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Ceramic silicone rubber and preparation method thereof

A technology for ceramicizing silicone rubber and silicone rubber, applied in the rubber field, can solve the problems of complicated and complicated laying and installation, falling off, and high equipment cost, and achieve the effects of improving the preparation reaction speed, good flexibility and elasticity, and reducing production costs.

Inactive Publication Date: 2014-02-05
常州市沃科科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, magnesia mineral refractory insulated cables have the following disadvantages in manufacturing and application: first, the equipment cost is high, and magnesia mineral refractory insulated cables require special production and processing equipment, which is expensive and the equipment cost is high; second, the production cost High, because the outer sheath of the magnesia mineral refractory insulated cable is all copper, the price of copper is high, making the production cost higher, and it is limited to a certain extent in terms of practical application; Laying, installation and use are inconvenient, because copper sheathed magnesium oxide mineral fire-resistant insulated cables have special requirements in the process of production, processing, transportation, line laying, installation and use, such as the production and processing of magnesium oxide mineral fire-resistant insulated cables cannot be compared with polymer materials Such convenient processing, cumbersome and complicated laying and installation, high cost of raw materials, it is difficult to popularize and apply on a large scale, especially in civil buildings, etc., until now it has not been widely and universally used
[0004] In the production process, the fire-resistant cable wrapped with mica tape needs to be wound in multiple layers. Due to the limitation of process conditions, lap joint defects often occur at the lap joints. The fire-resistant effect is reduced, and the circuit is short-circuited, making it difficult to ensure the safety and smoothness of power and communication in case of fire.

Method used

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Effect test

preparation example Construction

[0058] The ceramic silicone rubber of the present embodiment has two preparation methods, and the first preparation method includes the following steps:

[0059] ① Put 100 parts of the silicone rubber, 1-100 parts of silicon dioxide, 0-30 parts of silicone oil, 0.00001-10 parts of platinum complex and / or platinum compound, and 0-10 parts of coupling agent in the kneader Medium mixing;

[0060] ② Vacuumize the kneader, keep the vacuum at -0.1~-0.04Mpa, and keep the temperature at 100~200°C;

[0061] ③ Add 1 to 150 parts of vitrified powder into the kneader to knead the vitrified powder evenly with the kneaded silicone rubber, silicon dioxide, silicone oil, platinum complex and / or platinum compound, and coupling agent to form a dough Shaped ceramic rubber;

[0062] ④ move the lumpy ceramic rubber out of the kneader and cool it;

[0063] ⑤ Knead the cooled lump-shaped ceramic rubber on an open mill, add 0.1 to 10 parts of vulcanizing agent and knead to form ceramic rubber.

...

Embodiment 1

[0084] Take 100 parts of dimethyl silicone rubber (MQ), 20 parts of silicon dioxide, 1 part of methyl silicone oil, 0.01 part of 1000ppm isopropanol solution of chloroplatinic acid, 0.1 part of KH560 coupling agent, 20 parts of aluminum oxide According to the first preparation method of the ceramic silicone rubber mentioned above, the ceramic silicone rubber is prepared. When the ceramic silicone rubber is vulcanized and molded, add 1 part of 2,5-dimethyl-2,5-bis(tert-butyl peroxide) oxy)hexane.

Embodiment 2

[0086] Take 100 parts of methyl vinyl silicone rubber (VMQ), 100 parts of silicon dioxide, 30 parts of hydroxyl silicone oil, 10 parts of 1000ppm isopropanol solution of chloroplatinic acid, 0.1 part of A171 coupling agent, 150 parts of silicon dioxide According to the first preparation method of ceramic silicone rubber mentioned above, ceramic silicone rubber is prepared. When ceramic silicone rubber is vulcanized and molded, 2 parts of 2,4-dichlorobenzoyl peroxide (commonly known as double-two-four) are added. .

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PUM

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Abstract

The invention discloses ceramic silicone rubber. The ceramic silicone rubber contains the following materials in parts by weight: 100 parts of silicon rubber, 1-100 parts of silica, 0-30 parts of silicone oil, 0.00001-10 parts of platinum in platinum complex or platinum compound, 0-10 parts of coupling agent, 1-150 parts of ceramic powder and 0.01-10 parts of vulcanizing agent. A preparation method of the ceramic silicone rubber comprises the steps of milling the materials in a kneader, vacuumizing, milling uniformly to form lumpish ceramic rubber, cooling, adding the vulcanizing agent, and carrying out open milling, thereby obtaining the ceramic silicone rubber. The ceramic silicone rubber is easy to process and low in production cost and can be ablated into a ceramic-like shell, so as to protect an ablated object from being damaged. According to the ceramic silicone rubber disclosed by the invention, due to the addition of the platinum complex or platinum compound, the sintering temperature for the ceramic silicone rubber can be lowered, and the reaction rate during the preparation of the ceramic silicone rubber can be increased, so that the production efficiency is increased, and the production cost is reduced.

Description

technical field [0001] The invention relates to a rubber, in particular to a ceramicized silicon rubber with a fire-resistant function. Background technique [0002] At present, most fire-resistant and flame-retardant cables use magnesium oxide mineral insulation or mica tape winding to achieve fire-resistant functions. [0003] However, magnesia mineral refractory insulated cables have the following disadvantages in manufacturing and application: first, the equipment cost is high, and magnesia mineral refractory insulated cables require special production and processing equipment, which is expensive and the equipment cost is high; second, the production cost High, because the outer sheath of the magnesia mineral refractory insulated cable is all copper, the price of copper is high, making the production cost higher, and it is limited to a certain extent in terms of practical application; Laying, installation and use are inconvenient, because copper sheathed magnesium oxid...

Claims

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Application Information

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IPC IPC(8): C08L83/04C08L83/07C08L83/06C08K13/02C08K3/36C08K5/14C08K3/22C08K3/26C08K3/34C08K3/38C08K5/098C08K3/32C08K3/40
Inventor 周和平
Owner 常州市沃科科技有限公司
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