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Coating and conductive resin of film zinc coat

A conductive resin, coating galvanizing technology, applied in coatings, anti-corrosion coatings, etc., can solve the problems of unsatisfactory anti-corrosion performance, weak active cathodic protection, insufficient conductivity of coating galvanized products, etc., and achieve excellent adhesion , Improve the roughness of the substrate and the effect of strong adhesion

Active Publication Date: 2013-08-28
HUNAN JINPAN NEW MATERIAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, due to the defects in the selection of resin and resin-coated zinc powder technology in the existing coated galvanized products, the electrical conductivity of the coated galvanized products is insufficient, the active cathodic protection is weak, and the anti-corrosion performance is still unsatisfactory.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] The cladding and conductive resin of the coated film galvanized of the present embodiment are made by the following methods:

[0028] (1) Preparation of graphene oxide / acrylate copolymer

[0029] a. Weigh 350kg of organic solvent xylene, 440kg of methyl methacrylate, 80kg of hydroxybutyl acrylate, 70kg of hydroxyethyl methacrylate, 30kg of functional monomer hydroxyethyl methacrylate phosphate, initiator peroxygen-2- tert-butyl ethylhexanoate 20kg, graphene oxide 10kg;

[0030] b. Add the organic solvent and graphene oxide of the weighed formula amount of 75wt% into the reaction kettle A, and stir evenly;

[0031] c. The methyl methacrylate, hydroxybutyl acrylate, hydroxyethyl methacrylate, functional monomer hydroxyethyl methacrylate phosphate, the initiator peroxy-2-ethyl After the tert-butyl hexanoate is mixed evenly, add it to the dripping tank B;

[0032] d. In the stirring state, add the mixed monomer in the dropping tank B to the reaction kettle A dropwise...

Embodiment 2

[0038] The cladding and conductive resin of the coated film galvanized of the present embodiment are made by the following methods:

[0039] (1) Preparation of graphene oxide / acrylate copolymer

[0040] a. Weigh 400kg of organic solvent xylene, 350kg of methyl methacrylate, 100kg of hydroxybutyl acrylate, 100kg of hydroxyethyl methacrylate, 20kg of functional monomer hydroxyethyl methacrylate phosphate, initiator peroxy-2- tert-butyl ethylhexanoate 15kg, graphene oxide 15kg;

[0041]b. Add the organic solvent and graphene oxide of the weighed formula amount of 75wt% into the reaction kettle A, and stir evenly;

[0042] c. The methyl methacrylate, hydroxybutyl acrylate, hydroxyethyl methacrylate, functional monomer hydroxyethyl methacrylate phosphate, the initiator peroxy-2-ethyl After the tert-butyl hexanoate is mixed evenly, add it to the dripping tank B;

[0043] d. In the stirring state, add the mixed monomer in the dropping tank B to the reaction kettle A dropwise a...

Embodiment 3

[0049] The cladding and conductive resin of the coated film galvanized of the present embodiment are made by the following methods:

[0050] (1) Preparation of graphene oxide / acrylate copolymer

[0051] a. Weigh 300kg of organic solvent xylene, 500kg of methyl methacrylate, 50kg of hydroxybutyl acrylate, 80kg of hydroxyethyl methacrylate, 40kg of functional monomer hydroxyethyl methacrylate phosphate, initiator peroxygen-2- tert-butyl ethylhexanoate 25kg, graphene oxide 5kg;

[0052] b. Add the organic solvent and graphene oxide of the weighed formula amount of 75wt% into the reaction kettle A, and stir evenly;

[0053] c. The methyl methacrylate, hydroxybutyl acrylate, hydroxyethyl methacrylate, functional monomer hydroxyethyl methacrylate phosphate, the initiator peroxy-2-ethyl After the tert-butyl hexanoate is mixed evenly, add it to the dripping tank B;

[0054] d. In the stirring state, add the mixed monomer in the dropping tank B to the reaction kettle A dropwise ...

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Abstract

The invention discloses a coating and conductive resin of a film zinc coat, which is prepared by the following steps of: weighing an organic solvent, methyl methacrylate, hydroxybutyl acrylate, hydroxyethyl methylacrylate, hydroxyethyl methacrylate phosphate, tert-butyl peroxy-2-ethylhexanoate and graphene oxide; adding 3 / 4 of the organic solvent and the graphene oxide into a reaction kettle A and mixing uniformly; uniformly mixing the methyl methacrylate, hydroxybutyl acrylate, hydroxyethyl methylacrylate, hydroxyethyl methacrylate phosphate and 3 / 4 of the tert-butyl peroxy-2-ethylhexanoate, dropwise adding the mixture into a dropwise adding tank B, and then dropwise adding into the reaction kettle A; uniformly mixing the residual organic solvent and tert-butyl peroxy-2-ethylhexanoate, dropwise adding the mixture into the dropwise adding tank B, then dropwise adding into the reaction kettle A at 113-118 DEG C, preserving heat for 0.8-1.2 hours, cooling and filtering; and performing ultrasonic treatment, adding hydrazine hydrate for reaction, filtering, washing and drying. The prepared film zinc coat has better corrosion resistance.

Description

technical field [0001] The invention relates to a coating and galvanized resin, in particular to a one-component acrylate modified graphene coating and conductive resin. Background technique [0002] Coated galvanized products (also known as zinc-based coating or cold galvanized products on the market), with its new, long-term, environmentally friendly and convenient steel structure anti-corrosion technology, especially in steel structure maintenance, show outstanding advantages. It not only inherits the advantages of traditional electrogalvanizing, thermal spraying zinc and zinc-rich coatings, but also overcomes their shortcomings. The dry film metal zinc content can be as high as 96%, and it has dual protection functions of cathodic protection and barrier protection, and has good application prospect. [0003] However, due to the defects in the selection of resin and resin-coated zinc powder technology in the existing coated galvanized products, the electrical conductivit...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/14C08F220/28C08F220/04C08K3/04C08F8/30C09D133/12C09D5/10
Inventor 廖有为杨焰车轶材廖阳飞王文曾凡涌
Owner HUNAN JINPAN NEW MATERIAL TECH CO LTD
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