletizer to collide with each other and compact the balls, the particle size of the spheres is controlled at 10~12mm, and the falling strength of the pellets is 4.6~4.7 times·0.5m -1 , in the roasting process of producing strontium carbonate by the black ash method, the particle size of the spheroids of the ore powder is too large, the reaction is not complete, the yield of strontium is reduced, and the waste of strontium resources is caused

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Example 1 The mixed pelletizing process of 200 mesh celestite ore powder and reduced coal includes the following steps:

[0018] (1) Stir and mix 50kg of celestite ore powder with a particle size of 200 mesh, 9.5kg of reduced coal with a particle size of 180 mesh, and 1.02kg of bentonite to obtain raw materials.

[0019] Among them: the mass ratio of sulfate in celestite ore powder to fixed carbon in reduced coal (kg / kg) is 1:2.5; bentonite accounts for 2% of the total mass of celestite ore powder and reduced coal.

[0020] (2) Stir 0.5 kg of industrial polyacrylic alcohol with 25L water at 80°C to dissolve it completely, prepare it into a 20g / L polyacrylic alcohol solution, and then add water to dilute it to a concentration of 2g / L polyacrylic alcohol solution.

[0021] ⑶ The raw material is sprayed with polyacrylic alcohol solution, after stirring and mixing uniformly, the pellets are extruded on a ball press until the particle size of the sphere is 15mm and the water conte...

Embodiment 2

[0025] Example 2 The mixed pelletizing process of 200 mesh celestite ore powder and reduced coal includes the following steps:

[0026] (1) Stir and mix 50 kg of celestite ore powder with a particle size of 200 mesh, 6.35 kg of reduced coal with a particle size of 180 mesh, and 2.8 kg of bentonite to obtain raw materials.

[0027] Among them: the mass ratio of sulfate radicals in celestite ore powder to fixed carbon in reduced coal (kg / kg) is 1:2; bentonite accounts for 5% of the total mass of celestite ore powder and reduced coal.

[0028] (2) Stir 0.5 kg of industrial polyacrylic alcohol with 25L of water at 85°C to dissolve it completely, prepare a 20g / L polyacrylic alcohol solution, and then add water to dilute it to a concentration of 3g / L polyacrylic alcohol solution.

[0029] ⑶ The raw material is sprayed with polyacrylic alcohol solution, after stirring and mixing uniformly, the pellets are extruded on a ball press until the particle size of the sphere is 15mm and the water...

Embodiment 3

[0033] Example 3 The mixed pelletizing process of 200 mesh celestite ore powder and reduced coal includes the following steps:

[0034] (1) Stir and mix 50 kg of celestite ore powder with a particle size of 200 mesh, 11.4 kg of reduced coal with a particle size of 180 mesh, and 1.8 kg of bentonite to obtain raw materials.

[0035] Among them: the mass ratio of sulfate in celestite ore powder to fixed carbon in reduced coal (kg / kg) is 1:3; bentonite accounts for 3% of the total mass of celestite ore powder and reduced coal.

[0036] (2) Stir 0.5 kg of industrial polyacrylic alcohol with 25L of water at 82°C to dissolve it completely, configure it into a 20g / L polyacrylic alcohol solution, and then add water to dilute it to a polyacrylic alcohol solution with a concentration of 4g / L.

[0037] ⑶ The raw material is sprayed with polyacrylic alcohol solution, after stirring and mixing uniformly, the pellets are extruded on a ball press until the particle size of the sphere is 15mm and t...

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Abstract

The invention relates to a process for balling by mixing 200 meshes of celestite mineral powders and reduction coals. The process comprises the steps of (1) stirring and uniformly mixing the celestite mineral powders, the reduction coals and bentonite to obtain a raw material; (2) stirring industrial polypropylene glycol by water so as to completely dissolve the polypropylene glycol, and configuring the polyvinyl alcohol to be 20g / L of polypropylene glycol solution, then adding water and diluting the polypropylene glycol solution to be 2-4g / L of polyvinyl alcohol solution; and (3) spraying and adding the polypropylene glycol solution into the raw material, stirring and mixing uniformly, then extruding and balling on a ball pressing machine until the grain size of a ball body is 15mm, and the water content of the ball body accounts for 5-7% of the total weight of the ball body; and (4) drying the ball body obtained from the step (3) to constant weight, and roasting the dried ball body according to a conventional process to be used for producing strontium carbonate. According to the process, few devices are invested, the cost is low, the process is simple, and impurities capable of affecting the quality of strontium carbonate are not introduced into the raw materials.

Description

technical field [0001] The invention relates to the technical field of strontium carbonate production, in particular to a process for mixing and pelletizing 200-mesh celestite ore powder and reduced coal. Background technique [0002] The proven reserves of celestite in the Dafengshan area of ​​the Qaidam Basin in Qinghai reach more than 20 million tons, making it the largest strontium deposit in the world. The grade of strontium ore is low, the content of strontium sulfate in celestite mine is between 30% and 50%, and the particle size is fine. The roasting process for the preparation of strontium carbonate by the conventional black ash method is that celestite with a particle size of 1-5 mm and anthracite undergo redox reactions at 1000-1200 ° C to form strontium sulfide. Celestite mineral powder and coal powder are roasted in the rotary kiln according to the conventional process. The negative pressure in the rotary kiln causes the mineral powder to be sucked away by the ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B1/242
Inventor 杨占寿祁瑞清王树轩邹兴武祁米香王舒娅李宁
Owner QINGHAI INST OF SALT LAKES OF CHINESE ACAD OF SCI
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