ABS plastic surface metal layers and preparing method thereof

A technology of ABS plastic and surface metal layer, which is applied in the direction of metal layered products, metal material coating technology, chemical instruments and methods, etc., can solve problems such as hazards, poor corrosion resistance, unenvironmental production personnel and environmental products, and achieve The effect of reducing production costs, improving the yield rate, and eliminating harm to the environment

Active Publication Date: 2014-05-14
XIAMEN RUNNER IND CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] One of the purposes of the present invention is to solve the problems existing in the existing ABS plastic electroplating. If copper electroplating and chromium electroplating are required, electroplating copper will lead to poor corrosion resistance of the entire electroplating layer, and a thick nickel layer needs to be plated for corrosion resistance. Protection, electroplating hexavalent chromium, very unenvironmental protection, great harm to production personnel and environmental products, providing a metal layer on the surface of ABS plastic

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] A metal layer on the surface of ABS plastic, the structure of which starts from the ABS plastic layer, chemical nickel layer, 0.05 μm in thickness, impact nickel layer, 1 μm in thickness, semi-gloss nickel layer, 10 μm in thickness, PVD corrosion-resistant alloy layer, The thickness is 0.1 μm, the corrosion-resistant alloy can be zirconium silicon alloy (zirconium silicon atomic composition is zirconium 50 silicon 50), PVD color layer, the thickness is 0.3 μm, and the color layer is zirconium nitride.

[0038] The method of preparing a metal layer on the surface of ABS plastic is as follows:

[0039] 1) Pre-treatment of ABS plastic: chemical degreasing→coarsening→neutralization→catalysis→degelling→chemical nickel;

[0040] 2) ABS plastic electroplating: After the first pretreatment of ABS plastic, perform impact nickel electroplating → semi-bright nickel; perform impact nickel electroplating, use the known impact nickel formula for electroplating, control the thickness ...

Embodiment 2

[0053] A metal layer on the surface of ABS plastic, the structure of which starts from the ABS plastic layer is, chemical nickel layer, 0.5 μm in thickness, impact nickel layer, 3 μm in thickness, semi-gloss nickel layer, 3 μm in thickness, PVD corrosion-resistant alloy layer, The thickness is 0.3 μm, the corrosion-resistant alloy can be chrome-silicon alloy (the atomic composition of chromium silicon is chromium 98 silicon 2), the PVD color layer is 0.1 μm in thickness, and the color layer is zirconium carbide nitrogen.

[0054] The method of preparing a metal layer on the surface of ABS plastic is as follows:

[0055] 1) Pre-treatment of ABS plastic: chemical degreasing→coarsening→neutralization→catalysis→degelling→chemical nickel;

[0056] 2) ABS plastic electroplating: After the first step of pretreatment on ABS plastic, perform impact nickel electroplating → semi-bright nickel; perform impact nickel electroplating, use the known impact nickel formula for electroplating, c...

Embodiment 3

[0070] A metal layer on the surface of ABS plastic, the structure of which starts from the ABS plastic layer is, chemical nickel layer, 0.2 μm in thickness, impact nickel layer, 2 μm in thickness, semi-gloss nickel layer, 3 μm in thickness, PVD corrosion-resistant alloy layer, The thickness is 2 μm, the corrosion-resistant alloy can be nickel-chromium alloy (nickel-chromium atomic composition is nickel 50 chromium 50), PVD color layer, the thickness is 0.2 μm, and the color layer is chrome.

[0071] The method of preparing a metal layer on the surface of ABS plastic is as follows:

[0072] 1) Pre-treatment of ABS plastic: chemical degreasing→coarsening→neutralization→catalysis→degelling→chemical nickel; the process is carried out according to the conventional treatment process in the industry, and the thickness of the chemical nickel layer is 0.2.

[0073] 2) ABS plastic electroplating: After the first pretreatment of ABS plastic, perform impact nickel electroplating → semi-br...

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Abstract

The invention discloses ABS plastic surface metal layers and a preparing method thereof and relates to the field of plastic surface processing. The ABS plastic surface metal layers include a chemical nickel layer, an impact nickel layer, a semi-bright nickel layer, a PVD anticorrosion alloy layer and a PVD color layer which are arranged sequentially from the ABS plastic surface, wherein the chemical nickel layer is 0.05 micron - 0.5 micron thick, the impact nickel layer is 1 micron - 3 microns thick, the semi-bright nickel layer is 3 microns - 10 microns thick, the PVD anticorrosion alloy layer is 0.1 micron - 2 microns thick, and the PVD color layer is 0.1 micron - 0.3 micron thick. The preparing method comprises the steps that ABS plastic preprocessing is conducted, the preprocessed ABS plastic is sequentially electroplated with the impact nickel layer and the semi-bright nickel layer, wiredrawing is conducted on the ABS plastic semi-bright nickel layer, hydrocarbon vacuum degreasing and drying are conducted on the wiredrawn ABS plastic electroplated piece, and then the ABS plastic electroplated piece is plated with the PVD anticorrosion alloy layer and the PVD color layer to achieve the preparation of the metal layers on the ABS plastic.

Description

technical field [0001] The invention relates to plastic surface treatment technology, in particular to a metal layer on the surface of ABS plastic and a preparation method thereof. Background technique [0002] At present, the plastics widely used in automotive electroplating include ABS, PC+ABS and PA. The plastics used in bathroom products mainly include ABS plastics. Plastic electroplating is to adopt a certain processing method. First, obtain a conductive film on the plastic surface, and then use electroplating. thickening process. Therefore, the plastic electroplating process can also be simply divided into two steps. The first step is the pretreatment of plastic electroplating: degreasing → roughening → neutralization → catalysis → degelling → chemical nickel; the second step is plastic electroplating: pre-plating nickel → bright copper → semi-bright nickel → bright nickel → nickel seal → bright chrome. This process will produce a large amount of waste water and heav...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C28/02C23C14/34C23C14/14B32B15/082
CPCC23C14/022C23C14/205C23C14/345C23C14/3485C23C18/1653C23C18/2086C23C18/22C23C18/30C23C28/322C23C28/34C23C28/36C25D5/14C25D5/627Y10T428/12569
Inventor 余水乔永亮张先超李明仁
Owner XIAMEN RUNNER IND CORP
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