New low-cost oxidation denitrating technology

A low-cost, new process technology, applied in the field of liquid-phase oxidation denitrification process, can solve the problem of high cost of denitrification process, achieve the effects of good absorption effect, easy industrialization implementation, and simple process flow

Active Publication Date: 2013-07-10
陈洪会 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Aiming at the problem of high cost of denitrification process in the prior art, the present invention provides a new low-cost flue gas oxidation denitrification process, using cheap lime water and

Method used

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  • New low-cost oxidation denitrating technology

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Effect test

Embodiment 1

[0034] A new low-cost oxidation denitrification process, the specific steps are as follows:

[0035] A Prepare calcium chlorate solution

[0036] Using lime water and chlorine gas as raw materials, prepare an aqueous solution with a chlorate ion concentration of 50 g / L;

[0037] B Oxidation section

[0038] In the oxidation section, after diluting the prepared aqueous solution, it is sprayed into the oxidation tower from the upper part of the oxidation tower as an oxidant, and countercurrently contacts with the flue gas entering from the lower part, so that the nitrogen oxides in the flue gas are oxidized;

[0039] C absorption section

[0040] In the absorption section, lye is used as the absorbent to spray into the absorption tower from the upper part of the absorption tower to absorb the nitrogen oxides in the oxidized flue gas, generate corresponding nitrite and dissolve in water, so as to achieve the purpose of denitrification.

Embodiment 2

[0042] This embodiment is basically the same as Embodiment 1, on this basis:

[0043] The chlorate ion concentration of described A step is 100g / L.

[0044] After the aqueous solution of described B step is diluted, chlorate ion concentration is 5g / L.

Embodiment 3

[0046] This embodiment is basically the same as Embodiment 1, on this basis:

[0047] The chlorate ion concentration of described A step is 200g / L.

[0048] After the aqueous solution of described B step is diluted, chlorate ion concentration is 50g / L.

[0049] The lye in the C step is lime water with a mass concentration of 0.01%.

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Abstract

The invention provides a new low-cost oxidation denitrating technology aiming at the problem that the denitrating technology in the prior art is high in cost. The new low-cost oxidation denitrating technology comprises the specific steps as follows: A) preparing aqueous solution with chlorate ion concentration of 50-500g/L by taking lime water and chlorine as raw materials; B) in oxidation section, diluting the prepared aqueous solution to serve as an oxidant, and spraying into the oxidation section from the upper part, so as to contact with smoke entering from the lower part reversely and enable nitric oxide in the smoke to have oxidation reaction; and C) in an absorption section, spraying alkali liquor as an absorbent into the absorption section from the upper part to absorb the oxidized nitric oxide in the smoke to produce corresponding nitrite dissolved in water, thereby achieving the denitration purpose. The new low-cost oxidation denitrating technology has the advantages of being simple in technological flow, low in operation cost and the like.

Description

technical field [0001] The invention relates to a liquid-phase oxidation and denitrification process, in particular to a new low-cost flue gas oxidation and denitrification process. Background technique [0002] Flue gas desulfurization and denitrification are used to control coal combustion product SO 2 One of the important methods of NOx and NOx, based on the current situation of the wide application of wet flue gas desulfurization technology in my country, the development of wet synergistic denitrification technology combined with wet desulfurization has broad industrial application prospects. Since 95% of NOx in the flue gas exists in the form of NO with low solubility, the NO is first oxidized into easily absorbed NO before the wet absorption process. 2 At the same time, the oxidant should be cheap and easy to obtain, and the oxidation product can be recycled. These are the keys to the simultaneous wet desulfurization and denitrification technology. [0003] Among the...

Claims

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Application Information

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IPC IPC(8): B01D53/78B01D53/75B01D53/60
Inventor 陈洪会李东林郎治
Owner 陈洪会
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