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A kind of melamine modified hectorite emulsifier and the method for emulsifying ASA thereof

An emulsifier emulsifying, melamine technology, applied in the direction of adding water repellent, textile and papermaking, fiber raw material treatment, etc., can solve the problem of poor hydrolytic stability of ASA emulsion, poor sizing effect of ASA emulsion, and low efficiency of hectorite modification problems, to achieve the effect of easy operation, high sizing efficiency and improved sizing efficiency

Active Publication Date: 2016-01-06
山东熙来淀粉有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to overcome the current problems of using modified hectorite to stabilize the ASA emulsion sizing agent: low modification efficiency of hectorite, poor hydrolytic stability of ASA emulsion, complicated emulsification steps or poor ASA emulsion or sizing effect, The invention provides a melamine modified laponite emulsifier

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Add 1 part hectorite powder gradually to preheated to 60°C with constant stirring o C in 100 parts of deionized water, after uniform dispersion, cooled to room temperature, directly used as the water phase. Take 50 parts of ASA (octadecenyl succinic anhydride) as the oil phase. Add the water phase prepared above into the oil phase under stirring, and use high-speed emulsification and shearing equipment to stir and emulsify at a speed of 1000 rpm for 10 minutes to obtain an oil-in-water ASA emulsion. The mass percentage of ASA in the emulsion is About 33%, after the emulsion was left for 24 hours, the water phase precipitated out at the bottom.

[0034] Take 100 parts and the degree of beating is about 42 o SR poplar bleached thermomechanical pulp was added to 9900 parts of water, and after being decomposed by a fiber deflagging machine, 1 part of Al was added 2 (SO 4 ) 2 ?18H 2 O, mix and stir for 1 minute, add 1 part of the ASA emulsion sizing agent prepared abov...

Embodiment 2

[0037] Add 1 part hectorite powder gradually to preheated to 60°C with constant stirring o 50 parts of deionized water of C, after uniform dispersion, cooled to room temperature; 0.1 part of melamine was dissolved in 50 parts of deionized water under stirring, and mixed with the above hectorite dispersion liquid as the water phase; 50 parts of ASA ( octadecenyl succinic anhydride) as the oil phase. Add the water phase prepared above into the oil phase under stirring, and use high-speed emulsification and shearing equipment to stir and emulsify at a speed of 1000 rpm for 10 minutes to obtain a stable and uniform oil-in-water ASA emulsion. The mass percentage of ASA was about 33%, and the appearance of the emulsion did not change after standing for 24 hours.

[0038] Take 100 parts and the degree of beating is about 42 o SR poplar bleached thermomechanical pulp was added to 9900 parts of water, and after being decomposed by a fiber deflagging machine, 1 part of Al was added 2...

Embodiment 3

[0041] Gradually add 0.5 parts of hectorite powder to the preheated to 40 o 40 parts of deionized water of C, after uniform dispersion, cooled to room temperature; 0.005 parts of melamine was dissolved in 10 parts of deionized water under stirring, and mixed with the above laponite dispersion as the water phase; another 50 parts of ASA (hexadecenyl succinic anhydride) as the oil phase. Add the above-prepared water phase into the oil phase under stirring, and use high-speed emulsification and shearing equipment to stir and emulsify at a speed of 7500 rpm for 3 minutes to obtain a stable and uniform oil-in-water ASA emulsion. The mass percentage of ASA is about 50%, and the appearance of the emulsion does not change after standing for 24 hours.

[0042] Take 100 parts and the degree of beating is about 40 o SR poplar alkaline hydrogen peroxide mechanical pulp was added to 9900 parts of water, and after being decomposed by a fiber disintegrating machine, 1 part of Al 2 (SO 4 ...

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Abstract

The invention relates to a melamine-modified hectorite emulsifier and a method for emulsifying ASA (Acetyl Salicilic Acid) by using the emulsifier, belonging to the technical field of emulsification of a paper-making sizing agent. The melamine-modified hectorite emulsifier is composed of melamine and hectorite which independently exist. The method for emulsifying the ASA by the emulsifier comprises the following steps of: respectively dispersing and dissolving the hectorite and the melamine in deionized water, then uniformly mixing; and then, uniformly mixing with the ASA. The melamine has high modifying efficiency to the hectorite, so that the stability of the hectorite to an ASA emulsion can be greatly improved by using a little melamine to modify the hectorite. The ASA sizing emulsion which is stabilized by adopting the melamine-modified hectorite emulsifier has good stability, does not generate particle aggregation, precipitation or separates out a water phase after being placed for 24 hours, is not easily hydrolyzed, does not change very much in sizing performance after being placed for 3 hours, and is high in sizing efficiency; relative to the ASA emulsion which is independently stabilized by the hectorite, the sizing efficiency is greatly improved.

Description

technical field [0001] The invention relates to a melamine-modified hectorite emulsifier and a method for emulsifying ASA, and belongs to the technical field of paper-making sizing agent emulsification. Background technique [0002] ASA is the abbreviation of alkenyl succinic anhydride (alkenylsuccinicanhydride), which is often used as an internal pulp sizing agent in the paper industry to improve the water resistance of paper. ASA has the advantages of high reactivity, wide pH range, good compatibility with aluminum salts, and non-slip paper. Compared with other reactive sizing agents such as AKD (alkyl ketene dimer), ASA has more advantages in sizing paper and cardboard containing various high-yield pulp, secondary fiber pulp and straw pulp. Therefore, its The application in the paper industry will become more and more extensive. [0003] Papermaking often uses water as the medium, and ASA is an oily liquid that needs to be emulsified into an oil-in-water emulsion before...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D21H21/16D21H17/14
Inventor 刘温霞谭华张伟王慧丽王哲
Owner 山东熙来淀粉有限公司