Antiglare film, manufacturing method thereof, polarizing plate, image display device, and touch panel member
An anti-glare film and anti-glare layer technology, applied in polarizing elements, optical elements, diffusing elements, etc., can solve the problems of visibility deterioration, darkening of the screen of the display device, and reduction of contrast ratio.
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Embodiment 1
[0385]
[0386] (Preparation of silica dispersion)
[0387] AEROSILR812 (manufactured by AEROSIL Japan Co., Ltd., the average particle size of primary particles is 7nm)
[0388] 10 parts by mass
[0389] 90 parts by mass of ethanol
[0390] After mixing the above materials with a dissolver for 30 minutes, they were dispersed with a high pressure homogenizer (Manton Gaulin). While stirring, 88 parts by mass of dichloromethane was put into the silica dispersion liquid, and stirred and mixed with a dissolver for 30 minutes to prepare a silica dispersion dilution liquid. Filtration was performed with a particulate dispersion diluent filter (Advantec Toyo Co., Ltd.: Polypropylene winding filter (POLYPROPYLENEWOUND CARTRIDGEFILTER) TCW-PPS-1N).
[0391]
[0392] (Glue composition)
[0393] 90 parts by mass of cellulose triacetate
[0394] (Mn=148000, Mw=310000 acetyl substitution degree 2.92)
[0395] 10 parts by mass of aromatic terminal ester plasticizer (2-4)
[0396] 2.5 parts by mass of Ti...
Embodiment 2
[0595]
[0596] The following transparent hard coat coating composition 1 filtered with a polypropylene filter with a pore size of 0.4 μm was coated on the base material film 1 prepared in Example 1 using a microgravure coater, and was dried at a constant speed. After drying at a temperature of 80°C and a deceleration drying zone temperature of 80°C, while purging with nitrogen to achieve an atmosphere with an oxygen concentration of 1.0% by volume or less, an ultraviolet lamp is used to irradiate the part with an illuminance of 100mW / cm 2 , Irradiation 0.25J / cm 2 The coating layer was cured to form a transparent hard coat layer with a dry film thickness of 5 μm.
[0597] After the transparent hard coating layer was formed, it was rolled into a roll to produce a transparent hard coating film 1. The total haze of the clear hard coating film 1 was measured using a measuring machine (NDH2000) manufactured by Nippon Denshoku Industries Co., Ltd., and the result was 0.3%, which was ver...
Embodiment 3
[0639]
[0640] In the production of the anti-glare film 1, the anti-glare layer coating layer composition 1 was applied and provided on both sides, and the double-sided anti-glare film 1 was produced in the same manner except that the anti-glare layer coating layer composition 1 was applied.
[0641] Next, a transparent conductive film of indium tin oxide (ITO) with a surface resistivity of about 200Ω was formed on one side of the anti-glare layer by sputtering to produce Figure 7 The anti-glare film 1 with a conductive film is shown.
[0642]
[0643] In the production of the anti-glare films 2 to 11, an anti-glare layer was applied on both sides in the same manner as the double-sided anti-glare film 1, except that the double-sided anti-glare films 2 to 11 were produced in the same manner.
[0644] Next, in the same way as the production of the anti-glare film 1 with a conductive film, an anti-glare layer was coated on both sides, and then a sputtering method was used to set the tr...
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Abstract
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