A system and method for wet desulfurization and denitrification

A desulfurization, denitrification and wet desulfurization technology, applied in the field of flue gas purification, can solve the problems of lack of denitration function, etc., and achieve the effects of low investment cost, inhibition of ammonia escape and aerosol generation, and low reaction temperature

Active Publication Date: 2016-01-06
ZHONGYE-CHANGTIAN INT ENG CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0014] In order to obtain high-quality ammonium sulfate in the traditional wet ammonia desulfurization system, air is usually blown into the desulfurization tower directly through the oxidation fan to oxidize the ammonium sulfite in the absorption liquid into ammonium sulfate. Due to the lack of sufficient denitrification agent in the absorption liquid — Ammonium sulfite, so there is basically no denitrification function

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  • A system and method for wet desulfurization and denitrification

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Effect test

Embodiment 1

[0047] Desulfurization and denitrification system ( figure 1 ), including desulfurization and denitrification tower 9 and desulfurization tower 4, the two towers are connected by pipelines;

[0048] A desulfurization tower oxidation blower 5 is arranged outside the desulfurization tower 4, which is connected with the desulfurization tower through pipelines. The air intake position of the oxidation fan is below the liquid level.

[0049] The desulfurization and denitrification tower 9 is provided with a flue gas inlet in the middle (entered through the booster fan 10) and an outlet at the top of the tower, which are connected to the flue gas inlet in the middle of the desulfurization tower through pipes; Connect ammonia storage tank 7 with ammonia delivery pump 8; the ammonium sulfate absorption solution outlet at the bottom of the desulfurization tower is connected with the ammonium sulfate absorption solution inlet at the bottom of the desulfurization and denitrification tow...

Embodiment 2

[0054] A certain sintering flue gas temperature is 120°C, where SO 2 The concentration is 1200mg / Nm 3 , NO x The concentration is 130mg / Nm 3 , after entering the desulfurization and denitrification system of embodiment 1, it first enters the desulfurization and denitrification tower 9 from the middle, and the flue gas to be purified is in contact with the three-layer spray absorption liquid from bottom to top, and then purified by the demister 15, from The discharge from the top of the desulfurization and denitrification tower 9 enters the middle of the desulfurization tower 4 through the connecting pipe between the desulfurization and denitrification tower 9 and the desulfurization tower 4 . The absorption liquid in the desulfurization and denitrification tower 9 is mainly a mixture of ammonium sulfite and ammonium sulfate, and the pH is adjusted to 5.0 with ammonia water. The liquid-gas ratio is controlled to be 4L / m by the circulation pump 11 of the desulfurization and d...

Embodiment 3

[0058] A certain sintering flue gas temperature is 145°C, where SO 2 The concentration is 3400mg / Nm 3 , NO x The concentration is 280mg / Nm 3 After entering the desulfurization and denitrification system (Example 1), it first enters the desulfurization and denitrification tower 9 from the middle, and the flue gas to be purified is in contact with the three-layer spray absorption liquid from bottom to top, and then purified by the demister 15. It is discharged from the top of the desulfurization and denitrification tower 9, and enters the middle part of the desulfurization tower 4 through the connecting pipe between the desulfurization and denitrification tower 9 and the desulfurization tower 4. The absorption liquid in the desulfurization and denitrification tower 9 is mainly a mixture of ammonium sulfite and ammonium sulfate, and the pH is adjusted to 4.8 with ammonia water. The gas ratio is controlled to 8L / m by the circulation pump 11 of the desulfurization and denitrific...

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Abstract

The invention provides a system for wet desulfurization and denitrification. The system comprises a desulfurization and denitrification tower and a desulfurization tower which are connected through a pipeline, wherein a flue gas inlet, a flue gas outlet, an ammonia water inlet, a process water inlet, an ammonium sulfate absorption liquid inlet and an ammonium sulfite absorption liquid discharge opening are formed in the desulfurization and denitrification tower; a flue gas inlet, a process water inlet, an ammonium water inlet and an ammonium sulfate absorption liquid discharge opening are formed in the desulfurization tower; a chimney is arranged at the top of the desulfurization tower; an oxidation air blower is arranged outside the desulfurization tower; circulating pumps used for circulation of absorption liquid in the towers are arranged outside the desulfurization and denitrification tower and the desulfurization tower respectively. Compared with the traditional wet method, the method provided by the invention can simultaneously perform desulfurization and denitrification, the desulfurization rate is more than 95 percent, and the denitrification rate is more than 40 percent; ammonia escape and aerosol generation amount is less; the by-products can be in resource utilization; the temperature of the denitrification reaction is low, heating treatment is not needed to be performed on the flue gas, and the operation cost is low; compared with other methods for simultaneous desulfurization and denitrification, the method is low in investment and construction cost.

Description

technical field [0001] The invention belongs to the field of flue gas purification, and in particular relates to a system and method for removing sulfur oxides and nitrogen oxides in flue gas. Background technique [0002] At present, there are two main types of sintering flue gas desulfurization and denitrification technologies widely used at home and abroad, one is the combination of wet desulfurization technology and selective catalytic reduction (SCR) denitrification technology; the other is carbon-based material adsorption desulfurization and denitrification technology. [0003] The most commonly used method for wet flue gas desulfurization is the limestone / gypsum method, and the desulfurization efficiency can be as high as 90%. SCR denitrification technology can achieve a denitrification rate of 70% to 90%, but the temperature required by this technology is 250 to 450°C, and the temperature of sintering flue gas is generally 90 to 170°C, which cannot meet the temperatu...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D53/78B01D53/60C01C1/245
CPCY02A50/20
Inventor 魏进超叶恒棣贺新华刘昌齐谢琛李勇
Owner ZHONGYE-CHANGTIAN INT ENG CO LTD
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