A preparation method of treated copper foil with porous structure on the surface
A porous structure and surface treatment technology, applied in the field of copper foil materials, can solve the problems of low bonding strength of resin substrates, difficulty in meeting higher product quality and performance, and small specific surface area, so as to improve quality and performance, and controllable porous structure And even, the effect of increasing the specific surface area
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Embodiment 1
[0019] The conventional chemical corrosion method is used to perform surface dealloying treatment on the surface-treated copper foil with the tin-zinc alloy layer as the anti-oxidation passivation layer. Dilute 98% concentrated sulfuric acid to 1g / l, prepare sulfuric acid solution, and prevent oxidation of tin-zinc alloy under the conditions of 0° and temperature of 40°C between the surface of tin-zinc alloy anti-oxidation passivation layer and the surface of sulfuric acid solution The surface layer of the passivation layer is subjected to a dealloying treatment for 600 s, and a porous layer with a submicron-scale porous structure is prepared on the surface layer to obtain a treated copper foil with a sub-micron-scale porous structure on the surface. Then wash with deionized water. On this basis, the KH-550 silane coupling agent was formulated into a 1% concentration dilute solution, and a thin layer of silane coupling agent layer was immersed on the surface of the porous layer...
Embodiment 2
[0021] The conventional chemical corrosion method is used to perform surface dealloying treatment on the surface-treated copper foil with the tin-zinc alloy layer as the anti-oxidation passivation layer. Dilute 98% concentrated sulfuric acid to 3g / l, prepare a sulfuric acid solution, and prevent oxidation of the tin-zinc alloy under the conditions of an angle of 180° between the surface of the tin-zinc alloy anti-oxidation passivation layer and the surface of the sulfuric acid solution and a temperature of 30°C The surface layer of the passivation layer is subjected to a dealloying treatment for 800 s, and a porous layer with a sub-micron-scale porous structure is prepared on the surface layer to obtain a treated copper foil with a sub-micron-scale porous structure on the surface. Then wash with deionized water. On this basis, the KH-550 silane coupling agent was formulated into a 0.5% concentration dilute solution, and a thin layer of silane coupling agent layer was immersed o...
Embodiment 3
[0023] The conventional chemical corrosion method is used to perform surface dealloying treatment on the surface-treated copper foil with the tin-zinc alloy layer as the anti-oxidation passivation layer. Dilute 98% concentrated sulfuric acid to 5g / l, prepare sulfuric acid solution, and prevent oxidation of tin-zinc alloy under the condition that the surface of tin-zinc alloy anti-oxidation passivation layer and the surface of sulfuric acid solution form an angle of 90° and the temperature is 20°C. The surface layer of the passivation layer is subjected to a dealloying treatment for 1200s, and a porous layer with a sub-micron-scale porous structure is prepared on the surface layer to obtain a treated copper foil with a sub-micron-scale porous structure on the surface.
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