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Preparation method of nanometer sio2/cellulose composite separation membrane

A cellulose and separation membrane technology, used in semi-permeable membrane separation, chemical instruments and methods, membrane technology, etc., can solve the problems of uneven dispersion of matrix materials, unsatisfactory modification effect, and high chemical reactivity, etc. The effect of uniform internal structure distribution, improved film strength and uniformity, and improved mechanical properties

Active Publication Date: 2015-07-29
OLANSI HEALTHCARE CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

nano-SiO 2 It has the characteristics of many surface defects, small particle size, high purity, large specific surface, high surface energy, and high chemical reactivity, so a single nano-SiO 2 Particles are prone to agglomeration when they are in contact with each other, and the dispersion in the matrix material is not uniform, and the modification effect is not ideal

Method used

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  • Preparation method of nanometer sio2/cellulose composite separation membrane
  • Preparation method of nanometer sio2/cellulose composite separation membrane
  • Preparation method of nanometer sio2/cellulose composite separation membrane

Examples

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Effect test

Embodiment 1

[0037] Nano SiO of this embodiment 2 The preparation method of / cellulose composite separation membrane includes the following steps:

[0038] (1) Dissolve cellulose in ionic liquid to form casting film: mix fully dried cotton pulp with ionic liquid 1-ethyl-3-methylimidazole acetate, and dissolve at 90°C for 2h to prepare Into a casting liquid with a mass fraction of 4%.

[0039] (2) Preparation of nano-SiO 2 : Mix tetraethylorthosilicate and ethanol thoroughly at a volume ratio of 1:25 to obtain a reaction solution; add 25% ammonia water to the reaction solution, stir at room temperature for 1 min, and then at 60°C for 20 hours Transparent SiO 2 Gel solution; the volume of the reaction solution is 4% of the volume of ammonia; the obtained gel solution is heated and evaporated to obtain a gel, which is dried at 80° C. for 20 hours to obtain white nano SiO 2 powder.

[0040] (3) Use the silane coupling agent γ-(2,3-glycidoxy) propyl trimethoxy silane on the nano SiO 2 Modification: A...

Embodiment 2

[0052] Nano SiO of this embodiment 2 The preparation method of / cellulose composite separation membrane includes the following steps:

[0053] (1) Dissolve cellulose in ionic liquid to form casting film: mix fully dried cotton pulp with ionic liquid 1-ethyl-3-methylimidazole acetate, and dissolve at 80℃ for 2h to prepare Into a casting liquid with a mass fraction of 3%.

[0054] (2) Preparation of nano-SiO 2 : Mix tetraethyl orthosilicate and ethanol at a volume ratio of 1:50 to obtain a reaction solution; add 30% ammonia water to the reaction solution, stir at room temperature for 1 min, and then at 75°C for 25 hours Transparent SiO 2 Gel solution; the volume of the reaction solution is 9.3% of the volume of ammonia; the obtained gel solution is heated and evaporated to obtain a gel, which is dried at 100 ℃ for 25 hours to obtain white nano SiO 2 powder.

[0055] (3) Use the silane coupling agent γ-(2,3-glycidoxy) propyl trimethoxy silane on the nano SiO 2 Modification: Add 25mL of...

Embodiment 3

[0058] Nano SiO of this embodiment 2 The preparation method of / cellulose composite separation membrane includes the following steps:

[0059] (1) Dissolve cellulose in ionic liquid to form casting film: mix fully dried cotton pulp with ionic liquid 1-ethyl-3-methylimidazole acetate and dissolve it at 100°C for 3 hours to prepare Into a casting liquid with a mass fraction of 5%.

[0060] (2) Preparation of nano-SiO 2 : Mix tetraethyl orthosilicate and ethanol thoroughly at a volume ratio of 1:40 to obtain a reaction solution; add 25% ammonia water to the reaction solution, stir at room temperature for 3 minutes, and then at 45°C for 15 hours Transparent SiO 2 Gel solution; the volume of the reaction solution is 1.8% of the volume of ammonia; the obtained gel solution is heated and evaporated to obtain a gel, which is dried at 60° C. for 15 hours to obtain white nano SiO 2 powder.

[0061] (3) Use the silane coupling agent γ-(2,3-glycidoxy) propyl trimethoxy silane on the nano SiO 2 ...

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Abstract

The invention discloses a preparation method of nano-SiO2 / cellulose composite separating membranes, which comprises the following steps: (1) dissolving cellulose in ionic liquid so as to form a membrane-casting solution; (2) preparing nano-SiO2; (3) carrying out modification on the nano-SiO2 by using a silane coupling agent gamma-(2, 3-epoxy propoxy) n-propyltrimethoxysilane; and (4) dispersing the modified nano-SiO2 in the membrane-casting solution obtained in sep (1) so as to obtain a mixed membrane-casting solution; and preparing the mixed membrane-casting solution into a membrane and drying the membrane so as to obtain a nano-SiO2 / cellulose composite separating membrane. According to the invention, the dispersion and uniformity of nano-SiO2 particles in cellulose membranes are improved, and the mechanical strength and thermal stability of the cellulose membranes are further enhanced.

Description

Technical field [0001] The invention relates to the technical field of inorganic / organic composite separation membranes, in particular to nano SiO 2 / Cellulose composite separation membrane preparation method. Background technique [0002] As the most abundant natural renewable resource in the world, cellulose has the advantages that other synthetic materials can hardly compare. The traditional natural usable cellulose mainly comes from wood, but my country's wood resources are limited and a large amount of it depends on imports, so the rational development and utilization of other cellulose resources can alleviate the demand for wood resources. However, natural cellulose has the structural characteristics of high crystallinity and a large number of hydrogen bonds between and inside molecules, making it difficult to dissolve in water and common organic solvents. Therefore, cellulose cannot be directly processed into film materials. For a long time, scholars from various countri...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D71/10B01D69/12B01D67/00
Inventor 肖凯军王兆梅刘洋李冰洁
Owner OLANSI HEALTHCARE CO LTD
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