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A continuous decoking method for a thermal plasma reactor

A thermal plasma and reactor technology, applied in cleaning methods and appliances, chemical instruments and methods, cleaning hollow objects, etc., can solve the problems affecting the cracking gas dedusting and separation process, cracking gas flow and composition fluctuations, and potential safety hazards, etc. problems, to achieve significant cleaning effect, short cleaning time, small fluctuations in composition and flow

Active Publication Date: 2018-09-21
ZHEJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the reactor structure of the oxygen decoking method is simple and easy to implement, but if the mixed oxygen and hydrogen are not properly operated, there is a risk of explosion; although the water (steam) decoking method has a good effect, the energy consumption is relatively high , water vapor condensation can easily cause short circuit of the equipment, posing safety hazards
[0008] In addition, since the cracking reaction raw materials containing hydrocarbons such as coal and hydrocarbons will react with oxygen or water (steam), which will affect the coke cleaning process, the cracking reaction must be stopped during coke cleaning. Therefore, the existing oxygen coke cleaning The method and the water (steam) coke cleaning method are both intermittent operations. This alternate method of cracking reaction and coke cleaning will inevitably lead to huge fluctuations in the flow rate and composition of the cracking gas, which will affect the subsequent cracking gas dedusting and separation process.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Using the arc method to crack the reactor, with H 2 The discharge generates thermal plasma, and methane is used as the cracking raw material. While the cleavage reaction is going on, the CO 2 Adhering to the inner wall of the reactor, it is continuously fed into the reactor in a tangential direction to carry out the decoking reaction. CO 2 The feeding amount of the gas is 0.5vol% of the total gas amount, and the reactor is opened after the cracking reaction is carried out for 2 hours, and there is no coking residue in the reactor.

Embodiment 2

[0034] Using jet method cracking reactor, with H 2 The discharge generates thermal plasma, and methane is used as the cracking raw material. While the cleavage reaction is going on, the CO 2 Adhere to the inner wall of the reactor and continuously pass into the reactor in the axial direction to carry out the decoking reaction. CO 2 The feeding amount of the gas is 0.5vol% of the total gas amount, and the reactor is opened after the cracking reaction is carried out for 2 hours, and there is no coking residue in the reactor.

Embodiment 3

[0036] Using the arc method to crack the reactor, with H 2 Mixed gas with Ar (H 2 The content is 70vol%) to generate thermal plasma by discharge, and methane is used as cracking raw material. While the cleavage reaction is going on, the CO 2 Adhering to the inner wall of the reactor, it is continuously fed into the reactor in a tangential direction to carry out the decoking reaction. CO 2 The feeding amount of the gas is 1.0vol% of the total gas amount, and the reactor is opened after the cracking reaction is carried out for 2 hours, and there is no coking residue in the reactor.

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PUM

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Abstract

The invention discloses a continuous decoking method for a thermal plasma reactor. The continuous decoking method is characterized in that in the cleavage reaction process, decoking gas is continuously introduced to react with a coking material so as to finish coke cleaning; the decoking gas is carbon dioxide or a gas mixture of carbon dioxide and hydrogen. According to the invention, the pyrolysis gas flow and composition can't be influenced, the decoking can be conducted continuously, the continuous decoking method has the characteristics of short decoking time and high decoking efficiency, more safety and lower energy consumption; the continuous decoking method is suitable for different thermal plasma reactors and has an obvious cleaning effect for coking materials with different properties and content.

Description

technical field [0001] This paper relates to the field of thermal plasma reaction engineering at high temperature, in particular to a continuous decoking method for thermal plasma reactors. Background technique [0002] With the gradual depletion of oil resources and rising oil prices, people have turned their attention to coal, which is more abundant in resources. As a basic chemical raw material that can be obtained in large quantities from coal, acetylene is a good substitute for downstream products of petroleum and ethylene. There are two ways to produce acetylene in my country: calcium carbide hydrolysis and methane partial oxidation. The former has a long production process and CO 2 Large emissions and serious pollution, the latter is limited by the limited domestic natural gas resources. [0003] Thermal plasma pyrolysis coal acetylene technology utilizes the characteristics of thermal plasma high temperature (>3000K), high enthalpy, and rich in active particles....

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B08B9/08
CPCB08B9/08
Inventor 任其龙苏宝根闻光东邢华斌鲍宗必张治国杨启炜陈丰秋何潮洪陈新志吴忠标荣冈陈隆道
Owner ZHEJIANG UNIV
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