Zinc oxide-based pressure-sensitive ceramic material for lightning arrester as well as preparation method and application of material
A technology of ceramic materials and varistor ceramics, applied in varistors, overvoltage protection resistors, etc., can solve the problems of large leakage current and small nonlinear coefficient, and achieve good product performance, wave absorption ability and high current resistance Strong impact effect
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Embodiment 1
[0044] The commercially available indirect zinc oxide with a purity of 99.7% is used as the main component, and its radius particle size is less than 1 micron. The first subcomponent is commercially available chemically pure Bi 2 o 3 ,Co 2 o 3 , MnO 2 , Cr 2 o 3 , NiO; the second subcomponent is commercially available chemically pure Sb 2 o 3 ; The third component is commercially available chemically pure Y 2 o 3 and WO 3 ; The fourth secondary component is commercially available chemically pure Al 2 o 3 .
[0045] The formula of the pressure-sensitive ceramic material is calculated in mole fraction, and the content of each component is as follows:
[0046] Main ingredient: Zinc oxide ZnO 100mol parts
[0047] First subcomponent: bismuth oxide Bi 2 o 3 , 0.7 mol parts dicobalt trioxide Co 2 o 3 , 0.8 mol parts manganese dioxide MnO 2 , 0.5 mol part Chromium trioxide Cr 2 o 3 0.5 mol parts And nickel oxide NiO 0.8mol parts,
[0048] Second subcomp...
Embodiment 2
[0064] The formula of the pressure-sensitive ceramic material is calculated in mole fraction, and the content of each component is as follows:
[0065] Main ingredient: Zinc oxide ZnO 100mol parts
[0066] First subcomponent: bismuth oxide Bi 2 o 3 , 0.7 mol parts dicobalt trioxide Co 2 o 3 , 0.8 mol parts manganese dioxide MnO 2 , 0.5 mol part Chromium trioxide Cr 2 o 3 0.5 mol parts And nickel oxide NiO 0.8mol parts,
[0067] Second subcomponent: antimony trioxide Sb 2 o 3 1.0 mol part;
[0068] The third subcomponent: Diyttrium trioxide Y 2 o 3 0.08 mol parts 、 Tungsten trioxide WO 3 0.5 mol part;
[0069] The fourth subcomponent: aluminum oxide Al 2 o 3 0.005mol parts.
[0070] The preparation method is the same as in Example 1.
[0071] It can be seen from Table 1 that the electrical performance test data of the pressure-sensitive ceramic material obtained by the above-mentioned implementation, Example 2, the small current characteristics...
Embodiment 3
[0074] The formula of the pressure-sensitive ceramic material is calculated in mole fraction, and the content of each component is as follows:
[0075] Main ingredient: Zinc oxide ZnO 100mol parts
[0076] First subcomponent: bismuth oxide Bi 2 o 3 , 0.7 mol parts dicobalt trioxide Co 2 o 3 , 0.8 mol parts manganese dioxide MnO 2 , 0.5 mol part Chromium trioxide Cr 2 o 3 0.5 mol parts And nickel oxide NiO 0.8mol parts,
[0077] Second subcomponent: antimony trioxide Sb 2 o 3 1.0 mol part;
[0078] The third subcomponent: Diyttrium trioxide Y 2 o 3 0.08 mol parts 、 Tungsten trioxide WO 3 0.9 mol parts;
[0079] The fourth subcomponent: aluminum oxide Al 2 o 3 0.005mol parts.
[0080] The preparation method is the same as in Example 1.
[0081] It can be seen from Table 1 that the electrical performance test data of the pressure-sensitive ceramic material obtained by the above implementation, the small current characteristics of the ceramic samp...
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