Conductive magnetic permeable textile fabric and preparation method thereof
A textile fabric, conductive and magnetically conductive technology, applied in textiles, papermaking, fiber processing, etc., to achieve the effect of easy mass production, maintaining comfort, and simple process
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[0039] The preparation method of the above-mentioned conductive and magnetic conductive textile fabric of the present invention, the specific steps are:
[0040] 1) Pre-treatment of textile fabrics: First, ultrasonically treat the textile fabrics with organic solvents to remove impurities, then soak them in coupling agent solution at room temperature or in a water bath, and dry them for later use;
[0041] 2) Fe 3 o 4 Disperse evenly in water, add initiator to form Fe 3 o 4 -initiator solution, and then soak the pre-treated textile fabric in Fe 3 o 4 - In the initiator solution, add pyrrole dropwise while stirring, and then stir and react at a temperature not exceeding normal temperature for 4 to 12 hours, wherein the molar ratio of initiator to pyrrole is 1 to 2:1, Fe 3 o 4 The mass ratio of Fe to pyrrole is 1:5 to 5:1, and Fe used per square meter of textile fabrics 3 o 4 The mass is 100g ~ 200g;
[0042] 3) Post-treatment of textile fabrics: washing and drying the ...
Embodiment 1
[0053] Clean the polyester fabric with a size of 5cm×5cm ultrasonically for 30 minutes with acetone and ethanol respectively, take out the fabric and let it dry naturally in a ventilated place; soak the cleaned fabric in 1% ethanol solution of 3-aminopropyltrimethoxysilane , placed in a water bath at 55°C for 2 hours, then taken out and dried; 0.5g Fe 3 o 4 Nanoparticles were dispersed in 50ml deionized water, and 3gFeCl was added 3 ·6H 2 O, ultrasonic (25°C, 90W) dispersion for 30min; then put the silane-treated polyester fabric into the above Fe 3 o 4- FeCl 3 ·6H 2 O solution, sonicate for 10 minutes, add 0.5ml of pyrrole dropwise while stirring, then place the reaction system in an ice-water bath (temperature 5°C) and continue to react for 6h, take out the cloth sample, wash it with water, and dry it in an oven at 80°C.
[0054] The microstructure and macroscopic properties of the obtained conductive magnetic polyester fabric are as follows:
[0055] 1. Conductive ma...
Embodiment 2
[0067] Clean the polyester fabric with a size of 5cm×5cm ultrasonically for 30 minutes with acetone and ethanol respectively, take out the fabric and let it dry naturally in a ventilated place; soak the cleaned fabric in 1% ethanol solution of 3-aminopropyltrimethoxysilane , place it in a water bath at 55°C for 2 hours, take it out and dry it. 0.5g Fe 3 o 4 Nanoparticles were dispersed in 50ml of deionized water, and 3g and 6g of FeCl were added respectively 3 ·6H 2 O, ultrasonic (25°C, 90W) dispersion for 30min; put the silane-treated polyester fabric into the above solution, ultrasonically treat it for 10min, add pyrrole dropwise while stirring, and dissolve 3g and 6gFeCl in the solution 3 ·6H 2 Add 0.5ml and 1.0ml of pyrrole to the solution of O respectively, then place it in a 5°C water bath and shake for 6h, take out the cloth sample, wash it with water, and dry it in an oven at 80°C. Add different PPY vs. PPY / Fe 3 o 4 The effect of coated polyester fabric resistiv...
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