Phosphorus, nitrogen and bromine compound system fire retardant and preparation method thereof

A flame retardant and system technology, applied in the field of functional polymer materials, can solve the problems of application scope and production cost defects, and achieve the effects of low production cost, simple preparation process and good flame retardant effect

Inactive Publication Date: 2013-05-01
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In recent years, phosphorus-nitrogen and phosphorus-bromine flame retardants have developed rapidly. Due to their synergistic and synergistic ef

Method used

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  • Phosphorus, nitrogen and bromine compound system fire retardant and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0019] A phosphorus-nitrogen-bromine composite system flame retardant, which is prepared from the following raw materials in the weight ratio: MHB (melamine hydrobromide) 50g, APP (ammonium polyphosphate) 55g, flame retardant synergist Lianquat 4.5 g.

[0020] In the present embodiment, the bromine content in melamine hydrobromide is 35%, and the nitrogen content is 43%, which belongs to fine white powder, Nantong Yite Chemical Co., Ltd.; the phosphorus content in ammonium polyphosphate is 31%, and the nitrogen content is 15%, which belongs to fine white powder , Shenzhen Hongtaiji Industrial Co., Ltd.; Lianku is a liquid with a purity greater than 95wt%, Shanghai Maierui Chemical Technology Co., Ltd., and the above contents are all percentages by mass.

[0021] The preparation method of the above-mentioned phosphorus-nitrogen-bromine composite system flame retardant:

[0022] 1) Prepare the raw materials in the following weight proportions: 50g of MHB (melamine hydrobrom...

Embodiment 2

[0025] A phosphorus-nitrogen-bromine composite system flame retardant, which is prepared from the following raw materials in the weight ratio: MHB (melamine hydrobromide) 55g, APP (ammonium polyphosphate) 60g, flame retardant synergist Liancum 5g .

[0026] In the present embodiment, the bromine content in melamine hydrobromide is 35%, and the nitrogen content is 43%, which belongs to fine white powder, Nantong Yite Chemical Co., Ltd.; the phosphorus content in ammonium polyphosphate is 31%, and the nitrogen content is 15%, which belongs to fine white powder , Shenzhen Hongtaiji Industrial Co., Ltd.; Lianku is a liquid with a purity greater than 95wt%, Shanghai Maierui Chemical Technology Co., Ltd., and the above contents are all percentages by mass.

[0027] The preparation method of the phosphorus-nitrogen-bromine composite system flame retardant:

[0028] 1) Prepare the raw materials with the following weight ratio: MHB (melamine hydrobromide) 55g, APP (ammonium polyp...

Embodiment 3

[0031] A phosphorus-nitrogen-bromine composite system flame retardant, which is prepared from the following raw materials in the weight ratio: MHB (melamine hydrobromide) 60g, APP (ammonium polyphosphate) 65g, flame retardant synergist Lianquat 5.5 g.

[0032] Bromine content 35% in the melamine hydrobromide in this embodiment, nitrogen content 43% belong to fine white powder, Nantong Yite Chemical Co., Ltd.; Phosphorus content 31% in ammonium polyphosphate, nitrogen content 15% belong to fine white powder, Shenzhen City Hongtaiji Industrial Co., Ltd.; Lianku is a liquid with a purity greater than 95wt%, Shanghai Maierui Chemical Technology Co., Ltd.

[0033] A preparation method of a phosphorus-nitrogen-bromine composite system flame retardant:

[0034] 1) Prepare the raw materials with the following weight ratio: MHB (melamine hydrobromide) 60g, APP (ammonium polyphosphate) 65g, flame retardant synergist 5.5g;

[0035] 2) Put melamine hydrobromide (MHB) and amm...

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Abstract

The invention discloses a phosphorus, nitrogen and bromine compound system fire retardant which comprises the following raw materials in parts by weight: 50-65 parts of melamine hydrobromide, 50-65 parts of ammonium polyphosphate and 4.5-6 parts of fire retarding synergism synergist. The fire retardant integrates the advantages of a phosphorus based fire retardant and a bromine based fire retardant, so that properties of the phosphorus based fire retardant and the bromine based fire retardant are complemented. In addition, antimony trioxide is replaced by the fire retarding synergism synergist, so that consumption of the fire retardant is reduced, and the fire retarding property, the processablility and the physical and mechanical properties of a material are improved. The fire retardant can be directly added and filled in to be processed into a product, so that a processing technique is simple; the production cost is lowered; furthermore, the compound fire retardant is added to the material to ensure that the bromine content of the material is low (approximately a halogen-free requirement is met in a modified product); and modern high-efficiency and environment-friendly requirements are met.

Description

technical field [0001] The invention relates to a phosphorus-nitrogen-bromine composite system flame retardant and a preparation method thereof, belonging to the field of functional polymer materials. technical background [0002] With the continuous improvement of the economy and technology level, the polymer material industry has developed rapidly. The three major synthetic materials - rubber, plastics and fibers are more and more used in various sectors of the country's economy and in various fields of people's daily life, but most Polymers are flammable and combustible materials, and when burning, they have a large heat release rate, high calorific value, fast flame propagation speed, are not easy to extinguish, and sometimes produce thick smoke and toxic gases, causing environmental hazards and people's lives. Safety poses a huge threat. According to the latest statistics from relevant departments, a considerable part of the fires that have occurred in recent years are...

Claims

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Application Information

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IPC IPC(8): C08K5/3492C08K3/32C08K5/01C08L23/12
Inventor 高山俊王柱张林沈春晖
Owner WUHAN UNIV OF TECH
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