A nano-microcapsule material with self-healing and wear-resistant functions and its preparation method
A nano-microcapsule and microcapsule finishing technology, applied in microcapsule preparation, microsphere preparation, textile and papermaking, etc., can solve the problems of uncomfortable ultra-light and thin down jackets, superfine fibers do not work, and reduce the air permeability of fabrics, etc. Enhanced anti-drilling performance, good anti-drilling, excellent perspiration and moisture permeability
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[0039] This example provides a nano-microcapsule material with self-healing and wear-resistant functions, which is prepared by the following steps:
[0040] (1) Chitosan modification: Add acetic acid solution into the reactor, add chitosan under nitrogen protection, heat to 65°C and stir until chitosan is completely dissolved, add ammonium persulfate, N,N′- Methyl bisacrylamide and acrylic acid, react at 65°C for 4 hours, stop the reaction, add ethanol, stir for 30 minutes, add alkali to adjust the pH to 7, filter, wash with water, soak in absolute ethanol for 24 hours, take it out, and dry it in vacuum. Obtain a white fluffy solid, and the mass ratio of acetic acid, chitosan, ammonium persulfate, N,N'-methylenebisacrylamide, acrylic acid and ethanol in the acetic acid solution is 3.5:15:1.5:0.3 in sequence :1:4;
[0041] (2) Introducing self-healing groups: Add the above-mentioned white fluffy solid, trithiocarbonate, ether, and azobisisobutyronitrile into the reactor at a m...
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