Time-of-flight mass spectrometer

A mass analysis device and time-of-flight technology, applied in the field of grid electrodes, can solve the problems of increasing grid electrodes, reducing ion transmittance, increasing cost, etc. Effect

Active Publication Date: 2014-06-11
SHIMADZU SEISAKUSHO CO LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, in the method described in Patent Document 1, the number of grid-shaped electrodes is increased, so there are problems such as an increase in cost and a decrease in ion transm

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Embodiment Construction

[0059] Hereinafter, an orthogonal acceleration method TOFMS according to an embodiment of the present invention will be described with reference to the drawings. figure 2 It is the overall structure diagram of the orthogonal acceleration method TOFMS of the present embodiment, figure 1 It is an explanatory view and an external perspective view of the manufacturing steps of the grid-shaped electrode 100 used in the orthogonal acceleration method TOFMS of this embodiment.

[0060] The orthogonal acceleration TOFMS of the present embodiment has: an ion source 4, which ionizes the target sample; an ion transport optical system 5, which sends ions into the orthogonal acceleration unit 1; and an orthogonal acceleration unit 1, which ionizes the ion Accelerate and send this ion into TOF type mass separator 2; TOF type mass separator 2, it is equipped with reflector (reflectron) 24; ions; and the orthogonal acceleration power supply unit 6 that applies a predetermined voltage to th...

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Abstract

A thin metal plate (113) and two rectangular rod-shaped metal members (112) that are parallel to each other are alternately superposed repeatedly, and thick metal plates (111) are disposed on both ends of the stack to sandwich the stack. Each surface which is in contact with another surface is bonded thereto by diffusion bonding to form an integrated multilayer structure (110). The multilayer structure (110) is cut at given intervals along planes perpendicular to the thin metal plates (113). Thus, a grid-shaped electrode (100) which has spaces, as openings (102), formed by thin metal plates (113) serving as blades (101) and by metal members (112) as spacers is obtained. With this configuration, it is possible to increase the thickness of the blades (101) to heighten the mechanical strength while keeping the width of the blades (101) and the distance therebetween small. Furthermore, leakage of an electric field from the flight space side to the ion acceleration region side can be inhibited, and the ions which are being introduced can hence be prevented from escaping from the ion acceleration region to the flight space side.

Description

technical field [0001] The present invention relates to a time-of-flight mass spectrometer (Time-of-Flight Mass Spectrometer, hereinafter referred to as "TOFMS"). grid electrodes. Background technique [0002] In TOFMS, ions derived from sample components are given constant kinetic energy to fly a fixed distance in space, the time required for the flight is measured, and the mass-to-charge ratio of the ions is obtained from the flight time. Therefore, when ions are accelerated to start flying, if there is a deviation in the position of the ion and the initial energy of the ion, the time of flight of the ion with the same mass-to-charge ratio will deviate, resulting in a decrease in mass resolution and mass accuracy. . As one of the methods for solving such problems, there is known orthogonal acceleration (also referred to as vertical acceleration, orthogonal traction) that accelerates ions in a direction perpendicular to the incident direction of the ion beam and sends the...

Claims

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Application Information

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IPC IPC(8): H01J49/06G01N27/62H01J49/40
CPCH01J49/403
Inventor 古桥治
Owner SHIMADZU SEISAKUSHO CO LTD
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