High-strength magnesium-lithium alloy and preparation method thereof

A magnesium-lithium alloy, high-strength technology, applied in the field of magnesium-based alloy preparation, can solve the problems of limited β-phase strengthening effect, influence on alloy strength, thermal stability and corrosion resistance, and increase in alloy cost, so as to facilitate commercialization Application, improvement of corrosion resistance and thermal stability, effect of reducing alloy cost

Inactive Publication Date: 2015-05-27
HARBIN ENG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the Li content of these two types of alloys is relatively high. Although the high Li content ensures that the alloy has good plasticity, it will inevitably cause an increase in the cost of the alloy, and it will also affect the strength, thermal stability and corrosion resistance of the alloy.
In addition, the traditional deformation treatment process (such as: extrusion, rolling, etc.) has very limited strengthening effect on the β phase, which leads to the fact that the β phase or α+β dual-phase magnesium-lithium alloy will not be greatly improved in the subsequent deformation treatment. increase strength

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] The chemical composition (mass percentage) of the alloy is: Li: 4.6%, RY: 2.4%, Zn: 0.8%, the total amount of unavoidable Fe, Cu, Ni, Si and other impurities is less than 0.03%, and the balance is Mg.

[0024] The casting and processing techniques for preparing alloys are:

[0025] First, weigh the material according to the proportion, add Mg, Li, Zn and Mg-RY master alloy into the graphite crucible of the vacuum induction melting furnace, evacuate to 0.01MPa, and then fill it with argon. The melting process has been carried out under the protection of argon atmosphere. The melting temperature is 660°C. The smelted melt is cast into an iron mold to obtain an as-cast alloy.

[0026] Main hot extrusion process parameters: 2 passes of extrusion are used in this embodiment.

[0027] The as-cast alloy is subjected to homogenization treatment before extrusion: the homogenization temperature is 320° C., the holding time is 5 hours, and the cooling method is air cooling.

...

Embodiment 2

[0034] The chemical composition (mass percentage) of the alloy is: Li: 5.0%, RY: 3.2%, Zn: 0.8%, the total amount of unavoidable Fe, Cu, Ni, Si and other impurities is less than 0.03%, and the balance is Mg.

[0035] The casting and processing techniques for preparing alloys are:

[0036] First, weigh the material according to the proportion, add Mg, Li, Zn and Mg-RY master alloy into the graphite crucible of the vacuum induction melting furnace, evacuate to 0.01MPa, and then fill it with argon. The melting process has been carried out under the protection of argon atmosphere. The melting temperature is 700°C. The smelted melt is cast into an iron mold to obtain an as-cast alloy.

[0037] Main hot extrusion process parameters: 2 passes of extrusion are used in this embodiment.

[0038] The as-cast alloy is subjected to homogenization treatment before extrusion: the homogenization temperature is 320° C., the holding time is 6 hours, and the cooling method is air cooling.

...

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Abstract

The invention provides high-strength magnesium-lithium alloy and a preparation method thereof. Commercial pure Mg, commercial pure Li, commercial pure Zn, Mg-RY middle alloy are taken as materials; the high-strength magnesium-lithium alloy is prepared from the materials by mass percent: 4.5-5.5% of Li, 2.0-3.8% of RY, 0.2-1.0% of Zn, less than 0.03% of gross of inevitable Fe, Cu, Ni and Si impurities, and the balance of Mg in a mixing manner according to the ratio. The preparation method comprises the steps of: based on commercial pure Mg, commercial pure Li, commercial pure Zn, Mg-RY middle alloy as materials, mixing the following components in percentage by mass: 4.5-5.5% of Li, 2.0-3.8% of RY, 0.2-1.0% of Zn, less than 0.03% of gross of inevitable Fe, Cu, Ni and Si impurities, and the balance of Mg; smelting in a vacuum induction smelting furnace, wherein the inside of the furnace is vacuumized before smelting, and then aerating argon is aerated to protect, the smelting process is carried out under protection of argon atmosphere, and the smelting temperature is 660-750 DEG C; casting the smelted melt into a metal die to obtain as-cast alloy; carrying out hot extrusion for at least twice to obtain the high-strength magnesium-lithium alloy. The obtained alloy disclosed by the invention has high strength and good plasticity; the tensile strength at room temperature is 220-260 MPa; the yield strength is 180-220MPa; the elongation percentage is 15-25%.

Description

technical field [0001] The invention relates to a magnesium-based alloy, and the invention also relates to a preparation method of the magnesium-based alloy. Background technique [0002] Magnesium-lithium alloy is the lightest metal structural material. It has the advantages of low density, high specific strength and specific stiffness, good shock absorption, and easy cutting. It is considered to be the best material for lightweight production of spacecraft and automobiles. [0003] At present, there are mainly three grades of magnesium-lithium alloys that have been industrially used in the world; MA21, MA18 and LA141, but the strength of these three magnesium-lithium alloys is not very high. Therefore, increasing the strength of Mg-Li alloys is an important issue. In the patent document with application number 200410096186.1, a lithium-containing magnesium alloy material and its preparation method are disclosed. Alloying elements such as Al, RE, Zn, and Zr are used to str...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C23/00C22C1/02C22F1/06
Inventor 张景怀冷哲郭旭英张丽林华益费鹏飞尹婷婷张密林巫瑞智
Owner HARBIN ENG UNIV
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