Tetrasiloxane containing sugar acylamino and preparation method

A technology containing sugar amide groups and tetrasiloxane, which is applied in the field of organosilicon compound preparation, can solve the problems of affecting performance and losing surface activity, and achieve the effect of good adsorption performance and difficult hydrolysis

Inactive Publication Date: 2014-10-01
BEIJING TECHNOLOGY AND BUSINESS UNIVERSITY
View PDF5 Cites 7 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Moreover, this type of trisiloxane is easily hydrolyzed in aqueous solution, and most of it

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Tetrasiloxane containing sugar acylamino and preparation method
  • Tetrasiloxane containing sugar acylamino and preparation method
  • Tetrasiloxane containing sugar acylamino and preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Add 1.62kg of hexamethyldisiloxane, 1.99kg of chloropropyltrimethoxysilane, and 0.006kg of concentrated sulfuric acid into reaction kettle 1, react at a temperature of 40°C for 4 hours, add sodium hydroxide to deactivate the catalyst, and filter The solid was removed and distilled under reduced pressure to obtain chloropropyltetrasiloxane. Add 3.73kg of chloropropyltetrasiloxane and 0.74kg of 1,3-propylenediamine into the reaction kettle 2, heat to 60°C, and react for 4 hours. - Aminopropyl-γ-aminopropyltetrasiloxane. Add 4.10kg of N-β-aminopropyl-γ-aminopropyltetrasiloxane and 1.78kg of gluconolactone into reaction kettle 3, use methanol as a solvent, heat to 60°C, react for 8 hours, and evaporate the solvent methanol to obtain tetrasiloxane containing sugar amido groups. It is measured that it does not hydrolyze within 30 days in water.

Embodiment 2

[0030] Add 8.12kg of hexamethyldisiloxane, 1.99kg of chloropropyltrimethoxysilane, and 0.10kg of acid clay to reaction kettle 1, react at a temperature of 50°C for 4 hours, remove the catalyst by filtration, and distill under reduced pressure to obtain chloropropane Tetrasiloxane. Add 3.73kg of chloropropyltetrasiloxane and 2.64kg of 1,4-butanediamine into the reaction kettle 2, heat to 80°C, and react for 3 hours. - Aminobutyl-γ-aminopropyltetrasiloxane. Add 4.24kg of N-β-aminobutyl-γ-aminopropyltetrasiloxane and 1.96kg of gluconic acid into the reaction kettle 3, use ethanol as solvent, heat to 70°C, react for 8 hours, evaporate the solvent ethanol, Tetrasiloxane containing sugar amido groups is obtained. It is measured that it does not hydrolyze within 30 days in water.

Embodiment 3

[0032] Add 16.24kg of hexamethyldisiloxane, 1.99kg of chloropropyltrimethoxysilane, and 0.54kg of concentrated sulfuric acid into reaction kettle 1, react at a temperature of 60°C for 4 hours, add sodium hydroxide to deactivate the catalyst, and filter The solid was removed and distilled under reduced pressure to obtain chloropropyltetrasiloxane. Add 3.73kg of chloropropyltetrasiloxane and 6.12kg of 1,5-pentamethylenediamine into the reaction kettle 2, heat to 90°C, react for 2 hours, the mixture is allowed to stand for layers, and the upper layer is distilled under reduced pressure to obtain N-β -Aminoamyl-γ-aminopropyltetrasiloxane. Add 4.38kg of N-β-aminopentyl-γ-aminopropyltetrasiloxane and 1.78kg of mannolactone to reaction kettle 3, use methanol as solvent, heat to 80°C, react for 10 hours, evaporate Solvent methanol to obtain tetrasiloxane containing sugar amido group. It is measured that it does not hydrolyze within 30 days in water.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention provides tetrasiloxane containing sugar acylamino and a preparation method, and belongs to the technical field of organic compound composition. The tetrasiloxane containing sugar acylamino is a compound obtained in a bonding reaction through silicone, oxygen, nitrogen or carbon in molecules; the preparation method comprises the following steps: propyl chloride tetrasiloxane is prepared by hexamethyldisiloxane and chloride propyl silane at presence of an acid catalyst; N-Beta-ammonia alkyl-Gamma-aminopropyl tetrasiloxane is prepared by propyl chloride tetrasiloxane and alkyl diamine; the tetrasiloxane containing sugar acylamino is prepared by the N-Beta-ammonia alkyl-Gamma-aminopropyl tetrasiloxane and saccharic acid or saccharic acid internal ester in a lower alcohol solvent; the tetrasiloxane containing sugar acylamino cannot be hydrolyzed in the water within 30 days and can be widely applied in the fields of pesticides and the like.

Description

technical field [0001] The invention relates to the field of preparation methods of organosilicon compounds, in particular to a sugar amide group-containing tetrasiloxane and a preparation method thereof. Background technique [0002] In addition to the properties of ordinary surfactants, trisiloxane surfactants also have more advantages than ordinary surfactants. They can be applied to non-aqueous systems, have lower surface tension, and extremely low physiological toxicity. In particular, it has good wetting and spreading properties. [0003] Han Fu (Chinese patent 200410092453.8) reported a method for preparing a glucose amido-modified trisiloxane surfactant, by reacting aminosilane with hexamethyldisiloxane to generate aminotrisiloxane, and then reacting with glucose Acid lactones react to form glucosamidotrisiloxane surfactants. [0004] In this sugar amide-containing trisiloxane surfactant, the carbon chain linking group between trisiloxane and glucose amide is very ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C07H23/00C07H1/00A01N25/30
Inventor 韩富武丽丽周雅文徐宝财
Owner BEIJING TECHNOLOGY AND BUSINESS UNIVERSITY
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap