Catalytic cracking coupling process for preparing low-carbon olefin and C<5+> hydrocarbon by using organic oxygen-containing compound

A low-carbon olefin, catalytic cracking technology, applied in the field of organic oxygen-containing compound to low-carbon olefin process, organic oxygen-containing compound to low-carbon olefin system field

Active Publication Date: 2014-05-21
CHNA ENERGY INVESTMENT CORP LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method for improving the yield of low carbon olef

Method used

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  • Catalytic cracking coupling process for preparing low-carbon olefin and C&lt;5+&gt; hydrocarbon by using organic oxygen-containing compound
  • Catalytic cracking coupling process for preparing low-carbon olefin and C&lt;5+&gt; hydrocarbon by using organic oxygen-containing compound

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0064] use figure 1 The organic oxygenated compounds shown in the preparation of light olefins with C 5+ Hydrocarbon catalytic cracking coupling system prepares light olefins from methanol, wherein, using the system product gas through figure 2 The process shown in the resulting C 5+ The mixture of hydrocarbon by-products and concentrated sewage containing methanol and dimethyl ether is used as C in this embodiment 1 5+ hydrocarbon feedstock, the C 5+ Hydrocarbon feedstock such as figure 2 Shown is vaporized and heated to around 350°C.

[0065] Set 4 C's on Regenerated Catalyst Delivery Piping 5+ Hydrocarbon inlets, 4 inlets are staggered and arranged oppositely, by controlling the circulation flow of the regenerated catalyst and C 5+ The amount of hydrocarbon injected, so that the regenerated catalyst and C 5+ The weight ratio of hydrocarbons in the regenerated catalyst delivery pipeline is controlled between 0.05-0.15, so that their contact reaction time in the rege...

Embodiment 2

[0068] In addition to changing the process parameters, the experimental process of Example 1 was repeated, and the process parameters and final experimental results used in Example 2 are also shown in Table 1 and Table 2 below.

Embodiment 3

[0070] In addition to changing the process parameters, the experimental process of Example 1 was repeated, and the process parameters used in Example 3 and the final experimental results thereof are also shown in Table 1 and Table 2 below.

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Abstract

The invention discloses a catalytic cracking coupling process for preparing low-carbon olefin and C<5+> hydrocarbon by using an organic oxygen-containing compound. The catalytic cracking coupling process comprises the following steps: converting the organic oxygen-containing compound into the low-carbon olefin under the effect of a catalyst in a reactor for preparing the low-carbon olefin by the organic oxygen-containing compound; in a catalyst regenerator, heating for oxidizing and decarbonizing a waste catalyst which enters the catalyst regenerator through a waste catalyst conveying pipeline from the reactor so as to regenerate a regenerated catalyst; conveying the regenerated catalyst back into the reactor by a regenerated catalyst conveying pipeline; introducing the C<5+> hydrocarbon into the regenerated catalyst conveying pipeline; under the catalytic effect of the catalyst, catalytically cracking the C<5+> hydrocarbon into the low-carbon olefin; and conveying the generated low-carbon olefin and the regenerated catalyst into the reactor by the regenerated catalyst conveying pipeline. According to the process disclosed by the invention, the high temperature of the regenerated catalyst is effectively utilized and the C<5+> hydrocarbon is cracked into the low-carbon olefin to form active hydrocarbon tank species, so as to shorten a reaction induction period, reduce the selectivity of converting the organic oxygen-containing compound into active carbon tank species and improve the yield of the low-carbon olefin.

Description

technical field [0001] The present invention relates to a kind of organic oxygen-containing compound preparation low-carbon olefin and C 5+ Hydrocarbon catalytic cracking coupling process and a process for preparing low-carbon olefins from organic oxygen-containing compounds; at the same time, the present invention also relates to a process for preparing low-carbon olefins from organic oxygen-containing compounds and C 5+ A hydrocarbon catalytic cracking coupling system and a system for producing low-carbon olefins from organic oxygen-containing compounds. Background technique [0002] At present, the production of light olefins from organic oxygen compounds, such as methanol to olefins (MTO), is realized by acidic solid catalyst (SAPO-34). Typically, C converted from organic oxygenates such as methanol 2 –C 3 The conversion of light olefins such as ethylene and propylene can be higher than 78%. However, due to the inevitable formation of C in reaction products such as t...

Claims

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Application Information

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IPC IPC(8): C07C1/20C07C4/06C07C11/04C07C11/06C07C11/08
CPCY02P20/52Y02P20/584Y02P30/20Y02P30/40
Inventor 邢爱华孙琦朱伟平门卓武
Owner CHNA ENERGY INVESTMENT CORP LTD
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