Environment-friendly high-temperature-resistant durable flame retardant fibers and preparation method thereof
A flame-retardant fiber and high-temperature-resistant technology, which is applied in the field of environmentally friendly high-temperature-resistant durable flame-retardant fiber and its preparation, can solve the problems of accelerated aging, difficulty, and increased viscosity of viscose glue, and achieve the elimination of alkali washing and desulfurization process, The effect of reducing processing costs and simplifying the process
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Embodiment 1
[0051] An environment-friendly high-temperature-resistant and durable flame-retardant fiber, the raw materials of the flame-retardant fiber include cellulose, a flame retardant, and a cationic crosslinking agent, and the weight fraction ratio of each raw material is:
[0052] Cellulose 65~84
[0053] Flame retardant 16~35
[0054] Cationic crosslinking agent 1~3.
[0055] Further, the degree of polymerization of the cellulose is 600-800.
[0056] Further, the flame retardant is a silicon dioxide nitrogen compound.
[0057] Further, the ionic form of the cationic crosslinking agent is Ti 4+ , RN 3+ 、Al 3+ , Ca 2+ one or a mixture of several.
[0058] Another object of the present invention is achieved through the following technical solutions:
[0059] A method for preparing an environment-friendly high-temperature-resistant and durable flame-retardant fiber, the method comprising the following steps:
[0060] 1) Preparation of viscose collagen solution According to th...
Embodiment 2
[0092] This embodiment is a preferred solution based on Example 1. The quality of the raw materials used is the same as that of Example 1. Please refer to Example 1 for the same parts as in Example 1. The method described in this example includes the following steps:
[0093] Preparation of viscose collagen solution According to the traditional preparation method of viscose collagen solution, cotton (wood) cellulose is prepared by lye hydration, pressing, crushing, aging, sulfonation, one-stage filtration, two-stage filtration, three-stage filtration, and defoaming. Viscose collagen solution (IIIF glue) for spinning. The composition of IIIF glue is required to be: methyl cellulose 8.1-9.8%; sodium hydroxide 5.4-7.8%. The viscosity of IIIF glue is required to be 40-60 seconds (falling ball method); the degree of maturity is 14-16ml (10% ammonium chloride). The flame retardant injection is prepared according to the volume ratio of dispersant: 10% lye: flame retardant = (0.05~0....
Embodiment 3
[0096] This embodiment is a preferred solution based on Example 1. The quality of the raw materials used is the same as that of Example 1. Please refer to Example 1 for the same parts as in Example 1. The method described in this example includes the following steps:
[0097] First prepare viscose collagen solution according to the traditional method of viscose collagen solution preparation. Cotton (wood) cellulose is processed by alkali solution, pressing, crushing, aging, sulfonation, one-stage filtration, two-stage filtration, three-stage filtration, and defoaming. Prepare viscose collagen solution (IIIF glue) for spinning. The composition of IIIF glue is required to be: methyl cellulose 8.1-9.8%; sodium hydroxide 5.4-7.8%. The viscosity of IIIF glue is required to be 40-60 seconds (falling ball method); the degree of maturity is 14-16ml (10% ammonium chloride). The flame retardant injection is prepared according to the volume ratio of dispersant: 10% lye: flame retardant ...
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