Special solid corrosion and scale inhibitor for oilfield reinjection water

A technology of corrosion and scale inhibitor, oil field re-injection water, applied in descaling and water softening, complex/solubilizer treatment, water/sludge/sewage treatment, etc., can solve the problem of increasing packaging storage sites and managing transportation costs , the concentration of aqueous solution should not be adjusted, and the cost of material transportation will be increased, so as to facilitate packaging, storage, transportation and use, reduce recycling and transportation costs, and achieve good scale inhibition effects.

Active Publication Date: 2014-04-09
SHANDONG HUAYOU CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] 1. Since the dosage form is an aqueous solution, a large number of plastic packaging barrels are required, which leads to high packaging costs and heavy packaging weight
Recycling of packaging is required for this, increasing storage space for packaging and managing transportation costs
[0004] 2. More than 50% of the formula is water, and this part of water is an invalid component, which will increase the transportation cost of materials
[0005] 3. In order to reduce packaging volume and transportation costs, it is usually formulated into a formulation with a high solid content of more than 30%. This formulation is easy to crystallize and solidify in winter in the north, which adds a lot of inconvenience to practical applications
[0011] Although the above inventions have changed the dosage form of the existing corrosion and scale inhibitors, they are mainly for the purpose of slow release and are suitable for downhole treatment of remote oil wells. The advantages are that they can greatly reduce the workload of dosing and increase the stability of scale inhibitors. Disadvantages: ⑴The concentration in the aqueous solution should not be adjusted due to changes in the release rate and water flow, ⑵Due to the slow dissolution rate, it is not suitable for solid dosing equipment for large water treatment

Method used

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  • Special solid corrosion and scale inhibitor for oilfield reinjection water
  • Special solid corrosion and scale inhibitor for oilfield reinjection water
  • Special solid corrosion and scale inhibitor for oilfield reinjection water

Examples

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Embodiment 1

[0036] Embodiment 1, a special solid corrosion and scale inhibitor for oil field reinjection water, is a product made of the following raw materials in the following weight percentages, using the following preparation method:

[0037]

[0038] The preparation method of solid corrosion and scale inhibitor for oilfield reinjection water comprises the following steps:

[0039] (1). Add hydroxyethylidene diphosphonic acid (HEDP), maleic acid-acrylic acid copolymer, and alkylimidazoline corrosion inhibitor into the kneader, and stir evenly at room temperature.

[0040] (2). Add inorganic alkali in batches, neutralize to pH=6~8, after adding, knead and stir at room temperature for 25~30 minutes,

[0041] (3). Heating to 100-130°C, kneading, stirring and drying until the moisture content is 20%-30%,

[0042] (4). The material is shaped and dried by a screw extruder,

[0043] (5). Add zinc sulfate and sodium hexametaphosphate, stir and mix for 25-30 minutes to get the finished pr...

Embodiment 2

[0049] Embodiment 2, a special solid corrosion and scale inhibitor for oilfield reinjection water, is a product made of the following raw materials in the following weight percentages, using the following preparation method:

[0050]

[0051]The preparation method of solid corrosion and scale inhibitor for oilfield reinjection water comprises the following steps:

[0052] (1). Add hydroxyethylidene diphosphonic acid (HEDP), maleic acid-acrylic acid copolymer, and alkylimidazoline corrosion inhibitor into the kneader, and stir evenly at room temperature.

[0053] (2). Add inorganic alkali in batches, neutralize to pH=6~8, after adding, knead and stir at room temperature for 25~30 minutes,

[0054] (3). The material is shaped and dried by a screw extruder,

[0055] (4). Add zinc sulfate and sodium hexametaphosphate, stir and mix for 25-30 minutes to get the finished product.

[0056] The specification requirements of the raw materials used in this embodiment are the same as...

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Abstract

The invention discloses a special solid corrosion and scale inhibitor for oilfield reinjection water and a preparation method thereof, and belongs to a chemical composition for treatment of oilfield water. The invention particularly relates to a composition for corrosion resistance and scale inhibition in oilfield sewage treatment and reinjection processes. The corrosion and scale inhibitor is prepared from the following raw materials: 20%-50% of 40%-60% 1-hydroxyethylidene-1,1-diphosphonic acid (HEDP), 20%-50% of 40%-60% acrylic acid-maleic acid copolymer, 0-10% of 30%-60% alkyl imidazoline inhibitor, 0.1%-10% of zinc sulfate, 3%-40% of inorganic base and 10%-30% of sodium hexametaphosphate. The special solid corrosion and scale inhibitor disclosed by the invention is obtained by the raw materials through processes, such as kneading stirring, evaporating concentrating, shaping, drying and mixing. The inhibitor can be used for the water quality treatment of the oilfield reinjection water of a solid medication system, can be used for effectively reducing the decomposition of sodium hexametaphosphate in the storage period, and has very good corrosion resistance and scale inhibition effects on a reinjection water treatment system and a transportation system.

Description

technical field [0001] The invention belongs to a chemical composition used for oilfield water treatment, in particular to a composition for inhibiting corrosion and scale in the process of oilfield sewage treatment and reinjection. Background technique [0002] Oil production in my country's oilfields has generally entered the third stage, that is, fully mechanized production through reinjection of water to increase ground pressure. Oilfield reinjection water is generally hot water with high salinity, and the water injection system is prone to corrosion and scaling. For this purpose, corrosion and scale inhibitors should be added to the water injection system. The currently used corrosion and scale inhibitors are usually a composite system of organic phosphoric acid, polymeric carboxylic acid and polymeric phosphate, usually an aqueous solution. This system has good limit effect and synergy, and has the advantages of low cost, less dosage, and convenient use, but it also ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F5/08C02F5/10C02F5/14
Inventor 高乾善段丽菊迟斌
Owner SHANDONG HUAYOU CHEM
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