Branched nanostructures for battery electrodes
By using branched nanostructures and electroactive coatings in lithium-ion batteries, the degradation problem of silicon thin films caused by stress expansion in lithium-ion batteries is solved, achieving more efficient and longer-lasting energy storage.
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[0052] The anode substrate material for Li-ion batteries consists of silicon nanowires grown by a vapor-liquid-solid (VLS) growth process in which the catalyst used is nickel.
[0053] At a base pressure of 1x10 -6 The nickel catalyst layer was deposited on the current collector foil (using stainless steel foil) in a Physical Vapor Deposition (PVD) electron beam evaporator and sampled at room temperature. The deposited nickel layer is approximately 15nm thick and has a purity of 99%.
[0054] The sampling samples were placed inside a horizontal hot-wall chemical vapor deposition (CVD) furnace, where the current collector substrate and catalyst layer were heated to 500 °C under a flow of 200 sccm argon and a reference pressure of 100 Torr. The high temperature causes the catalyst layer to transform into a liquid phase and aggregate into liquid globules. After the temperature stabilized at 500°C, the argon flow of 200 sccm and the reference pressure of 100 Torr were maintained...
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