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Method for preparing fruit and vegetable enzymatic browning high-efficiency inhibiting component from Maillard reaction product

A technology of Maillard reaction and fruit and vegetable enzymes, which is applied in the field of preparation of high-efficiency inhibitory components, can solve problems such as high-efficiency components that have not yet been seen, and achieve the effects of widening separation, reducing losses, and increasing added value

Active Publication Date: 2013-05-08
HAIKOU EXPERIMENTAL STATION CHINESE ACAD OF TROPICAL AGRI SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, so far, there have been no reports on the enrichment and isolation of highly effective components that inhibit enzymatic browning of fruits and vegetables from relatively melamine products.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] In this example, L-cysteine ​​and glucose were used as reaction raw materials. Firstly, the reaction substrates were prepared into solutions with a concentration of 1 mol / L. The two solutions were mixed in equal volumes, and the pH value was adjusted to 2 with NaOH solution.

[0023] Next, the mixed solution was placed in a closed container resistant to high temperature and high pressure, and reacted at a temperature of 110° C. for 1 hour. After the reaction, after the reaction product is cooled, it is classified by ultrafiltration (the membrane pore size is 3000D) to obtain Maillard products with different molecular weights.

[0024] Secondly, the low molecular weight Maillard product is concentrated and dried.

[0025] Using absolute ethanol, using a solid-liquid ratio of 1:50, extracting on a shaking table for 30 minutes, distilling under reduced pressure, recovering the organic solvent and drying it for later use, the yield of the highly active component obtained wa...

Embodiment 2

[0027] In this example, glutathione and xylose were used as reaction raw materials. First, the reaction substrates were prepared to concentrations of 1 mol / L and 2 mol / L respectively. The two solutions were mixed in equal volumes, and the pH value was adjusted to 2.5 with NaOH solution.

[0028] Next, the mixed solution was placed in a closed container resistant to high temperature and high pressure, and reacted at a temperature of 120° C. for 2 hours. After the reaction, after the reaction product is cooled, it is classified by ultrafiltration (the membrane pore size is 500D) to obtain Maillard products with different molecular weights.

[0029] Secondly, the low molecular weight Maillard product is concentrated and dried.

[0030] Extraction is carried out with supercritical carbon dioxide fluid, and the yield of highly active components is 23.5%.

Embodiment 3

[0032] In this example, histidine and xylose were used as reaction raw materials. Firstly, the reaction substrates were prepared to concentrations of 2 mol / L and 1 mol / L respectively. The two solutions were mixed in equal volumes, and the pH value was adjusted to 3.5 with NaOH solution.

[0033] Next, the mixed solution was placed in a closed container resistant to high temperature and high pressure, and reacted at a temperature of 130°C for 1.5h. After the reaction, after the reaction product is cooled, it is classified by ultrafiltration (the membrane pore size is 1000D) to obtain Maillard products with different molecular weights.

[0034] Next, the low molecular weight Maillard product is concentrated and dried.

[0035] Using ethanol with a concentration of 50%, using a solid-liquid ratio of 1:30, extracting on a shaking table for 30 minutes, distilling under reduced pressure, recovering the organic solvent and drying it for later use, the yield of the highly active compo...

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PUM

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Abstract

The invention discloses a method for preparing a fruit and vegetable enzymatic browning high-efficiency inhibiting component from a Maillard reaction product. The method mainly comprises the steps that: (1) reducing sugar and dipeptide and derivative thereof or amino acid and derivative thereof with a mass ratio of (0.5-5):1 are subjected to a reaction for 0.5-5h under a pH value of 2-10 and a temperature of 105-150 DEG C, such that a Maillard reaction product is produced; (2) the produced Maillard reaction product is rapidly cooled to room temperature within 0.5h, and is filtered by using a membrane with a pore size of 500-3000Da, such that the Maillard reaction product is divided into a high-molecular-weight part and a low-molecular-weight part; (3) the low-molecular-weight part is concentrated and dried; and (4) after drying, the product is extracted by using a 20-100% ethanol solution; the extract liquid is subjected to reduced-pressure distillation, such that ethanol is recovered, and a high-activity component is obtained; or extraction is carried out by using supercritical carbon dioxide, such that the high-activity component is directly obtained. The method is non-toxic, non-sulfur, and safe. The preparation time is short, and the method is suitable for industrialized productions. With the high-efficiency component, enzymatic browning of fruit and vegetable prone to browning in fresh-keeping and processing can be effectively controlled.

Description

technical field [0001] The invention relates to a preparation method of an efficient inhibitory component for enzymatic browning of fruits and vegetables, in particular to a method for preparing an efficient inhibitory component for enzymatic browning of a food system based on Maillard reaction coupling ultrafiltration and extraction technology. Background technique [0002] The average loss rate of fruits and vegetables in my country is 25%, which is much higher than 5% in developed countries. Enzymatic browning is one of the important causes of loss during preservation and processing of many fruits and vegetables such as bananas, apples, pears, mushrooms, potatoes, and lotus roots. Enzymatic browning is a phenomenon in which phenolic substances in fruits and vegetables are oxidized to quinones and form melanin under the action of polyphenol oxidase (PPO). Inhibiting the enzymatic browning of fruits and vegetables is of great significance to maintaining their commodity val...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A23B7/154
Inventor 袁德宝李芬芳金志强谭琳
Owner HAIKOU EXPERIMENTAL STATION CHINESE ACAD OF TROPICAL AGRI SCI