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Preparation method of hydrocracking catalyst

A hydrocracking and catalyst technology, which is applied in the direction of physical/chemical process catalysts, molecular sieve catalysts, chemical instruments and methods, etc., can solve the problems of low effective utilization of active metals and poor catalyst performance, so as to improve product quality and reduce processing costs. Hydrogen performance, effect of increasing cracking probability

Active Publication Date: 2013-07-10
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] The kneading method can also prepare catalysts with various active metal contents, but the performance of the catalyst prepared by the kneading method is relatively poor, the effective utilization rate of the active metal is low, and the hydrogenation catalyst is rarely prepared by the kneading method in industrial production.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] Take 1000g of alumina dry rubber powder and carry out steam treatment. At a gauge pressure of 0.05MPa, the hydrothermal treatment temperature is 45°C, and the treatment time is 1.5 hours. The water content of the obtained alumina dry rubber powder after hydrothermal treatment is 35wt%. The capacity is 1.1mL / g, and the specific surface area is 440m 2 / g, numbered LA-1.

Embodiment 2

[0042] Take 1000g of alumina dry rubber powder and carry out steam treatment. At a gauge pressure of 0.08MPa, a hydrothermal treatment temperature of 75°C, and a treatment time of 2 hours, the water content of the obtained alumina dry rubber powder after hydrothermal treatment is 43wt%, and the pores The capacity is 1.15mL / g, and the specific surface area is 420m 2 / g, numbered LA-2.

Embodiment 3

[0044] Take 1000g of alumina dry rubber powder and carry out steam treatment. At a gauge pressure of 0.1MPa, the hydrothermal treatment temperature is 90°C, and the treatment time is 3 hours. The water content of the obtained alumina dry rubber powder after hydrothermal treatment is 50wt%. The capacity is 1.17mL / g, and the specific surface area is 415m 2 / g, numbered LA-3.

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Abstract

The invention discloses a preparation method of a hydrocracking catalyst. The preparation method comprises carrying out low-temperature hydro-thermal treatment on alumina dry gel powder, dipping the alumina dry gel powder into a hydrogenation active metal-containing solution, carrying out drying, and carrying out full grinding, molding, drying and calcination of the dipped material with a molecular sieve in the presence of a peptizing agent or a binder. The preparation method improves a catalyst pore structure. The hydrocracking catalyst has a large specific surface area and a large pore volume, is conducive to optimization cooperation of a hydrogenation ingredient and a cracking ingredient, has high catalytic activity, and is suitable for hydrocracking yield-increasing of high-quality heavy naphtha from vacuum distillate having a high dry point and poor quality and for improvement of tail oil product quality.

Description

technical field [0001] The invention relates to a method for preparing a hydrocracking catalyst, in particular to a method for preparing a hydrocracking catalyst for heavy distillate oil. Background technique [0002] Hydrocracking technology has the characteristics of strong adaptability of raw materials, great flexibility of product schemes, high selectivity of target products, good product quality, and high added value. It can directly convert various heavy and low-quality raw materials into clean fuel oil and high-quality chemical raw materials. It has become one of the most important heavy oil deep processing techniques in modern oil refining and petrochemical industries, and has been increasingly widely used at home and abroad. Although the processing capacity of my country's existing hydrocracking units has exceeded 50.0Mt / a, due to the deterioration of domestic crude oil quality year by year, the import of high-sulfur crude oil has increased significantly, and enviro...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J29/16C10G47/20
Inventor 刘昶王凤来杜艳泽赵红关明华
Owner CHINA PETROLEUM & CHEM CORP
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