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Polymer modification silane containing fluoro oxidation alkylene, surface treating agent relating same and object

A technology of alkylene oxide and surface treatment agent, applied in polyether coatings, coatings, etc., can solve problems such as insufficient heat resistance, achieve antifouling performance, excellent water and oil repellency, and high heat resistance Effect

Active Publication Date: 2014-10-29
SHIN ETSU CHEM IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The lens or antireflection film treated with the modified silane containing the perfluoroalkylene oxide polymer is excellent in slipperiness, release property and abrasion resistance, but insufficient in heat resistance

Method used

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  • Polymer modification silane containing fluoro oxidation alkylene, surface treating agent relating same and object
  • Polymer modification silane containing fluoro oxidation alkylene, surface treating agent relating same and object
  • Polymer modification silane containing fluoro oxidation alkylene, surface treating agent relating same and object

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0108] Mix the following formula (I) in the reaction vessel

[0109]

[0110] The indicated compound 100g (1.6×10 -2 mol) and 7.2 g of cesium fluoride, 44 g of tetraethylene glycol dimethyl ether, and 14 g of monoethylene glycol dimethyl ether were heated at 60° C. for 30 minutes, and aged at room temperature for 16 hours. Next, after cooling to -38° C., 29 g of hexafluoropropylene gas was supplied over 22 minutes for aging for 3 hours, and 16 g of hexafluoropropylene oxide gas was supplied over 54 minutes for aging for 3 hours. Then, 12 g of trimethylchlorosilane mixed with 30 g of heptane was added and mixed at room temperature for 1 hour. After filtering the resulting mixture, the organic solvent layer and the fluorine compound layer were separated, and the residual solvent was distilled off under reduced pressure to obtain the following formula (II):

[0111]

[0112] 106 g of perfluorooxyalkylene-containing polymers are shown.

[0113] Then, 145 g (2.3 × 10 -2 m...

Embodiment 2

[0122] Compound 40g (5.3 × 10 -3 mol) was dissolved in 10g of 1,3-trifluoromethylbenzene, and the toluene solution of chloroplatinic acid / vinylsiloxane complex 2.0×10 -2 g (as a Pt monomer containing 5.3×10 -7 mol) and 1-[1 or 2-(trimethoxysilyl) ethyl]-1,1,3,3-tetramethyldisiloxane (HDTMS) 1.8g (1.1×10 -2 mol), aged at 80°C for 4 hours, and the solvent and unreacted substances were distilled off under reduced pressure. Next, residual high boiling point components were removed by a molecular distillation apparatus to obtain 25 g of a liquid product.

[0123] The compound obtained in Example 2 was confirmed to have a structure of the following formula (VI) by NMR.

[0124]

Embodiment 3

[0126] Compound 40g (5.3 × 10 -3 mol) and tetramethylcyclotetrasiloxane (cyclosiloxane H4) 6.4g (2.7×10 -2 mol) was dissolved in 40 g of 1,3-trifluoromethylbenzene and heated to 90°C. Then, 2.0×10 toluene solution of chloroplatinic acid / vinylsiloxane complex was added dropwise -2 g (contains 5.0×10 as a Pt monomer -7 mol), aged at 90°C for 3 hours, and distilled off the solvent and unreacted substances under reduced pressure. The obtained product was mixed with 20 g of fluorine-based inert solvent PF5060 (manufactured by Sumitomo 3M Co., Ltd., Japan), 0.80 g of SHIRASAGI AS (manufactured by Japan Enviro Chemicals Co., Ltd.) was added as activated carbon, and stirred at room temperature for 1 hour. Then, SHIRASAGI AS was removed by filtration, and the solvent was distilled off to obtain 38 g of a liquid product represented by the following formula (VII).

[0127]

[0128] Next, 38 g (5.3 × 10 -3 mol) was dissolved in 21g of 1,3-trifluoromethylbenzene, and vinyltrimethox...

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Abstract

The invention provides a polymer modification silane containing fluoro oxidation alkylene and having a waterproof oilproof layer of excellent heat proof property, a surface treating agent having the silane and / or partial hydrolytic condensation product, and an object processed by the surface treating agent. The polymer modification silane containing fluoro oxidation alkylene is indicated by a following formula (1) (wherein, Rf refers to univalent or divalent linear link polymer residue containing fluoro oxidation alkylene, b is averagely 0-10, Z is a single 2-6valent group containing siloxane bond, R is singly alkyl or phenyl of 1-4 carbon atoms, X is a single hydrolytic group, a is a single 2 or 3, y is an integer between1-5 of each unit, alpha is an integer of 1-5, and beta is 1 or 2).

Description

technical field [0001] The present invention relates to a polymer-modified silane containing a fluorinated oxyalkylene group. Specifically, it relates to a polymer-modified silane containing a fluorinated oxyalkylene group which forms a film excellent in water and oil repellency and heat resistance. , a surface treatment agent containing the silane or a partial hydrolysis condensate thereof, and articles treated with the surface treatment agent. Background technique [0002] In recent years, touch panelization of screens, represented by mobile phone displays, is accelerating. However, the screen of the touch panel is in a bare state, and fingers or cheeks are often attached directly, and there is a problem that dirt such as sebum easily adheres. Therefore, in order to improve the appearance and visibility, there is an increasing demand for technology to prevent fingerprints from adhering to the display surface or technology to easily remove dirt, and it is desired to develo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G65/337C08G65/336C09D171/03
CPCC08G65/007C08G65/336
Inventor 酒匂隆介松田高至山根佑治
Owner SHIN ETSU CHEM IND CO LTD
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