Silver-based composite particle, preparation method of the silver-based composite particle and antibacterial agent containing the silver-based composite particle
A technology of composite particles and antibacterial agents, applied in the directions of botanical equipment and methods, chemicals for biological control, biocides, etc. It can improve the washing resistance, ensure durability, and prevent photochromic problems.
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preparation Embodiment 1
[0053] (1) Preparation of solution A: Add 10g of sodium silicate (equivalent to about 5 grams of effective silica content) into 200g of a mixed solvent of water and ethanol (water:ethanol=40:1, volume ratio), and stir evenly to form a mixed solution . Then add 3g of polyethylene glycol to the formed mixed solution, and continue to stir until the polyethylene glycol is completely dissolved to form a silicon-containing stock solution (referred to as A solution), wherein the mass percentage of polyethylene glycol in A solution is about 1.5% .
[0054] (2) Prepare B solution: Dissolve ammonium chloride in water to form B solution, in which the concentration of ammonium chloride is 1.2mol / L.
[0055] (3) Slowly add solution A to 200g solution B under stirring, and use pH test paper to detect the pH value of the mixed solution during the dropping process until the pH value of the final mixed solution is about 10 to end the reaction, and then keep the temperature at 55°C Stirring w...
preparation Embodiment 2
[0061] Except that poly(1,4-butylene glycol) was used instead of polyethylene glycol in step (1), and zinc nitrate was used instead of zinc chloride in step (5), the procedure of the remaining steps was the same as that of Preparation Example 1.
preparation Embodiment 3
[0063] Except that AgF aqueous solution was used instead of silver nitrate aqueous solution in step (4), and zinc nitrate was used instead of zinc chloride in step (5), the rest of the steps were the same as in Preparation Example 1.
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