Method and device for detecting crystal direction of silicon slice

一种检测方法、硅片的技术,应用在测量装置、半导体/固态器件测试/测量、测试晶体等方向,能够解决不适合全尺寸硅片快速表征、耗时长、成本高等问题

Active Publication Date: 2014-07-16
TRINA SOLAR CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] 1) X-ray diffraction technology (X-Ray diffraction, referred to as XRD), its beam spot diameter is generally several mm, and can only measure the crystal orientation of a single grain of a silicon wafer at a time, which is costly and time-consuming , completely unable to meet the needs of the industry
[0005] 2) Electron backscattered selective diffraction (EBSD for short), which is suitable for micro-area crystal orientation detection, can be used for surface scanning, and its spatial resolution can reach 0.1 μm, but the measurement range is only limited to how many cm 2 , not suitable for rapid characterization of full-scale silicon wafers
The rotary table reflection method disclosed in CN103151283A already has sufficient industrial applicability, but the applicant further found the following improvements in the process of implementing it: the calculation method is a method of comparing with the standard crystal orientation, and the theoretical accuracy limited

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  • Method and device for detecting crystal direction of silicon slice
  • Method and device for detecting crystal direction of silicon slice
  • Method and device for detecting crystal direction of silicon slice

Examples

Experimental program
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Effect test

experiment example 1

[0072] Experimental example 1 uses the method of the present invention to detect silicon wafers with known standard crystal orientations to verify the accuracy of the detection method of the present invention. The steps of Experimental Example 1 and the corresponding experimental data are given below.

[0073] 1. Put a 1cm×2cm standard commercial oriented small silicon wafer in 2.5% volume concentration KOH solution for 3 minutes;

[0074] 2. If Figure 2a As shown in the box in , place it on a rotating stage and collect the rotation curve of the grain point of interest;

[0075] 3. After obtaining the rotation curve, obtain the angle of its extremum, and solve its (111) surface normal vector according to formula 1, the crystal orientation index vector of the grain at this point can be obtained as , which is consistent with the standard The crystal orientation angle difference is less than 1.5°.

experiment example 2

[0077] Experimental example 2 uses the method of the present invention to detect the entire surface of a polycrystalline silicon wafer, and determines the crystal orientation of each crystal grain, thereby knowing the distribution of crystal orientations on the entire polycrystalline silicon wafer surface.

[0078] Experimental example 2 and corresponding experimental data are given below.

[0079] 1. Put the silicon carbide mortar cut polysilicon wafer into the KOH solution with a volume concentration of 2.5% and corrode it for 3 minutes;

[0080] 2. Put the etched silicon wafer on figure 1 Optical measurement is carried out on the device, in which the step angle of the rotary table is 0.1;

[0081] 3. Obtain the reflection spectrum of all crystal grains by digital image processing method;

[0082] 4. Calculate the crystal orientation of the reflectance spectrum according to formula 1 to obtain the precise crystal orientation of all crystal grains. For the convenience of ...

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Abstract

The invention provides a method and device for detecting the crystal direction of a silicon slice. The method includes the steps that an image pickup device which comprises a light source and one or more image pickup probes rotates in different angular directions to irradiate the silicon slice, corresponding reflection strength is acquired, and a reflection curve of interested crystal particles in a polar coordinate system is drawn; pixel brightness extreme values are marked in the reflection curve, the normal directions of three or more faces of regular octahedrons of the crystal particles <111> are determined, then normal vectors of all the regular octahedrons are calculated, and therefore the crystal directions of the interested crystal particles can be calculated.

Description

technical field [0001] The invention relates to a detection method and a detection device for silicon wafer crystal orientation. Background technique [0002] The grain size of solar ingot polycrystalline silicon wafers is generally about 1cm, and the number of single silicon wafer grains is more than 500. Due to the different crystal orientations among the crystal grains, the influence on the subsequent battery process is also different. For example, <100> crystal orientation can obtain pyramid texture with high light-harvesting effect by alkali texturing, while <111> crystal orientation can only obtain texture by acid texturing or other isotropic texturing methods. Different crystal grains have different crystal orientations, and different crystal orientations have different texture characteristics, which in turn produce different surface recombination rates, which affect the performance parameters of the final battery. Therefore, the accurate detection and e...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L21/66
CPCH01L22/12G01N21/4738G01N21/9501G01N21/55G01N2021/8477H04N23/45H04N23/56G01N21/84G06T7/0004G06T2207/10152G06T2207/30148H01L29/045G06T7/10
Inventor 付少永熊震
Owner TRINA SOLAR CO LTD
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